Metal ions or clusters that have been bonded with organic linkers to create one- or more-dimensional structures are referred to as metal-organic frameworks (MOFs). Reticular synthesis also forms MOFs with properly designated components that can result in crystals with high porosities and great chemical and thermal stability. Due to the wider surface area, huge pore size, crystalline nature, and tunability, numerous MOFs have been shown to be potential candidates in various fields like gas storage and delivery, energy storage, catalysis, and chemical/biosensing. This study provides a quick overview of the current MOF synthesis techniques in order to familiarize newcomers in the chemical sciences field with the fast-growing MOF research. Beginning with the classification and nomenclature of MOFs, synthesis approaches of MOFs have been demonstrated. We also emphasize the potential applications of MOFs in numerous fields such as gas storage, drug delivery, rechargeable batteries, supercapacitors, and separation membranes. Lastly, the future scope is discussed along with prospective opportunities for the synthesis and application of nano-MOFs, which will help promote their uses in multidisciplinary research.
1 May 2014 in Materials Science and Engineering: C
We have synthesized biocompatible fluorescent carbon dots (CDs) by a one-step hydrothermal method using Solanum tuberosum (potato) as a raw material. The CDs were characterized by UV-visible, fluorescence, Fourier transform infrared (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), dynamic light scattering (DLS) and high-resolution transmission electron microscopic (HR-TEM) techniques. We found that the carbonization of potato at ∼170 °C for 12 h produces highly fluorescent CDs of 0.2–2.2 nm size. The synthesized CDs are well dispersed in water and exhibited strong blue and bright blue emissions under UV illumination (λex = 302, 365 nm). The CDs showed a strong emission peak at 455 nm at an excitation wavelength of 374 nm. The CDs acted as fluorescent probes for multicolor (blue, green and red) imaging of HeLa cells and the CDs did not induce cell death, which indicates that the CDs are biocompatible and nontoxic to HeLa cells. Therefore, the CDs can be used as probes for cell-imaging applications in vitro and in vivo.
1 June 2018 in Advances in Colloid and Interface Science