Luca Gonsalvi

Dr. Luca Gonsalvi

Institute for the Chemistry of OrganoMetallic Compounds, Sesto Fiorentino, Italy
orcid

Research Focus & Metrics

Academic Career Length

30Years (1997-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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19 February 2010 in Chemical Reviews
Verified
Journal Article
Closed access
Maria CaporaliMaria Caporali
Maria Caporali
Luca GonsalviLuca Gonsalvi
Luca Gonsalvi
Andrea RossinAndrea Rossin
Andrea Rossin
Maurizio PeruzziniMaurizio Peruzzini
Maurizio Peruzzini

1 June 2004 in Coordination Chemistry Reviews
Verified
Journal Article
Closed access
APAndrew D. Phillips
Andrew D. Phillips
Luca GonsalviLuca Gonsalvi
Luca Gonsalvi
Antonio RomerosaAntonio Romerosa
Antonio Romerosa
Francesco  VizzaFrancesco Vizza
Francesco Vizza
Maurizio PeruzziniMaurizio Peruzzini
Maurizio Peruzzini


13 October 2005 in Chemical Society Reviews
Verified
Journal Article
Closed access
PDF file
Maurizio PeruzziniMaurizio Peruzzini
Maurizio Peruzzini
Luca GonsalviLuca Gonsalvi
Luca Gonsalvi
Antonio RomerosaAntonio Romerosa
Antonio Romerosa
The chemistry of phosphorus is nowadays rivalling that of carbon in terms of complexity and diversity. This tutorial review highlights the state-of-the-art in the field of metal-mediated activation and functionalization of white phosphorus. Particular attention is given to an illustration of the coordination abilities of the intact molecule as well as the disaggregating and reaggregating metal-mediated processes resulting in different polyphosphorus ligands from P1 to P12. The metal-promoted P–C and P–H bond forming processes are also reviewed showing that an ecoefficient catalytic protocol for transforming P4 into high value organophosphorus compounds is a concrete possibility for chemical companies. This tutorial review deals with the activation and functionalization of white phosphorus in the coordination sphere of transition metal complexes. Particular attention is given to the coordination abilities of the intact molecule as well as to the disaggregating and reaggregating metal-mediated processes yielding various polyphosphorus ligands from P1 to P12. The metal-promoted processes for P–C and P–H bond formation are also reviewed showing that an ecoefficient catalytic protocol for transforming P4 into high value organophosphorus compounds offers good opportunities for chemical companies.

4 May 2017 in Chemical Science
Verified
Journal Article
Open access
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FBFederica Bertini
Federica Bertini
MGMathias Glatz
Mathias Glatz
NGNikolaus Gorgas
Nikolaus Gorgas
BSBerthold Stöger
Berthold Stöger
Maurizio PeruzziniMaurizio Peruzzini
Maurizio Peruzzini
Luca GonsalviLuca Gonsalvi
Luca Gonsalvi
Mn(i) PNP pincer hydride complexes were shown for the first time to catalyse the hydrogenation of CO2 to formate reaching quantitative yields and high TONs.

13 July 2006 in Organometallics
Verified
Journal Article
Closed access
ADAntoine Dorcier
Antoine Dorcier
WAWee Han Ang
Wee Han Ang
Sandra BolañoSandra Bolaño
Sandra Bolaño
Luca GonsalviLuca Gonsalvi
Luca Gonsalvi
LJLucienne Juillerat-Jeannerat
Lucienne Juillerat-Jeannerat
PDPaul Dyson
Paul Dyson