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Dr. Valeria Daniele
University of L'Aquila, Department of Industrial and Information Engineering and Economics

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0 Nanomaterials
0 Nanomaterials and nanostructures
0 characterization analysis
0 Nanomaterials for drug delivery
0 Nanomaterials synthesis

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Journal article
Published: 20 March 2021 in Nanomaterials
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This work introduces an innovative, sustainable, and scalable synthesis of iron oxides nanoparticles (NPs) in aqueous suspension. The method, based on ion exchange process, consists of a one-step procedure, time and energy saving, operating in water and at room temperature, by cheap and renewable reagents. The influence of both oxidation state of the initial reagent and reaction atmosphere is considered. Three kinds of iron nanostructured compounds are obtained (2-lines ferrihydrite; layered-structure iron oxyhydroxide δ-FeOOH; and cubic magnetite), in turn used as precursors to obtain hematite and maghemite NPs. All the produced NPs are characterized by a high purity, small particles dimensions (from 2 to 50 nm), and high specific surface area values up to 420 m2/g, with yields of production >90%. In particular, among the most common iron oxide NPs, we obtained cubic magnetite NPs at room temperature, characterized by particle dimensions of about 6 nm and a surface area of 170 m2/g. We also obtained hematite NPs at very low temperature conditions (that is 2 h at 200 °C), characterized by particles dimensions of about 5 nm with a surface area value of 200 m2/g. The obtained results underline the strength of the synthetic method to provide a new, sustainable, tunable, and scalable high-quality production.

ACS Style

Ludovico Macera; Valeria Daniele; Claudia Mondelli; Marie Capron; Giuliana Taglieri. New Sustainable, Scalable and One-Step Synthesis of Iron Oxide Nanoparticles by Ion Exchange Process. Nanomaterials 2021, 11, 798 .

AMA Style

Ludovico Macera, Valeria Daniele, Claudia Mondelli, Marie Capron, Giuliana Taglieri. New Sustainable, Scalable and One-Step Synthesis of Iron Oxide Nanoparticles by Ion Exchange Process. Nanomaterials. 2021; 11 (3):798.

Chicago/Turabian Style

Ludovico Macera; Valeria Daniele; Claudia Mondelli; Marie Capron; Giuliana Taglieri. 2021. "New Sustainable, Scalable and One-Step Synthesis of Iron Oxide Nanoparticles by Ion Exchange Process." Nanomaterials 11, no. 3: 798.

Journal article
Published: 03 September 2020 in Nanomaterials
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Waterlogged wooden artifacts represent an important historical legacy of our past. They are very fragile, especially due to the severe phenomenon of acidification that may occur in the presence of acid precursors. To date, a satisfactory solution for the deacidification of ancient wood on a large scale has still not been found. In this paper, we propose, for the first time, eco-friendly curative and preventive treatments using nanoparticles (NPs) of earth alkaline hydroxides dispersed in water and produced on a large scale. We present the characterization of the NPs (by X-ray diffraction, atomic-force and electron microscopy, and small-angle neutron scattering), together with the study of the deacidification efficiency of our treatments. We demonstrate that all our treatments are very effective for both curative and preventive aims, able to assure an almost neutral or slightly alkaline pH of the treated woods. Furthermore, the use of water as a solvent paves the way for large-scale and eco-friendly applications which avoid substances that are harmful for the environment and for human health.

ACS Style

Giuliana Taglieri; Valeria Daniele; Ludovico Macera; Ralf Schweins; Sandro Zorzi; Marie Capron; Gilles Chaumat; Claudia Mondelli. Sustainable Nanotechnologies for Curative and Preventive Wood Deacidification Treatments: An Eco-Friendly and Innovative Approach. Nanomaterials 2020, 10, 1744 .

AMA Style

Giuliana Taglieri, Valeria Daniele, Ludovico Macera, Ralf Schweins, Sandro Zorzi, Marie Capron, Gilles Chaumat, Claudia Mondelli. Sustainable Nanotechnologies for Curative and Preventive Wood Deacidification Treatments: An Eco-Friendly and Innovative Approach. Nanomaterials. 2020; 10 (9):1744.

Chicago/Turabian Style

Giuliana Taglieri; Valeria Daniele; Ludovico Macera; Ralf Schweins; Sandro Zorzi; Marie Capron; Gilles Chaumat; Claudia Mondelli. 2020. "Sustainable Nanotechnologies for Curative and Preventive Wood Deacidification Treatments: An Eco-Friendly and Innovative Approach." Nanomaterials 10, no. 9: 1744.

Journal article
Published: 09 July 2020 in Construction and Building Materials
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Synchrotron X-ray diffraction investigations were performed to study the reactivity of a nanolime produced by an innovative method based on an ion exchange process, both in aqueous and in alcoholic suspensions. Moreover, for the first time, the nanolime reactivity was investigated both on laboratory glass slides and directly on artistic relevant stones, the biocalcarenite of Agrigento. The results showed that only aqueous suspension exhibits a complete conversion into calcite. The transformation is favoured on porous stone surface, allowing the nanolime suspension to be absorbed and dispersed, increasing the CO2 diffusion.

ACS Style

L. Macera; L. Gigli; V. Daniele; J.R. Plaisier; L. Arrizza; G. Taglieri. Synchrotron investigations of the nanolime reactivity on biocalcarenite stone surfaces. Construction and Building Materials 2020, 262, 120066 .

AMA Style

L. Macera, L. Gigli, V. Daniele, J.R. Plaisier, L. Arrizza, G. Taglieri. Synchrotron investigations of the nanolime reactivity on biocalcarenite stone surfaces. Construction and Building Materials. 2020; 262 ():120066.

Chicago/Turabian Style

L. Macera; L. Gigli; V. Daniele; J.R. Plaisier; L. Arrizza; G. Taglieri. 2020. "Synchrotron investigations of the nanolime reactivity on biocalcarenite stone surfaces." Construction and Building Materials 262, no. : 120066.

Journal article
Published: 22 May 2020 in Materials
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Invisible orthodontic aligners (IOAs) have been introduced in the orthodontic field as an innovative alternative for fixed brackets, in relation to their ability to be easily inserted/removed from the oral cavity without affecting the chewing ability and the aesthetic of the patients. The paper provides a complete physicochemical and mechanical characterization of thermoplastic materials in the form of disks used for commercial IOAs. A wide palette of specific techniques is considered, from tensile tests and dynamic-mechanical analysis, to X-Ray diffraction (XRD), differential scanning calorimetry (DSC), Fourier transformation infrared spectroscopy (FTIR-ATR) analyses and water absorption tests. The disks are investigated before and after immersion into staining beverages (red wine, coffee, nicotine and artificial saliva), in terms of colour variations, transparency, and microscopic surface modifications by means of colorimetry, UV-VIS absorbance and scanning electron microscopy (SEM). Among all the samples, polyurethane (PU) exhibited the highest crystallinity and the highest values of mechanical and thermal resistance, while the poly(ethylene terephthalate)-glycol (PETG) samples presented better transparency and less ability to absorb water. Moreover, red wine and coffee give noticeable colour variations after 14 days of immersion, together with a slight reduction of transparency.

ACS Style

Valeria Daniele; Ludovico Macera; Giuliana Taglieri; Alessandra Di Giambattista; Giuseppe Spagnoli; Alessandra Massaria; Massimo Messori; Enrico Quagliarini; Gianluca Chiappini; Vincenzo Campanella; Stefano Mummolo; Enrico Marchetti; Giuseppe Marzo; Vincenzo Quinzi. Thermoplastic Disks Used for Commercial Orthodontic Aligners: Complete Physicochemical and Mechanical Characterization. Materials 2020, 13, 2386 .

AMA Style

Valeria Daniele, Ludovico Macera, Giuliana Taglieri, Alessandra Di Giambattista, Giuseppe Spagnoli, Alessandra Massaria, Massimo Messori, Enrico Quagliarini, Gianluca Chiappini, Vincenzo Campanella, Stefano Mummolo, Enrico Marchetti, Giuseppe Marzo, Vincenzo Quinzi. Thermoplastic Disks Used for Commercial Orthodontic Aligners: Complete Physicochemical and Mechanical Characterization. Materials. 2020; 13 (10):2386.

Chicago/Turabian Style

Valeria Daniele; Ludovico Macera; Giuliana Taglieri; Alessandra Di Giambattista; Giuseppe Spagnoli; Alessandra Massaria; Massimo Messori; Enrico Quagliarini; Gianluca Chiappini; Vincenzo Campanella; Stefano Mummolo; Enrico Marchetti; Giuseppe Marzo; Vincenzo Quinzi. 2020. "Thermoplastic Disks Used for Commercial Orthodontic Aligners: Complete Physicochemical and Mechanical Characterization." Materials 13, no. 10: 2386.

Journal article
Published: 14 February 2020 in Nanomaterials
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This paper introduces an original, eco-friendly and scalable method to synthesize ferrihydrite nanoparticles in aqueous suspensions, which can also be used as a precursor to produce α-hematite nanoparticles. The method, never used before to synthesize iron oxides, is based on an ion exchange process allowing to operate in one-step, with reduced times, at room temperature and ambient pressure, and using cheap or renewable reagents. The influence of reagent concentrations and time of the process on the ferrihydrite features is considered. The transformation to hematite is then analyzed and discussed in relation to different procedures: (1) A natural aging in the water at room temperature; and (2) heat treatments at different temperatures and times. Structural and morphological features of the obtained nanoparticles are investigated by means of several techniques, such as X-ray diffraction, X-ray photoelectron spectroscopy, attenuated total reflectance Fourier transform infrared spectroscopy, transmission and scanning electron microscopy, thermal analysis, nitrogen adsorption and magnetic measurements. Ferrihydrite shows the typical spherical morphology and a very high specific surface area of 420 m2/g. Rhombohedral or plate-like hexagonal hematite nanoparticles are obtained by the two procedures, characterized by dimensions of 50 nm and 30 nm, respectively, and a specific surface area up to 57 m2/g, which is among the highest values reported in the literature for hematite NPs.

ACS Style

Ludovico Macera; Giuliana Taglieri; Valeria Daniele; Maurizio Passacantando; Franco D’Orazio. Nano-Sized Fe(III) Oxide Particles Starting from an Innovative and Eco-Friendly Synthesis Method. Nanomaterials 2020, 10, 323 .

AMA Style

Ludovico Macera, Giuliana Taglieri, Valeria Daniele, Maurizio Passacantando, Franco D’Orazio. Nano-Sized Fe(III) Oxide Particles Starting from an Innovative and Eco-Friendly Synthesis Method. Nanomaterials. 2020; 10 (2):323.

Chicago/Turabian Style

Ludovico Macera; Giuliana Taglieri; Valeria Daniele; Maurizio Passacantando; Franco D’Orazio. 2020. "Nano-Sized Fe(III) Oxide Particles Starting from an Innovative and Eco-Friendly Synthesis Method." Nanomaterials 10, no. 2: 323.

Journal article
Published: 20 June 2019 in Construction and Building Materials
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This paper presents an original, green and compatible treatment to consolidate the pointing lime plastering of the façade of a medieval Italian palace, subjected to detachments and pulverization phenomena. The cohesion between the mortar constituents was refurbished by an aqueous nanolime suspension, synthesized by a cheap, time/energy-saving and scalable method, here originally tested on historic mortars. The suspension showed a high reactivity, assuring a complete carbonation in few hours, “restoring” the binder fraction with a new-formed network of calcite nanoparticles. The treatment efficacy was evaluated by chemico-physical, mineralogical and mechanical characterization both on untreated and treated specimens.

ACS Style

G. Taglieri; V. Daniele; L. Macera; A. Mignemi. Innovative and green nanolime treatment tailored to consolidate the original mortar of the façade of a medieval building in L’aquila (Italy). Construction and Building Materials 2019, 221, 643 -650.

AMA Style

G. Taglieri, V. Daniele, L. Macera, A. Mignemi. Innovative and green nanolime treatment tailored to consolidate the original mortar of the façade of a medieval building in L’aquila (Italy). Construction and Building Materials. 2019; 221 ():643-650.

Chicago/Turabian Style

G. Taglieri; V. Daniele; L. Macera; A. Mignemi. 2019. "Innovative and green nanolime treatment tailored to consolidate the original mortar of the façade of a medieval building in L’aquila (Italy)." Construction and Building Materials 221, no. : 643-650.

Short communication
Published: 30 May 2019 in Soils and Foundations
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Innovations in jet grouting technology have primarily focused on the cutting efficiency of the jets, with the aim of creating larger columns and increasing the productivity of construction sites. Relatively little attention has been paid to the consequences of the grouting system on the mechanical properties of the formed material. This paper investigates this aspect by analysing the results of two field trials carried out in both sandy and clayey soils, where single and double fluid jet grouting were simultaneously performed, with varied grout composition and injection parameters. Parallel uniaxial compressive tests on samples cored from the columns show that the material formed with the double system is systematically lower in strength than the material formed using the single fluid system. The mineralogical composition of samples cored from the columns was analysed by performing parallel Scanning Electron Microscopy (SEM), X-ray diffraction analysis (XRD), Differential Thermal Analysis (DTA) and Thermo-Gravimetric Analyses (TGA) to determine the reasons for this difference. A lower proportion of cementitious products, an accelerated carbonation of portlandite and a less homogeneous distribution of cement hydration products was found on the surface of the soil particles of the double samples than for the single fluid columns.

ACS Style

Giuseppe Modoni; Lidia Wanik; Cristina Mascolo Maria; Erminio Salvatore; Joanna Bzówka; Shen Shui-Long; Valeria Daniele; Luca Pingue. Strength of sandy and clayey soils cemented with single and double fluid jet grouting. Soils and Foundations 2019, 59, 942 -954.

AMA Style

Giuseppe Modoni, Lidia Wanik, Cristina Mascolo Maria, Erminio Salvatore, Joanna Bzówka, Shen Shui-Long, Valeria Daniele, Luca Pingue. Strength of sandy and clayey soils cemented with single and double fluid jet grouting. Soils and Foundations. 2019; 59 (4):942-954.

Chicago/Turabian Style

Giuseppe Modoni; Lidia Wanik; Cristina Mascolo Maria; Erminio Salvatore; Joanna Bzówka; Shen Shui-Long; Valeria Daniele; Luca Pingue. 2019. "Strength of sandy and clayey soils cemented with single and double fluid jet grouting." Soils and Foundations 59, no. 4: 942-954.

Journal article
Published: 01 January 2019 in Solid State Phenomena
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The objective of this paper is to introduce a patented and eco-friendly method to synthesize aqueous suspension of all types of alkaline-earth metal hydroxides nanoparticles (NPs). This method is based on an ion exchange process; the exchange takes place at ambient temperature/pressure, starts from cheap or renewable reagents and, in one single step, results in the creation of the crystalline desired nanoparticles in only a few minutes. In terms of structural and morphological features, the synthesized nanoparticles are characterized by means of XRD-Rietveld refinement, FTIR, and TEM. In particular, we obtained pure and crystalline magnesium and calcium hydroxide suspensions, showing the typical brucite crystal structure with a hexagonal lamellar morphology and dimensions generally

ACS Style

Giuliana Taglieri; Valeria Daniele; Ludovico Macera. Synthesizing Alkaline Earth Metal Hydroxides Nanoparticles through an Innovative, Single-Step and Eco-Friendly Method. Solid State Phenomena 2019, 286, 3 -14.

AMA Style

Giuliana Taglieri, Valeria Daniele, Ludovico Macera. Synthesizing Alkaline Earth Metal Hydroxides Nanoparticles through an Innovative, Single-Step and Eco-Friendly Method. Solid State Phenomena. 2019; 286 ():3-14.

Chicago/Turabian Style

Giuliana Taglieri; Valeria Daniele; Ludovico Macera. 2019. "Synthesizing Alkaline Earth Metal Hydroxides Nanoparticles through an Innovative, Single-Step and Eco-Friendly Method." Solid State Phenomena 286, no. : 3-14.

Journal article
Published: 15 August 2018 in Construction and Building Materials
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In this paper, we investigate a conservation treatment on different kinds of Agrigento’s biocalcarenites, introducing a new non-commercial aqueous nanolime suspension for compatible and eco-friendly extensive applications. This nanolime, here tested for the first time, can be considered a green treatment for both the environment and the health of the conservator. Petrographic, chemico-physical and mechanical investigations of the different biocalcarenites were carried out before and after treatment application. This new nanolime yielded a very promising consolidation effectiveness for all the biocalcarenites, increasing the superficial cohesion and the drilling resistance without significantly altering the stone porosity or the aesthetical features.

ACS Style

V. Daniele; G. Taglieri; L. Macera; G. Rosatelli; J. Otero; A.E. Charola. Green approach for an eco-compatible consolidation of the Agrigento biocalcarenites surface. Construction and Building Materials 2018, 186, 1188 -1199.

AMA Style

V. Daniele, G. Taglieri, L. Macera, G. Rosatelli, J. Otero, A.E. Charola. Green approach for an eco-compatible consolidation of the Agrigento biocalcarenites surface. Construction and Building Materials. 2018; 186 ():1188-1199.

Chicago/Turabian Style

V. Daniele; G. Taglieri; L. Macera; G. Rosatelli; J. Otero; A.E. Charola. 2018. "Green approach for an eco-compatible consolidation of the Agrigento biocalcarenites surface." Construction and Building Materials 186, no. : 1188-1199.

Review
Published: 11 July 2018 in Journal of Applied Biomaterials & Functional Materials
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This review presents “a state of the art” report on sustainability in construction materials. The authors propose different solutions to make the concrete industry more environmentally friendly in order to reduce greenhouse gases emissions and consumption of non-renewable resources. Part 1—the present paper—focuses on the use of binders alternative to Portland cement, including sulfoaluminate cements, alkali-activated materials, and geopolymers. Part 2 will be dedicated to traditional Portland-free binders and waste management and recycling in mortar and concrete production.

ACS Style

Luigi Coppola; Tiziano Bellezze; Alberto Belli; Maria Chiara Bignozzi; Fabio Maria Bolzoni; Andrea Brenna; Marina Cabrini; Sebastiano Candamano; Marta Cappai; Domenico Caputo; Maddalena Carsana; Ludovica Casnedi; Raffaele Cioffi; Ombretta Cocco; Denny Coffetti; Francesco Colangelo; Bartolomeo Coppola; Valeria Corinaldesi; Fortunato Crea; Elena Crotti; Valeria Daniele; Sabino De Gisi; Francesco Delogu; Maria Vittoria Diamanti; Luciano Di Maio; Rosa Di Mundo; Luca Di Palma; Jacopo Donnini; Ilenia Farina; Claudio Ferone; Patrizia Frontera; Matteo Gastaldi; Chiara Giosuè; Loredana Incarnato; Barbara Liguori; Federica Lollini; Sergio Lorenzi; Stefania Manzi; Ottavio Marino; Milena Marroccoli; Maria Cristina Mascolo; Letterio Mavilia; Alida Mazzoli; Franco Medici; Paola Meloni; Glauco Merlonetti; Alessandra Mobili; Michele Notarnicola; Marco Ormellese; Tommaso Pastore; Mariapia Pedeferri; Andrea Petrella; Giorgio Pia; Elena Redaelli; Giuseppina Roviello; Paola Scarfato; Giancarlo Scoccia; Giuliana Taglieri; Antonio Telesca; Francesca Tittarelli; Francesco Todaro; Giorgio Vilardi; Fan Yang. Binders alternative to Portland cement and waste management for sustainable construction—part 1. Journal of Applied Biomaterials & Functional Materials 2018, 16, 186 -202.

AMA Style

Luigi Coppola, Tiziano Bellezze, Alberto Belli, Maria Chiara Bignozzi, Fabio Maria Bolzoni, Andrea Brenna, Marina Cabrini, Sebastiano Candamano, Marta Cappai, Domenico Caputo, Maddalena Carsana, Ludovica Casnedi, Raffaele Cioffi, Ombretta Cocco, Denny Coffetti, Francesco Colangelo, Bartolomeo Coppola, Valeria Corinaldesi, Fortunato Crea, Elena Crotti, Valeria Daniele, Sabino De Gisi, Francesco Delogu, Maria Vittoria Diamanti, Luciano Di Maio, Rosa Di Mundo, Luca Di Palma, Jacopo Donnini, Ilenia Farina, Claudio Ferone, Patrizia Frontera, Matteo Gastaldi, Chiara Giosuè, Loredana Incarnato, Barbara Liguori, Federica Lollini, Sergio Lorenzi, Stefania Manzi, Ottavio Marino, Milena Marroccoli, Maria Cristina Mascolo, Letterio Mavilia, Alida Mazzoli, Franco Medici, Paola Meloni, Glauco Merlonetti, Alessandra Mobili, Michele Notarnicola, Marco Ormellese, Tommaso Pastore, Mariapia Pedeferri, Andrea Petrella, Giorgio Pia, Elena Redaelli, Giuseppina Roviello, Paola Scarfato, Giancarlo Scoccia, Giuliana Taglieri, Antonio Telesca, Francesca Tittarelli, Francesco Todaro, Giorgio Vilardi, Fan Yang. Binders alternative to Portland cement and waste management for sustainable construction—part 1. Journal of Applied Biomaterials & Functional Materials. 2018; 16 (3):186-202.

Chicago/Turabian Style

Luigi Coppola; Tiziano Bellezze; Alberto Belli; Maria Chiara Bignozzi; Fabio Maria Bolzoni; Andrea Brenna; Marina Cabrini; Sebastiano Candamano; Marta Cappai; Domenico Caputo; Maddalena Carsana; Ludovica Casnedi; Raffaele Cioffi; Ombretta Cocco; Denny Coffetti; Francesco Colangelo; Bartolomeo Coppola; Valeria Corinaldesi; Fortunato Crea; Elena Crotti; Valeria Daniele; Sabino De Gisi; Francesco Delogu; Maria Vittoria Diamanti; Luciano Di Maio; Rosa Di Mundo; Luca Di Palma; Jacopo Donnini; Ilenia Farina; Claudio Ferone; Patrizia Frontera; Matteo Gastaldi; Chiara Giosuè; Loredana Incarnato; Barbara Liguori; Federica Lollini; Sergio Lorenzi; Stefania Manzi; Ottavio Marino; Milena Marroccoli; Maria Cristina Mascolo; Letterio Mavilia; Alida Mazzoli; Franco Medici; Paola Meloni; Glauco Merlonetti; Alessandra Mobili; Michele Notarnicola; Marco Ormellese; Tommaso Pastore; Mariapia Pedeferri; Andrea Petrella; Giorgio Pia; Elena Redaelli; Giuseppina Roviello; Paola Scarfato; Giancarlo Scoccia; Giuliana Taglieri; Antonio Telesca; Francesca Tittarelli; Francesco Todaro; Giorgio Vilardi; Fan Yang. 2018. "Binders alternative to Portland cement and waste management for sustainable construction—part 1." Journal of Applied Biomaterials & Functional Materials 16, no. 3: 186-202.

Review
Published: 10 July 2018 in Journal of Applied Biomaterials & Functional Materials
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The paper represents the “state of the art” on sustainability in construction materials. In Part 1 of the paper, issues related to production, microstructures, chemical nature, engineering properties, and durability of mixtures based on binders alternative to Portland cement were presented. This second part of the paper concerns the use of traditional and innovative Portland-free lime-based mortars in the conservation of cultural heritage, and the recycling and management of wastes to reduce consumption of natural resources in the production of construction materials. The latter is one of the main concerns in terms of sustainability since nowadays more than 75% of wastes are disposed of in landfills.

ACS Style

Luigi Coppola; Tiziano Bellezze; Alberto Belli; Maria C Bignozzi; Fabio Maria Bolzoni; Andrea Brenna; Marina Cabrini; Sebastiano Candamano; Marta Cappai; Domenico Caputo; Maddalena Carsana; Ludovica Casnedi; Raffaele Cioffi; Ombretta Cocco; Denny Coffetti; Francesco Colangelo; Bartolomeo Coppola; Valeria Corinaldesi; Fortunato Crea; Elena Crotti; Valeria Daniele; Sabino De Gisi; Francesco Delogu; Maria V Diamanti; Luciano Di Maio; Rosa Di Mundo; Luca Di Palma; Jacopo Donnini; Ilenia Farina; Claudio Ferone; Patrizia Frontera; Matteo Gastaldi; Chiara Giosuè; Loredana Incarnato; Barbara Liguori; Federica Lollini; Sergio Lorenzi; Stefania Manzi; Ottavio Marino; Milena Marroccoli; Maria C Mascolo; Letterio Mavilia; Alida Mazzoli; Franco Medici; Paola Meloni; Glauco Merlonetti; Alessandra Mobili; Michele Notarnicola; Marco Ormellese; Tommaso Pastore; Mariapia Pedeferri; Andrea Petrella; Giorgio Pia; Elena Redaelli; Giuseppina Roviello; Paola Scarfato; Giancarlo Scoccia; Giuliana Taglieri; Antonio Telesca; Francesca Tittarelli; Francesco Todaro; Giorgio Vilardi; Fan Yang. Binders alternative to Portland cement and waste management for sustainable construction – Part 2. Journal of Applied Biomaterials & Functional Materials 2018, 16, 207 -221.

AMA Style

Luigi Coppola, Tiziano Bellezze, Alberto Belli, Maria C Bignozzi, Fabio Maria Bolzoni, Andrea Brenna, Marina Cabrini, Sebastiano Candamano, Marta Cappai, Domenico Caputo, Maddalena Carsana, Ludovica Casnedi, Raffaele Cioffi, Ombretta Cocco, Denny Coffetti, Francesco Colangelo, Bartolomeo Coppola, Valeria Corinaldesi, Fortunato Crea, Elena Crotti, Valeria Daniele, Sabino De Gisi, Francesco Delogu, Maria V Diamanti, Luciano Di Maio, Rosa Di Mundo, Luca Di Palma, Jacopo Donnini, Ilenia Farina, Claudio Ferone, Patrizia Frontera, Matteo Gastaldi, Chiara Giosuè, Loredana Incarnato, Barbara Liguori, Federica Lollini, Sergio Lorenzi, Stefania Manzi, Ottavio Marino, Milena Marroccoli, Maria C Mascolo, Letterio Mavilia, Alida Mazzoli, Franco Medici, Paola Meloni, Glauco Merlonetti, Alessandra Mobili, Michele Notarnicola, Marco Ormellese, Tommaso Pastore, Mariapia Pedeferri, Andrea Petrella, Giorgio Pia, Elena Redaelli, Giuseppina Roviello, Paola Scarfato, Giancarlo Scoccia, Giuliana Taglieri, Antonio Telesca, Francesca Tittarelli, Francesco Todaro, Giorgio Vilardi, Fan Yang. Binders alternative to Portland cement and waste management for sustainable construction – Part 2. Journal of Applied Biomaterials & Functional Materials. 2018; 16 (4):207-221.

Chicago/Turabian Style

Luigi Coppola; Tiziano Bellezze; Alberto Belli; Maria C Bignozzi; Fabio Maria Bolzoni; Andrea Brenna; Marina Cabrini; Sebastiano Candamano; Marta Cappai; Domenico Caputo; Maddalena Carsana; Ludovica Casnedi; Raffaele Cioffi; Ombretta Cocco; Denny Coffetti; Francesco Colangelo; Bartolomeo Coppola; Valeria Corinaldesi; Fortunato Crea; Elena Crotti; Valeria Daniele; Sabino De Gisi; Francesco Delogu; Maria V Diamanti; Luciano Di Maio; Rosa Di Mundo; Luca Di Palma; Jacopo Donnini; Ilenia Farina; Claudio Ferone; Patrizia Frontera; Matteo Gastaldi; Chiara Giosuè; Loredana Incarnato; Barbara Liguori; Federica Lollini; Sergio Lorenzi; Stefania Manzi; Ottavio Marino; Milena Marroccoli; Maria C Mascolo; Letterio Mavilia; Alida Mazzoli; Franco Medici; Paola Meloni; Glauco Merlonetti; Alessandra Mobili; Michele Notarnicola; Marco Ormellese; Tommaso Pastore; Mariapia Pedeferri; Andrea Petrella; Giorgio Pia; Elena Redaelli; Giuseppina Roviello; Paola Scarfato; Giancarlo Scoccia; Giuliana Taglieri; Antonio Telesca; Francesca Tittarelli; Francesco Todaro; Giorgio Vilardi; Fan Yang. 2018. "Binders alternative to Portland cement and waste management for sustainable construction – Part 2." Journal of Applied Biomaterials & Functional Materials 16, no. 4: 207-221.

Journal article
Published: 01 March 2018 in Journal of Cultural Heritage
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ACS Style

Giuliana Taglieri; Jorge Otero; Valeria Daniele; Gianluca Gioia; Ludovico Macera; Vincenzo Starinieri; Asuncion Elena Charola. The biocalcarenite stone of Agrigento (Italy): Preliminary investigations of compatible nanolime treatments. Journal of Cultural Heritage 2018, 30, 92 -99.

AMA Style

Giuliana Taglieri, Jorge Otero, Valeria Daniele, Gianluca Gioia, Ludovico Macera, Vincenzo Starinieri, Asuncion Elena Charola. The biocalcarenite stone of Agrigento (Italy): Preliminary investigations of compatible nanolime treatments. Journal of Cultural Heritage. 2018; 30 ():92-99.

Chicago/Turabian Style

Giuliana Taglieri; Jorge Otero; Valeria Daniele; Gianluca Gioia; Ludovico Macera; Vincenzo Starinieri; Asuncion Elena Charola. 2018. "The biocalcarenite stone of Agrigento (Italy): Preliminary investigations of compatible nanolime treatments." Journal of Cultural Heritage 30, no. : 92-99.

Journal article
Published: 16 November 2017 in Journal of the American Ceramic Society
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Nanosized MgO is a functional material showing a great promise as destructive adsorbent for toxic chemical agents, unique optical electronic, magnetic, thermal, and mechanical properties, as well as in good bactericidal performance in aqueous environments and in the cancer therapy. In this study, MgO nanoparticles are obtained by thermal decomposition of nanosized Mg(OH)2, which are synthesized by means of an innovative, time and cost-effective, scalable, and patented method. The nanoparticles are characterized by means of several techniques such as thermal analyses, X-ray diffraction analysis, infrared spectroscopy, transmission electron microscopy, atomic force microscopy, and surface area measurements (BET). After a pseudomorphic decomposition of the hydroxide precursor, pure and crystalline MgO nanoparticles are obtained. These nanoparticles are roughly spherical, monodispersed, and monocrystalline, having size ≤10 nm. Moreover, they exhibited a surface area up to 178 m2/g, revealing a bimodal mesoporous distribution with the important part of the pores with dimensions peaked at 4.87 nm.

ACS Style

Giuliana Taglieri; Valeria Daniele; Claudia Mondelli. MgO nanoparticles synthesized starting from an innovative one-step process. Journal of the American Ceramic Society 2017, 101, 1780 -1789.

AMA Style

Giuliana Taglieri, Valeria Daniele, Claudia Mondelli. MgO nanoparticles synthesized starting from an innovative one-step process. Journal of the American Ceramic Society. 2017; 101 (4):1780-1789.

Chicago/Turabian Style

Giuliana Taglieri; Valeria Daniele; Claudia Mondelli. 2017. "MgO nanoparticles synthesized starting from an innovative one-step process." Journal of the American Ceramic Society 101, no. 4: 1780-1789.

Journal article
Published: 01 October 2017 in Ceramics International
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ACS Style

Hossein Shalchian; Jalil Vahdati Khaki; Abolfazl Babakhani; Giuliana Taglieri; Ida de Michelis; Valeria Daniele; Francesco Veglio. On the mechanism of molybdenite exfoliation during mechanical milling. Ceramics International 2017, 43, 12957 -12967.

AMA Style

Hossein Shalchian, Jalil Vahdati Khaki, Abolfazl Babakhani, Giuliana Taglieri, Ida de Michelis, Valeria Daniele, Francesco Veglio. On the mechanism of molybdenite exfoliation during mechanical milling. Ceramics International. 2017; 43 (15):12957-12967.

Chicago/Turabian Style

Hossein Shalchian; Jalil Vahdati Khaki; Abolfazl Babakhani; Giuliana Taglieri; Ida de Michelis; Valeria Daniele; Francesco Veglio. 2017. "On the mechanism of molybdenite exfoliation during mechanical milling." Ceramics International 43, no. 15: 12957-12967.

Journal article
Published: 14 August 2017 in Journal of the American Ceramic Society
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Ca(OH)2 nanoparticles in hydro-alcoholic dispersion (nanolime) are currently used for eco-compatible treatments of carbonate-based substrates in the field of Cultural Heritage conservation. Unfortunately, at present nanolime is synthesized by processes which present some drawbacks (considerable cost, multiple steps, low specific production yield), thus limiting the potential of its applications. We have developed a single-step procedure, based on an ion exchange process, making it possible to produce pure and crystalline Ca(OH)2 nanoparticles easily in water, at room temperature and ambient pressure, starting from cheap or renewable reactants. The simplicity of the process and its time- and energy-saving aspects are very promising factors for extending the production from laboratory to industrial scale. The aim of this paper is to investigate the structural and morphological features of the nanoparticles produced and to analyze the influence of crucial parameters of the synthesis process (i.e., time, water usage, reagent concentration and reaction volume) on the nanoparticles’ characteristics. The nanolime produced is investigated by XRD, FTIR, TEM, and AFM techniques. The nanoparticle reactivity in the carbonation process is also investigated, by varying the suspension concentration, the solvent and relative humidity conditions. Pure, crystalline, and very reactive Ca(OH)2 nanoparticles are obtained. The nanoparticles are constituted of thin lamellas, composed of primary hexagonal nanoparticles <10 nm, irrespective of time, water employed, reagents concentration, and reaction volume.

ACS Style

Giuliana Taglieri; Valeria Daniele; Ludovico Macera; Claudia Mondelli. Nano Ca(OH)2synthesis using a cost-effective and innovative method: Reactivity study. Journal of the American Ceramic Society 2017, 100, 5766 -5778.

AMA Style

Giuliana Taglieri, Valeria Daniele, Ludovico Macera, Claudia Mondelli. Nano Ca(OH)2synthesis using a cost-effective and innovative method: Reactivity study. Journal of the American Ceramic Society. 2017; 100 (12):5766-5778.

Chicago/Turabian Style

Giuliana Taglieri; Valeria Daniele; Ludovico Macera; Claudia Mondelli. 2017. "Nano Ca(OH)2synthesis using a cost-effective and innovative method: Reactivity study." Journal of the American Ceramic Society 100, no. 12: 5766-5778.

Journal article
Published: 01 June 2017 in Advanced Science Letters
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In this paper, MgO nanoparticles are prepared by calcinating Mg(OH)2 colloidal suspensions produced through an original, eco-friendly, single step, and scalable method. This method, based on an exchange ion process, is extremely simple and rapid (few minutes); it employs low-cost or renewable reactants, operates at room temperature and does not require intermediate steps, such as washings and purifications. The synthesized Mg(OH)2 nanoparticles, as well as the MgO ones, are characterized by means of chemico-physical, microstructural and morphological analyses such as thermal analyses (TG-DTA), X-ray diffraction analysis (XRD), infrared spectroscopy (FTIR), surface area measurements (BET) and transmission electron microscopy (TEM). Pure and crystalline phases are produced, characterized by very small crystals. MgO nanoparticles appear aggregated into large flocks, although maintaining a plate-like shape of the original hydrate phase; these flocks seem to be constituted by a two-dimensional network consisting of well-developed and roughly spherical and monodispersed nanoparticles, with size less than 10 nm.

ACS Style

Giuliana Taglieri; Valeria Daniele. MgO Nanoparticles Starting from Mg(OH)2 Colloidal Suspensions Synthesized by a Facile and Scalable Process. Advanced Science Letters 2017, 23, 5855 -5858.

AMA Style

Giuliana Taglieri, Valeria Daniele. MgO Nanoparticles Starting from Mg(OH)2 Colloidal Suspensions Synthesized by a Facile and Scalable Process. Advanced Science Letters. 2017; 23 (6):5855-5858.

Chicago/Turabian Style

Giuliana Taglieri; Valeria Daniele. 2017. "MgO Nanoparticles Starting from Mg(OH)2 Colloidal Suspensions Synthesized by a Facile and Scalable Process." Advanced Science Letters 23, no. 6: 5855-5858.

Journal article
Published: 01 May 2017 in Journal of Cultural Heritage
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Giuliana Taglieri; Valeria Daniele; Gianluigi Rosatelli; Stefano Sfarra; Maria Cristina Mascolo; Claudia Mondelli. Eco-compatible protective treatments on an Italian historic mortar (XIV century). Journal of Cultural Heritage 2017, 25, 135 -141.

AMA Style

Giuliana Taglieri, Valeria Daniele, Gianluigi Rosatelli, Stefano Sfarra, Maria Cristina Mascolo, Claudia Mondelli. Eco-compatible protective treatments on an Italian historic mortar (XIV century). Journal of Cultural Heritage. 2017; 25 ():135-141.

Chicago/Turabian Style

Giuliana Taglieri; Valeria Daniele; Gianluigi Rosatelli; Stefano Sfarra; Maria Cristina Mascolo; Claudia Mondelli. 2017. "Eco-compatible protective treatments on an Italian historic mortar (XIV century)." Journal of Cultural Heritage 25, no. : 135-141.

Journal article
Published: 19 October 2015 in Journal of Nanoparticle Research
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Nanoparticles form the fundamental building blocks for many exciting applications in various scientific disciplines. However, the problem of the large-scale synthesis of nanoparticles remains challenging. An original, eco-friendly, single step, and scalable method to produce magnesium hydroxide nanoparticles in aqueous suspensions is here presented. The method, based on an exchange ion process, is extremely simple and rapid (few minutes). It employs cheap or renewable reactants, operates at room temperature and does not require intermediate steps (washings/purifications) to eliminate undesired compounds. Moreover, it is possible to regenerate the exchange material and to reuse it for new operation of synthesis, according to a cyclic procedure, providing potential aptitudes of scalability of nanoparticles production. Some of the synthesis parameters are varied, and structural and morphological features of the produced nanoparticles, after few seconds from the beginning of the synthesis up to the ending time, are investigated by means of several techniques, such as X-ray diffraction (profile fitting and Rietveld refinement), transmission electron microscopy, infrared spectroscopy, thermal analyses, and surface area measurements. In any case, pure and stable suspensions are produced, characterized by crystalline and mesoporous Mg(OH)2 nanoparticles, with lamellar morphology. In particular, the nanolamellas appeared constituted by a superimposition of hexagonally plated and crystalline nanosized precursors (2–3 nm in dimensions), crystallographically oriented.

ACS Style

Giuliana Taglieri; Benito Felice; Valeria Daniele; Fabiola Ferrante. Mg(OH)2 nanoparticles produced at room temperature by an innovative, facile, and scalable synthesis route. Journal of Nanoparticle Research 2015, 17, 1 -13.

AMA Style

Giuliana Taglieri, Benito Felice, Valeria Daniele, Fabiola Ferrante. Mg(OH)2 nanoparticles produced at room temperature by an innovative, facile, and scalable synthesis route. Journal of Nanoparticle Research. 2015; 17 (10):1-13.

Chicago/Turabian Style

Giuliana Taglieri; Benito Felice; Valeria Daniele; Fabiola Ferrante. 2015. "Mg(OH)2 nanoparticles produced at room temperature by an innovative, facile, and scalable synthesis route." Journal of Nanoparticle Research 17, no. 10: 1-13.

Articles
Published: 01 January 2015 in Advances in Nanoparticles
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Ca(OH)2 nanoparticles in hydro-alcoholic dispersion (nanolime) were successfully employed in Cultural Heritage conservation, thanks to the ability to overcome the limiting aspects of traditional lime treatments. Nanolime were currently produced by chemical precipitation process, at high temperature, with long times of synthesis, and after several purification steps to remove undesired secondary phases. In this paper, an innovative, simple and original method for nanolime production was described. The method was based on an ion exchange process between an anionic resin and a calcium chloride aqueous solution, operating at room temperature. A pure Ca(OH)2 nanoparticles suspension can be rapidly obtained after separating the resin from suspension, and any purification step was necessary. The exhausted resins can be regenerated and reused for a cyclic nanolime production. Structural and morphological features of the produced nanolime were preliminarily characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Moreover, XRD measurements allowed estimating nanoparticles reactivity by following their carbonatation process in air, in relation to different water/alcohol ratios and medium or high relative humidity conditions. The produced Ca(OH)2 nanoparticles appeared hexagonally plated, with dimension less than 100 nm and, compared with those obtained by typical wet precipitation method, they proved to be more reactive.

ACS Style

Giuliana Taglieri; Valeria Daniele; Giovanni Del Re; Roberto Volpe. A New and Original Method to Produce Ca(OH)2 Nanoparticles by Using an Anion Exchange Resin. Advances in Nanoparticles 2015, 04, 17 -24.

AMA Style

Giuliana Taglieri, Valeria Daniele, Giovanni Del Re, Roberto Volpe. A New and Original Method to Produce Ca(OH)2 Nanoparticles by Using an Anion Exchange Resin. Advances in Nanoparticles. 2015; 04 (02):17-24.

Chicago/Turabian Style

Giuliana Taglieri; Valeria Daniele; Giovanni Del Re; Roberto Volpe. 2015. "A New and Original Method to Produce Ca(OH)2 Nanoparticles by Using an Anion Exchange Resin." Advances in Nanoparticles 04, no. 02: 17-24.

Journal article
Published: 01 January 2014 in Advances in Materials Physics and Chemistry
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The use of calcium hydroxide nanoparticles (nanolime) in hydro-alcoholic suspensions represents a good enhancement in particular in the conservation of stones and surfaces of interest in Cultural Heritage. In this work we have produced nanolime by using our alternative method of synthesis (based on the use of a surfactant agent in the original solution) and we have studied, for the first time, structural and morphological properties of the synthesized nanoparticles directly in hydro-alcoholic suspension by synchrotron X-ray diffraction technique and transmission electron micro-scope observations. The particles characterization was performed on suspensions synthesized by varying surfactant content in the synthesis procedure and the water/alcohol ratio, too. We have found that only pure and crystalline Ca(OH)2 particles produced during the synthesis procedure and they maintained stably in suspension. These particles were hexagonally plated and regularly shaped with side dimension ranging from 300 to 40 nm or less; they had a platy habit and they presented, particularly with high alcohol content in suspension, a preferred orientation along z-axis.

ACS Style

Giuliana Taglieri; Claudia Mondelli; Valeria Daniele; Emanuela Pusceddu; Giancarlo Scoccia. Synthesis, Textural and Structural Properties of Calcium Hydroxide Nanoparticles in Hydro-Alcoholic Suspension. Advances in Materials Physics and Chemistry 2014, 04, 50 -59.

AMA Style

Giuliana Taglieri, Claudia Mondelli, Valeria Daniele, Emanuela Pusceddu, Giancarlo Scoccia. Synthesis, Textural and Structural Properties of Calcium Hydroxide Nanoparticles in Hydro-Alcoholic Suspension. Advances in Materials Physics and Chemistry. 2014; 04 (03):50-59.

Chicago/Turabian Style

Giuliana Taglieri; Claudia Mondelli; Valeria Daniele; Emanuela Pusceddu; Giancarlo Scoccia. 2014. "Synthesis, Textural and Structural Properties of Calcium Hydroxide Nanoparticles in Hydro-Alcoholic Suspension." Advances in Materials Physics and Chemistry 04, no. 03: 50-59.