Plastics are widely used in every part of life. Microplastics (MPs) are classified as emerging contaminants in nature. Yet, microplastic transportation parameters in groundwater are not characterized well. In this study, microplastic transport in saturated homogeneous media was investigated. For this purpose, one-dimensional column tests were performed using the fluorescent and microplastic tracers to figure out the hydrodynamic conditions for the microplastic transport. Large silica, small silica, sand, and coarse gravel were the tested media. The hydrodynamic transport parameters were calculated by inverse solution methodology using the experimental and the analytical solution results. Only the coarse gravel medium with a minimum 1 mm and maximum 20 mm (5 mm of median) pore sizes and kinematic porosity 40.2% were found to be suitable for the transport of the used polyethylene (PE) whose particle size was between 200 and 500 µm. It is not possible to transport PE particles of selected size from fine-grained media. Transportation occurred in coarse-grained media such as coarse gravel. The calculated dispersivity values for the coarse gravel were 2.58 and 3.02 cm by using fluorescent and PE tracers, respectively. The experiments showed that the used PE particles cannot be transported if the mean flow velocity is lower than 2.02 cm/min in the coarse gravel medium. The microplastic accumulation might be an issue for an actual aquifer rather than the transportation of it considering the actual groundwater flow velocity is generally much lower.

Karst aquifers have been an important research topic for hydrologists for years. Due to their high storage capacity, karst aquifers are an important source of water for the environment. On the other hand, it is safety-critical because of its role in floods. Mugla Karst Aquifer (SW, Turkey) is the only major water-bearing formation in the close environs of Mugla city. Flooding in the wet season occurs every year in the recharge plains. The aquifer discharges by the seaside springs in the Akyaka district which is the main touristic point of interest in the area. Non-porous irregular internal structures make the karsts more difficult to study. Therefore, many different methodologies have been developed over the years. In this study, unit hydrograph analysis, correlation and spectral analyses were applied on the rainfall and spring water-level time series data. Although advanced karst formations can be seen on the surface like the sinkholes, it has been revealed that the interior structure is not highly karstified. 100–130 days of regulation time was found. This shows that the Mugla Karst has quite inertial behavior. Yet, the storage of the aquifer system is quite high, and the late infiltration effect caused by alluvium plains was detected. This characterization of the hydrodynamic properties of the Mugla karst system represents an important step to consider the rational exploitation of its water resources in the near future.

Hydraulic head and groundwater 111 Cd content interpolations using empirical Bayesian kriging (EBK) and geo-adaptive neuro-fuzzy inference system (geo-ANFIS)

The electrical resistivity tomography method has been widely used in geophysics for many purposes such as determining geological structures, water movement, saltwater intrusion, and tectonic regime modeling. Karstic springs are important for water basin management since the karst systems are highly complex and vulnerable to exploitation and contamination. An accurate geophysical model of the subsurface is needed to reveal the spring structure. In this study, several karst springs in the Gökova Bay (SW, Turkey) were investigated to create a 3D subsurface model of the nearby karstic cavities utilizing electrical resistivity measurements. For this approach, 2D resistivity profiles were acquired and interpreted. Stratigraphically, colluvium, conglomerate, and dolomitic-limestone units were located in the field. The resistivity values of these formations were determined considering both the literature and field survey. Then, 2D profiles were interpolated to create a 3D resistivity model of the study area. Medium-large sized cavities were identified as well as their locations relative to the springs. The measured resistivities were also correlated with the corresponding geological units. The results were then used to construct a 3D model that aids to reveal the cavity geometry in the subsurface. Additionally, several faults are detected and their effect on the cavities is interpreted.

Under varying flow rate conditions, the transport and retention of polydisperse microplastics (MPls), with an average particle size of 16 ± 6 µm, were investigated in saturated porous media. First-order reversible and irreversible kinetic sorption models were used to describe the sorption kinetics. Sensitivity analyses provided insight into the effects of each sorption parameter. Both numerical modeling and experimental measurements were utilized to evaluate the retention rates of sand filters. The influence of flow rate on sorption was reflected in variations in the distribution coefficient (K_d), the mass transfer coefficient (β), and the irreversible sorption rate (K₁). Lower flow rates were associated with higher K_d and β values, indicating increased sorption and reduced mass transfer rates. An increase in K_d resulted in a more gradual sorption process, with a decrease in peak concentration, whereas changes in β had a comparatively smaller impact on sorption rate and peak concentration. Lower K₁ values were linked to higher peak concentrations and decreased retention efficiency. Numerical modeling revealed retention rates of 28 ± 1% at a flow rate of 31 mL min⁻¹ and 17 ± 1% at 65 mL min⁻¹. The introduction of MPls into saturated sand environments modifies the transport dynamics within the medium. Consequently, these alterations affect the hydrological characteristics of porous media, impacting groundwater quality and agricultural output. The mean absolute error (MAE) of 6% between the modeled and observed retention rates indicated a high level of accuracy. This study underscores the importance of examining retention efficiency and the accuracy of numerical models in understanding MPl transport in porous media.