Current density and pH mapping techniques have been used to characterize the chemical and electrochemical phenomena which occur on the cut edge of galvanized steel. pH variations between 7 and 11 were observed, primarily due to the formation of hydroxyl ions by the cathodic reaction. Zinc‐based corrosion products precipitated in zones of intermediate pH were identified as ZnO and for model samples. The efficiency of these corrosion products as cathodic inhibitors was demonstrated by the absence of cathodic activity at open circuit and a −300 mV negative shift of the onset potential for hydrogen formation in the affected zones. The cathodic current, localized over the steel, was independent of potential, consistent with a diffusion‐limited reduction of oxygen. The anodic current, localized over the zinc, varied with potential, with a Tafel slope of 44 mV/decade for an order of magnitude decrease of potential below open circuit. The addition of to the electrolyte increased the Tafel slope to 63 mV/decade, consistent with a passivating inhibitor on the anode surface. © 2000 The Electrochemical Society. All rights reserved.