Mechanically adaptive electronic skins (e-skins) emulate tactition and thermoception by cutaneous mechanoreceptors and thermoreceptors in human skin, respectively. When exposed to multiple stimuli including mechanical and thermal stimuli, discerning and quantifying precise sensing signals from sensors embedded in e-skins are critical. In addition, different detection modes for mechanical stimuli, rapidly adapting (RA) and slowly adapting (SA) mechanoreceptors in human skin are simultaneously required. Herein, we demonstrate the fabrication of a highly sensitive, pressure-responsive organic field-effect transistor (OFET) array enabling both RA- and SA- mode detection by adopting easily deformable, mechano-electrically coupled, microstructured ferroelectric gate dielectrics and an organic semiconductor channel. We also demonstrate that the OFET array can separate out thermal stimuli for thermoreception during quantification of SA-type static pressure, by decoupling the input signals of pressure and temperature. Specifically, we adopt piezoelectric-pyroelectric coupling of highly crystalline, microstructured poly(vinylidene fluoride-trifluoroethylene) gate dielectric in OFETs with stimuli to allow monitoring of RA- and SA-mode responses to dynamic and static forcing conditions, respectively. This approach enables us to apply the sensor array to e-skins for bio-monitoring of humans and robotics.
In recent years, the use of functional textiles has attained attention due to their advantageous health and safety issues. Therefore, this study investigated the flame retardancy on cotton (COT) and polyester-cotton (PC) fabrics treated with different concentrations of silica and zinc nanoparticles through a sol-gel finishing technique. FTIR, SEM, and TGA were conducted for the characterization of coated fabric samples. The FTIR and SEM of Pristine and Treated Cotton and PC fabrics illustrated that the SiO2 (silica dioxide) and ZnO (Zinc oxide) nanoparticles were homogeneously attached to the fiber surface, which contributed to the enhancement of the thermal stability. The starting thermal degradation improved from 320 to 350 °C and maximum degradation was observed from 400 to 428 °C for the COT-2 cotton substrate. However, the initial thermal degradation improved from 310 to 319 °C and the highest degradation from 500 to 524 °C for the PC substrate PC-2. The outcomes revealed that the silica has a greater influence on the thermal properties of COT and PC fabric samples. Additionally, the tensile strength and flexural rigidity of the treated samples were improved with an insignificant decrease in air permeability.