Monitoring water quality is an essential tool for the control of pollutants and pathogens that can cause damage to the environment and human health. However, water quality analysis is usually performed in laboratory environments, often with the use of high-cost equipment and qualified professionals. With the progress of nanotechnology and the advance in engineering materials, several studies have shown, in recent years, the development of technologies aimed at monitoring water quality, with the ability to reduce the costs of analysis and accelerate the achievement of results for management and decision-making. In this work, a review was carried out on several low-cost developed technologies and applied in situ for water quality monitoring. Thus, new alternative technologies for the main physical (color, temperature, and turbidity), chemical (chlorine, fluorine, phosphorus, metals, nitrogen, dissolved oxygen, pH, and oxidation–reduction potential), and biological (total coliforms, Escherichia coli, algae, and cyanobacteria) water quality parameters were described. It was observed that there has been an increase in the number of publications related to the topic in recent years, mainly since 2012, with 641 studies being published in 2021. The main new technologies developed are based on optical or electrochemical sensors, however, due to the recent development of these technologies, more robust analyses and evaluations in real conditions are essential to guarantee the precision and repeatability of the methods, especially when it is desirable to compare the values with government regulatory standards.

We report the direct proof of parametric amplification in a semiconductor waveguide. Thanks to low propagation losses and high nonlinear efficiency, we amplified an input signal at 2 μm in a selectively oxidized GaAs/AlAs multilayer waveguide through the down conversion of a pump at 1 μm. The 4.5% single-pass gain measured for a 30 mW cw pump is compatible with parametric oscillation, provided that distributed and concentrated waveguide losses are further reduced.

The hydrogen conversion patterns on non-magnetic solids sensitively depend upon the degree of singlet/triplet mixing in the intermediates of the catalytic reaction. Three main ‘symmetry-breaking’ interactions are brought together. In a typical channel, the electron spin–orbit (SO) couplings introduce some magnetic excitations in the non-magnetic solid ground state. The electron spin is exchanged with a molecular one by the electric molecule–solid electron repulsion, mixing the bonding and antibonding states and affecting the molecule rotation. Finally, the magnetic hyperfine contact transfers the electron spin angular momentum to the nuclei. Two families of channels are considered and a simple criterion based on the SO coupling strength is proposed to select the most efficient one. The denoted ‘electronic’ conversion path involves an emission of excitons that propagate and disintegrate in the bulk. In the other denoted ‘nuclear’, the excited electron states are transients of a loop, and the electron system returns to its fundamental ground state. The described model enlarges previous studies by extending the electron basis to charge-transfer states and ‘continui’ of band states, and focuses on the broadening of the antibonding molecular excited state by the solid conduction band that provides efficient tunnelling paths for the hydrogen conversion. After working out the general conversion algebra, the conversion rates of hydrogen on insulating and semiconductor solids are related to a few molecule–solid parameters (gap width, ionization and affinity potentials) and compared with experimental measures.