Inorganic nanomaterials with enzyme-like activity have been attracting much attention due to their low cost, favorable stability, convenient storage, and simple preparation. Herein, Co₃O₄ nanoplates with a uniform nanostructure were prepared by the thermolysis of cobalt hydroxide at different temperatures, and the influence of the annealing temperature on the performance of the mimetic enzyme also was reported for the first time. The results demonstrated that Co₃O₄ nanoplates obtained at an annealing temperature of 200 °C possessed strong oxidase activity and efficiently catalyzed the oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB) without the addition of hydrogen peroxide to generate the blue color product ox-TMB. Once the annealing temperature was increased to 500 °C and 800 °C, the oxidase activity of Co₃O₄ decreased rapidly, and was even inactivated. This might be attributed to the relatively large specific surface area of Co₃O₄ annealed at 200 °C. Besides this, based on the TMB-Co₃O₄ nanoplate system, a colorimetric analysis method was developed to detect dopamine with a limit of 0.82 μmol/L in a linear range from 1.6 μmol/L to 20 μmol/L.

A method of sequential spraying of polyvinyl alcohol with carbon quantum dots (PVA@CDs) aqueous suspension and SiO₂ aqueous suspension is proposed to rapidly prepare multicolor dual-mode anti-counterfeiting labels. With the optimization of the concentration (15%) of colloidal microspheres in the SiO₂ aqueous suspension as well as the spraying process parameters (spray distance of 10 cm, spray duration of 3 s, and assembly temperature of 20 °C), different-sized SiO₂ microspheres (168 nm, 228 nm, and 263 nm) were utilized to rapidly assemble red, green, and blue photonic crystals. Furthermore, the tunable fluorescence emission of carbon quantum dots endows the labels with yellow, green, and blue fluorescence. The constructed dual-mode labeling was used to develop an anti-counterfeiting code with dual-channel information storage capabilities and also to create dual-mode multicolor anti-counterfeiting labels on various packaging substrates. This work provides a novel solution for anti-counterfeiting packaging and information storage.

The detection of dopamine is of great significance for human health. Herein, Pd nanoparticles were loaded on Cu nanoplates (Pd/Cu NPTs) by a novel liquid phase reduction method. A novel dopamine (DA) electrochemical sensor based on the Pd NPs/Cu/glass carbon electrode (Pd/Cu NPTs/GCE) was constructed. This sensor showed a wide linear range of 0.047 mM to 1.122 mM and a low limit of detection (LOD) of 0.1045 μM (S/N = 3) for DA. The improved performance of this sensor is attributed to the obtained tiny Pd nanoparticles which increase the catalytic active sites and electrochemical active surface areas (ECSAs). Moreover, the larger surface area of two–dimensional Cu nanoplates can load more Pd nanoparticles, which is another reason to improve performance. The Pd/Cu NPTs/GCE sensor also showed a good reproducibility, stability, and excellent anti–interference ability.

In recent years, cadmium sulfide (CdS) has been widely investigated due to its excellent photocatalytic performance. However, its practical application in pollutant treatment is limited by its narrow photoresponse range and susceptibility to photocorrosion. Herein, we design a unique four-layer core–shell structure NaYF₄:Yb³⁺,Er³⁺@NaYF₄@CdS@Au (CSNPs@CdS@Au), with an inert NaYF₄ shell coating on NaYF₄:Yb³⁺,Er³⁺ (CNPs) to form NaYF₄:Yb³⁺,Er³⁺@NaYF₄ (CSNPs) and CdS depositing on CSNPs (CSNPs@CdS); Au nanoparticles are loaded on CdS (CSNPs@CdS@Au). Compared with CdS (9.81%), CSNPs (5.0%), CSNPs/CdS (6.9%), and CSNPs@CdS (81.0%), CSNPs@CdS@Au degrades 97.7% Rhodamine B (RhB) within 15 min, exhibiting superior photocatalytic performance, attributable to two key factors: (1) the NaYF₄ inert shell encapsulation amplifies upconversion (UC) luminescence intensity by suppressing surface quenching; and (2) the electron transfer between Au nanoparticles and CdS effectively promotes spatial separation of photogenerated charge carriers and increases reactive active sites. Additionally, after five degradation cycles, CSNPs@CdS@Au still maintains a 93.25% degradation rate for RhB, confirming its excellent stability. This remarkable stability is attributed to the uniquely designed multilayer core–shell architecture, which significantly enhances structural integrity through physical isolation effects. This study establishes a material preparation strategy for efficient photocatalytic pollutant degradation.

Dopamine (DA) is an important catecholamine neurotransmitter in human metabolism that is associated with various critical diseases. Accurate detection of DA is of great significance for the diagnosis of these diseases. Here, we constructed a sensitive electrochemical sensor, S, N co-doped multi-walled carbon nanotubes (MWCNTs-N-S) loaded with Pd nanoparticles (Pd/MWCNTs-N-S). The linear range of the Pd/MWCNTs-N-S sensor is from 0.0001 to 2.0 mM, and the limit of detection (LOD) is 4.37 nM (S/N = 3) for DA detection. The improved detection performance of this sensor is attributed to the optimization of MWCNTs carrier structure and surface properties by N, S co-doping, as well as the significant improvement of electrochemical surface area (ECSA) for the commendable dispersion of Pd nanoparticles (3.79 nm). What is more, the Pd/MWCNTs-N-S sensor also exhibits good reproducibility, stability, and anti-interference ability. Overall, this study presents a straightforward strategy for the potential applications of Pd-based double co-doped MWCNTs sensors.