Transition metal nitrides, carbides and borides have a high potential for industrial applications as they not only have a high melting point but are generally harder and less compressible than the pure metals. Here we summarize recent advances in the synthesis of binary transition metal nitrides, carbides and borides focusing on the reaction of the elements at extreme conditions generated within the laser-heated diamond anvil cell. The current knowledge of their structures and high-pressure properties like high-(p; T) stability, compressibility and hardness is described as obtained from experiments.

The crown-ether coordination compounds ZnX₂(18-crown-6), EuX₂(18-crown-6) (X: Cl, Br, I), MnI₂(18-crown-6), Mn₃Cl₆(18-crown-6)₂, Mn₃I₆(18-crown-6)₂, and Mn₂I₄(18-crown-6) are obtained by ionic-liquid-based synthesis. Whereas MX₂(18-crown-6) (M: Zn, Eu) show conventional structural motives, Mn₃Cl₆(18-crown-6)₂, Mn₃I₆(18-crown-6)₂, and Mn₂I₄(18-crown-6) exhibit unusual single MnX₄ tetrahedra coordinated to the crown-ether complex. Surprisingly, some compounds show outstanding photoluminescence. Thus, rare Zn²⁺-based luminescence is observed and unexpectedly efficient for ZnI₂(18-crown-6) with a quantum yield of 54%. Unprecedented quantum yields are also observed for Mn₃I₆(18-crown-6)₂, EuBr₂(18-crown-6), and EuI₂(18-crown-6) with values of 98, 72, and 82%, respectively, which can be rationalized based on the specific structural features. Most remarkable, however, is Mn₂I₄(18-crown-6). Its specific structural features with finite sensitizer–activator couples result in an extremely strong emission with an outstanding quantum yield of 100%. Consistent with its structural features, moreover, anisotropic angle-dependent emission under polarized light and nonlinear optical (NLO) effects occur, including second-harmonic generation (SHG). The title compounds and their optical properties are characterized by single-crystal structure analysis, X-ray powder diffraction, chemical analysis, density functional theory (DFT) calculations, and advanced spectroscopic methods.

In radiographic methods, the attenuation of an incident beam on passing through an object is used to study the internal structure of this object. The availability of techniques to “look inside” large, optically intransparent objects without having to destroy them is obviously appealing and has had a profound impact in many fields, most clearly in medicine, but also in condensed matter studies. The development of radiography started with Röntgen’s discovery of X-rays in 1895, where the absorption of X-rays by bones were demonstrated publicly in 1896 by obtaining a radiograph of a hand. The medical applications were obvious, and already...