As the concept of sustainable pavement gains prominence, a growing number of industrial wastes and recycled materials have been utilized in the pavement industry to preserve natural resources. This study investigates the potential use of waste glass powder-based geopolymer cement as a stabilizing agent in recycled waste glass aggregate (GA) bases. Two recycled materials, waste glass powder (GP) and class F fly ash (FF), were used as the raw materials in the preparation of geopolymer. Virgin aggregate (VA) was replaced by GA at varying replacement ratios as the pavement base materials, and the mechanical behaviors before and after geopolymer stabilization were evaluated. Without stabilization, the incorporation of over 10% GA caused significant detrimental effects on the California bearing ratios (CBR) of base materials, which should be carefully managed in pavement construction. However, all geopolymer stabilized samples showed decent strength properties, indicating the effectiveness of geopolymer stabilization. The use of GA reduced the drying shrinkage of base samples, although the mechanical properties were compromised. During the sample preparation, a higher curing temperature and relative humidity resulted in better mechanical behaviors, and the surface of GA could dissolve in alkaline solution and involve in the geopolymerization at 40°C. The microstructure and minerology of geopolymer stabilizer of base materials were characterized by scanning electron microscopy (SEM) and X-ray defraction (XRD) analyses. This study confirmed the promise of using waste glass-based pavement base materials as the greener substitutes and the potential synergy between waste glass recycling and the pavement industry.