An accurate prediction of water quality (WQ) related parameters is considered as pivotal decisive tool in sustainable water resources management. In this study, five different ensemble machine learning (ML) models including Quantile regression forest (QRF), Random Forest (RF), radial support vector machine (SVM), Stochastic Gradient Boosting (GBM) and Gradient Boosting Machines (GBM_H2O) were developed to predict the monthly biochemical oxygen demand (BOD) values of the Euphrates River, Iraq. For this aim, monthly average data of water temperature (T), Turbidity, pH, Electrical Conductivity (EC), Alkalinity (Alk), Calcium (Ca), chemical oxygen demand (COD), Sulfate (SO ₄ ), total dissolved solids (TDS), total suspended solids (TSS), and BOD measured for ten years period were used in this study. The performances of these standalone models were compared with integrative models developed by coupling the applied ML models with two different feature extraction algorithms i.e., Genetic Algorithm (GA) and Principal Components Analysis (PCA). The reliability of the applied models was evaluated based on the statistical performance criteria of determination coefficient (R ² ), root mean square error (RMSE), mean absolute error (MAE), Nash-Sutcliffe model efficiency coefficient (NSE), Willmott index (d), and percent bias (PBIAS). Results showed that among the developed models, QRF model attained the superior performance. The performance of the evaluated models presented in this study proved that the developed integrative PCA-QRF model presented much better performance compared with the standalone ones and with those integrated with GA. The statistical criteria of R ² , RMSE, MAE, NSE, d, and PBIAS of PCA-QRF were 0.94, 0.12, 0.05, 0.93, 0.98, and 0.3, respectively.

Total dissolved solids (TDS) and electrical conductivity (EC) are important parameters in determining water quality for drinking and agricultural water, since they are directly associated to the concentration of salt in water and, hence, high values of these parameters cause low water quality indices. In addition, they play a significant role in hydrous life, effective water resources management and health studies. Thus, it is of critical importance to identify the optimum modeling method that would be capable to capture the behavior of these parameters. The aim of this study was to assess the ability of using three different models of artificial intelligence techniques: Adaptive neural based fuzzy inference system (ANFIS), artificial neural networks (ANNs) and Multiple Regression Model (MLR) to predict and estimate TDS and EC in Abu-Ziriq marsh south of Iraq. As so, eighty four monthly TDS and EC values collected from 2009 to 2018 were used in the evaluation. The collected data was randomly split into 75% for training and 25% for testing. The most effective input parameters to model TDS and EC were determined based on cross-correlation test. The three performance criteria: correlation coefficient (CC), root mean square error (RMSE) and Nash–Sutcliffe efficiency coefficient (NSE) were used to evaluate the performance of the developed models. It was found that nitrate (NO₃), calcium (Ca⁺²), magnesium (Mg⁺²), total hardness (T.H), sulfate (SO₄) and chloride (Cl⁻¹) are the most influential inputs on TDS. While calcium (Ca⁺²), magnesium (Mg⁺²), total hardness (T.H), sulfate (SO₄) and chloride (Cl⁻¹) are the most effective on EC. The comparison of the results showed that the three models can satisfactorily estimate the total dissolved solids and electrical conductivity, but ANFIS model outperformed the ANN and MLR models in the three performance criteria: RMSE, CC and NSE during the calibration and validation periods in modeling the two water quality parameters. ANFIS is recommended to be used as a predictive model for TDS and EC in the Iraqi marshes.

Exact estimation of evaporation rates is very important in a proper planning and efficient operation of water resources projects and agricultural activities. Evaporation is affected by many driving forces characterized by nonlinearity, non-stationary, and stochasticity. Such factors clearly hinder setting up rigorous predictive models. This study evaluates the predictability of coupling the additive regression model (AR) with four ensemble machine-learning algorithms—random Subspace (RSS), M5 pruned (M5P), reduced error pruning tree (REPTree), and bagging for estimating pan evaporation rates. Meteorological data encompass maximum temperature, minimum temperature, mean temperature, relative humidity, and wind speed from three different agroclimatic stations in Iraq (i.e., Baghdad, Mosul, and Basrah) were utilized as predictor parameters. The regression model in addition to the sensitivity analysis was employed to identify the best-input combinations for the evaluated methods. It was demonstrated that the AR-M5P estimated the evaporation with higher accuracy than others when combining wind speed, relative humidity, and the minimum and mean temperatures as input parameters. The AR-M5P model provided the best performance indicators, i.e., MAE = 33.82, RMSE = 45.05, RAE = 24.75, RRSE = 28.50, and r = 0.972 for Baghdad; MAE = 25.82, RMSE = 35.95, RAE = 23.75, RRSE = 29.64, and r = 0.956 for Mosul station, respectively. The outcomes of this study proved the superior performance of the hybridized methods in addressing such intricate hydrological relationships and hence could be employed for other environmental problems.