Up to now, fiber-reinforced composites with thermoplastic matrix have seen limited fields of use in the structural scope due to their high viscosity in the molten state, which results in poor impregnability of the reinforcement, leading to mechanical properties of the finished product that are not comparable to those of thermosets. Although the latter still dominate the various sectors of automotive, aerospace, transportation and construction, new applications involving the production of thermoplastic composites are growing rapidly, offering new approaches to the solution of this problem. The aim of this work is to study and evaluate the state of the art on the manufacturing processes of thermoplastic matrix composite, analyzing the parameters that come into play and that most influence the process and material performance. The advantages of film stacking and powder impregnation techniques are contrasted by the versatility of hybrid fabrics and, at the same time, parameters such as pressure and temperature must be carefully considered. A description of different thermoplastic composite processes such as powder impregnation, film stacking molding, hybrid woven fabric, hybrid yarn and products follows, which represent the current possibilities to move from a thermosetting matrix composite to a thermoplastic one, upon which the concept of sustainability is based. This article wants to present an overview of research that has been done in manufacturing thermoplastic reinforced composites and will serve as a baseline and aid for further research and development efforts.

Additive manufacturing is one of the main topics of the fourth industrial revolution; defined as Industry 4.0. This technology offers several advantages related to the construction and architectural sectors; such as economic; environmental; social; and engineering benefits. The usage of concrete in additive technologies allows the development of innovative applications and complexity design in the world of construction such as buildings; housing modules; bridges; and urban and domestic furniture elements. The aim of this review was to show in detail a general panoramic of extrusion-based additive processes in the construction sector; the main advantages of using additive manufacturing with the respect to traditional manufacturing; the fundamental requirements of 3D printable material (fresh and hardened properties), and state-of-the-art aesthetic and architectural projects with functional properties.

In the last ten years, the Portland cement industry has received wide criticism due to its related high embodied energy and carbon dioxide footprint. Recently, numerous “clean” strategies and solutions were developed. Among these, geopolymer technology is gaining growing interest as a functional way to design more eco-friendly construction materials and for waste management issues suffered by various industries. Previous research has highlighted the attractive engineering properties of geopolymeric materials, especially in terms of mechanical properties and durability, resulting in even higher performance than ordinary concrete. This review provides a comprehensive analysis of current state-of-the-art and implementations on geopolymer concrete materials, investigating how the key process factors (such as raw materials, synthesis regime, alkali concentration, water dosage, and reinforcement fillers) affect the rheological, microstructural, durability, and mechanical properties. Finally, the paper elucidates some noteworthy aspects for future research development: innovative geopolymer-based formulations (including alkali-activated blends for additive manufacturing and thermo-acoustic insulating cellular compounds), concrete applications successfully scaled in the civil-architectural fields, and the perspective directions of geopolymer technology in terms of commercialization and large-scale diffusion.

In the direction of reducing greenhouse emissions and energy consumption related to the activities of the cement and concrete industry, the increasingly popular concept of eco-sustainability is leading to the development and optimization of new technologies and low impact construction materials. In this respect, geopolymers are spreading more and more in the cementitious materials field, exhibiting technological properties that are highly competitive to conventional Portland concrete mixes. In this paper, the mix design, mechanical properties, microstructural features, and mineralogical properties of geopolymer mixes are discussed, investigating the influence of the main synthesis parameters (curing regime, type of precursors, activator molarity, mix design) on the performance of the final product. Moreover, recent developments of geopolymer technology based on the integration of functional nanofillers are reported. The novelty of the manuscript is to provide a detailed collection of past and recent comparative studies between geopolymers and ordinary Portland concrete mixes in terms of strength properties, durability, fire resistance, and environmental impact by LCA analysis, intending to evaluate the advantages and limitations of this technology and direct research towards a targeted optimization of the material.

3D printing technologies of construction materials are gaining ground in the building industry. As well documented in the literature, these advanced manufacturing methodologies aim to reduce work-related injuries and materials waste, enhancing architectural flexibility which would enable more sophisticated designs for engineering and aesthetic purposes. In this framework, the development of functional and eco-sustainable printable materials represents an extremely attractive challenge for research, promoting digital fabrication to reach its maximum cost-effective and technological potentials. The use of recycled tire rubber particles in 3D printable Portland-based compounds is an exclusive contribution in this field. This line of research aims to integrate the well-known engineering performances of rubber-cement materials with the advanced peculiarities of additive manufacturing methodologies. As an innovative contribution, the authors propose here a detailed study on the possible relationship between rubber particle size and technological properties of the 3D printable mix. Specifically, two groups of continuous size grading polymer aggregates (0-1 mm rubber powder and 1-3 mm rubber granules as fine and coarse fractions, respectively) were analyzed in terms of impact on rheology, print quality, microstructure, mechanical properties, and acoustic insulation performance. Concerning the print quality, rubber aggregates altered the fluidity of the fresh mix, improving the adhesion between the printed layers and therefore enhancing the mechanical isotropy in the post-hardening sample. A remarkable influence of the rubber gradation on the compounds' behaviour was found in hardened properties. By comparing the rubberized compounds, the fine polymer fraction shows greater interfacial cohesion with the cement paste. However, more significant mechanical strength loss was found due to a greater reduction in density and increased porosity degree. On the other hand, mortars doped with larger rubber particles tend to have a higher unit weight, finest pore distribution, minor mechanical strength drop, and higher ductility but worse interface binding with the matrix. Regarding the acoustic insulation properties, a proper balance between rubber powder and granules in the mixes allows to obtain comparable/superior performance compared to plain mortar but the effect of the aggregate size is strongly dependent on the sound frequency range investigated. Future findings revolve around applicability studies of these formulations in civil and architectural fields, benefiting from the design flexibility of 3D printing. Doi: 10.28991/cej-2021-03091701 Full Text: PDF