Antonella Esposito

Dr. Antonella Esposito

Groupe de Physique des Matériaux (GPM), Université de Rouen Normandie, Rouen, Normandie, France
orcid

Research Focus & Metrics

Academic Career Length

22Years (2005-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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22 June 2016 in Macromolecules
Verified
Journal Article
Closed access
Antonella EspositoAntonella Esposito
Antonella Esposito
NDNicolas Delpouve
Nicolas Delpouve
VCValerio Causin
Valerio Causin
ADAlexandre Dhotel
Alexandre Dhotel
Laurent DelbreilhLaurent Delbreilh
Laurent Delbreilh
EDeric Dargent
eric Dargent

3 May 2024 in Green Chemistry
Verified
Journal Article
Open access
PDF file
Mattia AnnatelliMattia Annatelli
Mattia Annatelli
JSJulián E. Sánchez-Velandia
Julián E. Sánchez-Velandia
GMGiovanna Mazzi
Giovanna Mazzi
SPSimão V. Pandeirada
Simão V. Pandeirada
Dimitrios A. GiannakoudakisDimitrios A. Giannakoudakis
Dimitrios A. Giannakoudakis
Fabio AricòFabio Aricò
Fabio Aricò
This review represents an overview of the status quo of the furan-based monomers and related bio-based polymers, highlighting key challenges for scaling from lab to pre-industrial levels.

23 February 2018 in Macromolecules
Verified
Journal Article
Closed access
ABAurélie Bourdet
Aurélie Bourdet
Antonella EspositoAntonella Esposito
Antonella Esposito
STShanmugam Thiyagarajan
Shanmugam Thiyagarajan
Laurent DelbreilhLaurent Delbreilh
Laurent Delbreilh
FAFrederic Affouard
Frederic Affouard
EDEric Dargent
Eric Dargent

5 June 2012 in Journal of Applied Polymer Science
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Journal Article
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JPJorge Arturo Soto Puente
Jorge Arturo Soto Puente
Antonella EspositoAntonella Esposito
Antonella Esposito
FCFrédéric Chivrac
Frédéric Chivrac
EDeric Dargent
eric Dargent

21 October 2019 in ACS Sustainable Chemistry & Engineering
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Journal Article
Open access
STShanmugam Thiyagarajan
Shanmugam Thiyagarajan
MMMichael A. Meijlink
Michael A. Meijlink
ABAurélie Bourdet
Aurélie Bourdet
WVWillem Vogelzang
Willem Vogelzang
RKRutger J. I. Knoop
Rutger J. I. Knoop
JHJacco van Haveren
Jacco van Haveren
Recent works highlighted how interesting are the properties of furan-based polyesters. Most of the attention has been focused on the homopolyester obtained with 2,5-furandicarboxylic acid and ethylene glycol, but other possibilities exist which could help tuning the final properties by carefully selecting the nature and proportion of the initial building blocks. This work reports the synthesis and properties (thermal stability, activation energy for thermal decomposition, glass transition temperature and aptitude to crystallize) of three series of polyesters obtained by combining various amounts of two isomers of furandicarboxylic acid with different linear aliphatic diols, such as ethylene glycol, 1,3-propanediol, and 1,4-butanediol. This approach provided homopolymers and copolymers with high molecular weights, good thermal stability, broad processing windows and a thermal behaviour that can be tuned both in terms of glass transition temperature and crystallinity. In most cases, the mixtures of 2,5- and 2,4-isomers obtained during the Henkel disproportionation reaction can be directly used to synthetize furan-based copolyesters with good properties, without the down-stream processing typically performed to separate the isomers prior to polymerization, which may considerably reduce the time and costs for biomass valorization.

19 January 2018 in Fibers
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Journal Article
Open access
PDF file
QVQuentin Viel
Quentin Viel
Antonella EspositoAntonella Esposito
Antonella Esposito
JSJean-Marc Saiter
Jean-Marc Saiter
Carlo SantulliCarlo Santulli
Carlo Santulli
JTJoseph A. Turner
Joseph A. Turner
In this work, the apparent shear strength at the interface between a bamboo fiber and the surrounding poly(lactic acid) (PLA) matrix is quantified. A method for processing pull-out test samples within a controlled embedded length is proposed and the details of the test procedure are presented, along with a critical discussion of the results. Two series of samples are considered: untreated and mercerized bamboo fibers from the same batch, embedded in the same polyester matrix. Electron and optical microscopy are used to observe the fiber–matrix interface before and after the test, and to identify the failure mode of each sample, especially as regards the occurrence of fibrillation in the fiber bundles. The values of apparent interfacial shear strength are calculated only for regular fibers successfully pulled out from the matrix, and reported with their statistical variations. Mercerization, whose efficiency was proven by Fourier transform infrared (FTIR) spectroscopy, did not appear though to improve the quality of the interface (τapp = 7.0 ± 3.1 MPa for untreated fibers and τapp = 5.3 ± 2.4 MPa for treated fibers).