The design of heat exchangers may change dramatically through the use of additive manufacturing (AM). Additive manufacturing, colloquially known as 3D printing, enables the production of monolithic metal bodies, devoid of contact resistance. The small volume of the exchanger, its lightness of weight, and the reduction of its production costs, compared to conventional methods, make the production of heat exchangers by AM methods conventional technologies. The review study presents a new look at the TPMS as a promising type of developed surface that can be used in the area of heat transfer. (Thus far, the only attractive option. The most important feature of additive manufacturing is the ability to print the geometry of theoretically any topography. Such a topography can be a minimal surface or its extended version—triply periodic minimal surface (TPMS). It was practically impossible to manufacture a TPMS-based heat exchanger with the method of producing a TPMS.) The issues related to the methods of additive manufacturing of metal products and the cycle of object preparation for printing were discussed, and the available publications presenting the results of CFD simulations and experimental tests of heat exchangers containing a TPMS in their construction were widely discussed. It has been noticed that the study of thermal-flow heat transfer with the use of TPMSs is a new area of research, and the number of publications in this field is very limited. The few data (mainly CFD simulations) show that the use of TPMSs causes, on the one hand, a several-fold increase in the number of Nu, and on the other hand, an increase in flow resistance. The use of TPMSs in heat exchangers can reduce their size by 60%. It is concluded that research should be carried out in order to optimize the size of the TPMS structure and its porosity so that the gains from the improved heat transfer compensate for the energy expenditure on the transport of the working fluid. It has been noticed that among the numerous types of TPMSs available for the construction of heat exchangers, practically, four types have been used thus far: primitive, gyroid, I-WP, and diamond. At the moment, the diamond structure seems to be the most promising in terms of its use in the construction of heat exchangers and heat sinks. It is required to conduct experimental research to verify the results of the CFD simulation.
In the paper, the Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS) results of the surface layer formed on pure titanium after plasma electrolytic oxidation (micro arc oxidation) at the voltage of 450 V are shown. As an electrolyte, the mixture of copper nitrate Cu(NO3)2 (10–600 g/L) in concentrated phosphoric acid H3PO4 (98 g/mol) was used. The thickness of the obtained porous surface layer equals about 10 μm, and it consists mainly of titanium phosphates and oxygen with embedded copper ions as a bactericidal agent. The maximum percent of copper in the PEO surface layer was equal to 12.2 ± 0.7 wt % (7.6 ± 0.5 at %), which is the best result that the authors obtained. The top surface layer of all obtained plasma electrolytic oxidation (PEO) coatings consisted most likely mainly of Ti3(PO4)4∙nH3PO4 and Cu3(PO4)2∙nH3PO4 with a small addition of CuP2, CuO and Cu2O.
The polarisation characteristics of the electropolishing process in a magnetic field (MEP – magnetoelectropolishing), in comparison with those obtained under standard/conventional process (EP) conditions, have been obtained. The occurrence of an EP plateau has been observed in view of the optimization of MEP process. Up-to-date stainless steel surface studies always indicated some amount of free-metal atoms apart from the detected oxides and hydroxides. Such a morphology of the surface film usually affects the thermodynamic stability and corrosion resistance of surface oxide layer and is one of the most important features of stainless steels. With this new MEP process we can improve metal surface properties by making the stainless steel more resistant to halides encountered in a variety of environments. Furthermore, in this paper the stainless steel surface film study results have been presented. The results of the corrosion research carried out by the authors on the behaviour of the most commonly used material - medical grade AISI 316L stainless steel both in Ringer’s body fluid and in aqueous 3% NaCl solution have been investigated and presented earlier elsewhere, though some of these results, concerning the EIS Nyquist plots and polarization curves are also revealed herein. In this paper an attempt to explain this peculiar performance of 316L stainless steel has been undertaken. The SEM studies, Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) were performed on 316L samples after three treatments: MP – abrasive polishing (800 grit size), EP – conventional electrolytic polishing, and MEP – magnetoelectropolishing. It has been found that the proposed magnetoelectropolishing (MEP) process considerably modifies the morphology and the composition of the surface film, thus leading to improved corrosion resistance of the studied 316L SS.