Graeme Moad

Dr. Graeme Moad

CSIRO Manufacturing
orcid

Research Focus & Metrics

Academic Career Length

53Years (1974-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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22 July 1998 in Macromolecules
Verified
Journal Article
Closed access
JCJohn Chiefari
John Chiefari
YCY. K. (Bill) Chong
Y. K. (Bill) Chong
FEFrances Ercole
Frances Ercole
JKJulia Krstina
Julia Krstina
JJJustine Jeffery
Justine Jeffery
STSan Thang
San Thang

14 June 2005 in Australian Journal of Chemistry
Verified
Journal Article
Open access
PDF file
Graeme MoadGraeme Moad
Graeme Moad
EREzio Rizzardo
Ezio Rizzardo
STSan Thang
San Thang
This paper presents a review of living radical polymerization achieved with thiocarbonylthio compounds [ZC(=S)SR] by a mechanism of reversible addition–fragmentation chain transfer (RAFT). Since we first introduced the technique in 1998, the number of papers and patents on the RAFT process has increased exponentially as the technique has proved to be one of the most versatile for the provision of polymers of well defined architecture. The factors influencing the effectiveness of RAFT agents and outcome of RAFT polymerization are detailed. With this insight, guidelines are presented on how to conduct RAFT and choose RAFT agents to achieve particular structures. A survey is provided of the current scope and applications of the RAFT process in the synthesis of well defined homo-, gradient, diblock, triblock, and star polymers, as well as more complex architectures including microgels and polymer brushes.

1 March 2008 in Polymer
Verified
Journal Article
Open access
Graeme MoadGraeme Moad
Graeme Moad
EREzio Rizzardo
Ezio Rizzardo
STSan H. Thang
San H. Thang
This review traces the development of addition–fragmentation chain transfer agents and related ring-opening monomers highlighting recent innovation in these areas. The major part of this review deals with reagents that give reversible addition–fragmentation chain transfer (RAFT). These reagents include dithioesters, trithiocarbonates, dithiocarbamates and xanthates. The RAFT process is a versatile method for conferring living characteristics on radical polymerizations providing unprecedented control over molecular weight, molecular weight distribution, composition and architecture. It is suitable for most monomers polymerizable by radical polymerization and is robust under a wide range of reaction conditions. It provides a route to functional polymers, cyclopolymers, gradient copolymers, block polymers and star polymers

7 September 2012 in Australian Journal of Chemistry
Verified
Journal Article
Open access
PDF file
Graeme MoadGraeme Moad
Graeme Moad
EREzio Rizzardo
Ezio Rizzardo
STSan Thang
San Thang
This paper provides a third update to the review of reversible deactivation radical polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC(=S)SR) by a mechanism of reversible addition-fragmentation chain transfer (RAFT) that was published in June 2005 (Aust. J. Chem.2005, 58, 379). The first update was published in November 2006 (Aust. J. Chem.2006, 59, 669) and the second in December 2009 (Aust. J. Chem.2009, 62, 1402). This review cites over 700 publications that appeared during the period mid 2009 to early 2012 covering various aspects of RAFT polymerization which include reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses, and a diverse range of applications. This period has witnessed further significant developments, particularly in the areas of novel RAFT agents, techniques for end-group transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

20 November 2009 in Australian Journal of Chemistry
Verified
Journal Article
Open access
PDF file
Graeme MoadGraeme Moad
Graeme Moad
EREzio Rizzardo
Ezio Rizzardo
STSan Thang
San Thang
This paper provides a second update to the review of reversible deactivation radical polymerization achieved with thiocarbonylthio compounds (ZC(=S)SR) by a mechanism of reversible addition–fragmentation chain transfer (RAFT) that was published in June 2005 (Aust. J. Chem.2005, 58, 379–410). The first update was published in November 2006 (Aust. J. Chem.2006, 59, 669–692). This review cites over 500 papers that appeared during the period mid-2006 to mid-2009 covering various aspects of RAFT polymerization ranging from reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses and a diverse range of applications. Significant developments have occurred, particularly in the areas of novel RAFT agents, techniques for end-group removal and transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

30 October 2006 in Australian Journal of Chemistry
Verified
Journal Article
Open access
PDF file
Graeme MoadGraeme Moad
Graeme Moad
EREzio Rizzardo
Ezio Rizzardo
STSan Thang
San Thang
This paper provides a first update to the review of living radical polymerization achieved with thiocarbonylthio compounds (ZC(=S)SR) by a mechanism of Reversible Addition–Fragmentation chain Transfer (RAFT) published in June 2005. The time since that publication has witnessed an increased rate of publication on the topic with the appearance of well over 200 papers covering various aspects of RAFT polymerization ranging over reagent synthesis and properties, kinetics, and mechanism of polymerization, novel polymer syntheses, and diverse applications.