Svetlana V. Amosova

Prof. Dr. Svetlana V. Amosova

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Division of the Russian Academy of Sciences
orcid

Research Focus & Metrics

Academic Career Length

43Years (1984-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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30 May 2018 in Russian Chemical Reviews
Verified
Journal Article
Closed access
GAG A Abakumov
G A Abakumov
APA V Piskunov
A V Piskunov
VCV K Cherkasov
V K Cherkasov
IFI L Fedushkin
I L Fedushkin
VAV P Ananikov
V P Ananikov
MAM V Andreev
M V Andreev

5 May 2011 in The Journal of Organic Chemistry
Verified
Journal Article
Closed access
AAAdrian A. Accurso
Adrian A. Accurso
SCSo-Hye Cho
So-Hye Cho
AAAsmarah Amin
Asmarah Amin
VPVladimir A. Potapov
Vladimir A. Potapov
SASvetlana V. Amosova
Svetlana V. Amosova
MFM. G. Finn
M. G. Finn

4 November 2015 in Current Organic Chemistry
Verified
Journal Article
Closed access
PDF file
Vladimir A. PotapovVladimir A. Potapov
Vladimir A. Potapov
Maria V. MusalovaMaria V. Musalova
Maria V. Musalova
SASvetlana V. Amosova
Svetlana V. Amosova
The review describes reactions of selenium and tellurium halides with alkenes and alkynes leading to useful organochalcogen compounds with main focus on the literature of last decade. The reactions of selenium dichloride and dibromide - new electrophilic reagents, which have been recently introduced in organic synthesis, along with the reactions of "classic" electrophilic reagents selenium and tellurium tetrahalides are discussed. The application of selenium dihalides in the last decade allows carrying out a series of previously unknown efficient reactions, which provide a variety of useful products including novel heterocyclic compounds. As a rule, reactions of selenium dihalides with alkynes proceed as anti-addition to give anti-Markovnikov products, whereas reactions of tellurium tetrahalides with alkynes occur in most cases as syn-addition to give Markovnikov products. However, there are exceptions to the rules, which are discussed in the review. For example, reactions of tellurium tetrahalides with acetylene proceed as anti-addition. Addition of selenium dihalides to alkenes gives Markovnikov products or a mixture of Markovnikov and anti-Markovnikov products. The formation of Markovnikov thermodynamic products in this case is the result of rearrangement of initial formed anti-Markovnikov kinetic products. The trends of reactions of selenium dihalides with alkenes and alkynes can be rationalized by assuming the formation of seleniranium and selenirenium intermediates. Stereoselective syn-addition of tellurium tetrachloride to alkynes apparently proceeds via a mechanism involving the 4-membered transition state.

1 January 2009 in Tetrahedron Letters
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Journal Article
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SASvetlana V. Amosova
Svetlana V. Amosova
MPMaxim V. Penzik
Maxim V. Penzik
AAAlexander I. Albanov
Alexander I. Albanov
VPVladimir A. Potapov
Vladimir A. Potapov


1 October 2003 in Russian Journal of Organic Chemistry
Verified
Journal Article
Closed access
PDF file
VPV. A. Potapov
V. A. Potapov
SASvetlana V. Amosova
Svetlana V. Amosova