Nanoclay-reinforced polymers have attracted considerable universal attention in academic and industrial research due to their outstanding properties and their ever-expanding utilization in diversified applications. In that regard, in the present review, the structure of layered silicate clay, as well as procedures for clay material modification, are outlined. We also discuss the general characterization techniques, synthesis methods, and various properties of polymer–clay nanocomposites (PCNs), and some examples likewise are depicted from the scientific literature. The study’s primary goal is to provide an up-to-date survey of polymer–clay nanocomposites and their specific applications in industries such as automotive, flame-retardant, and biomedical applications, coating, and packaging.

The direct influence of La³⁺ ions on the gamma-ray shielding properties of cobalt-doped heavy metal borate glasses with the chemical formula 0.3CoO-(80-x)B₂O₃-19.7PbO-xLa₂O₃: x = 0, 0.5, 1, 1.5, and 2 mol% was examined herein. Several significant radiation shielding parameters were evaluated. The glass density was increased from 3.11 to 3.36 g/cm³ with increasing La³⁺ ion content from 0 to 2 mol%. The S5 glass sample, which contained the highest concentration of La³⁺ ions (2 mol%), had the maximum linear (μ) and mass (μ_m) attenuation coefficients for all photon energies entering, while the S1 glass sample free of La³⁺ ions possessed the minimum values of μ and μ_m. Both the half value layer (T_1/2) and tenth value layer (TVL) of all investigated glasses showed a similar trend of (T_1/2, TVL)_S1 > (T_1/2, TVL)_S2 > (T_1/2, TVL)_S3 > (T_1/2, TVL)_S4 > (T_1/2, TVL)_S5. Our results revealed that the S5 sample had the highest effective atomic number (Z_eff) values over the whole range of gamma-ray energy. S5 had the lowest exposure (EBF) and energy absorption (EABF) build-up factor values across the whole photon energy and penetration depth range. Our findings give a strong indication of the S5 sample’s superior gamma-ray shielding characteristics due to the highest contribution of lanthanum oxide.

This study aimed to investigate the nuclear radiation shielding properties of erbium (Er)-reinforced and samarium (Sm)-reinforced borate glasses. In the 0.015–15 MeV photon energy range, attenuation coefficients, as well as half-value layer tenth-value layers, and the mean-free path have been calculated. Additionally, effective, and equivalent atomic numbers, effective atomic weight, electron density, and exposure and energy absorption build-up factors were also calculated. To evaluate the overall nuclear radiation attenuation competencies of Er-rich and Sm-rich glasses, effective removal cross-section values for fast neutrons and projected range/mass stopping power values for alpha and proton particles were also determined. The glass sample BZBEr2.0 had the highest linear and mass attenuation coefficients (µandµ_m), effective conductivity (C_eff), the effective number of electrons (N_eff), and effective atomic number (Z_eff) values as well as the lowest half-value layer (T_1/2), tenth value layers (T_1/10), mean free path (λ), exposure build-up factor, and energy absorption build-up factor values.µ_mvalues were reported as 2.337, 2.556, 2.770, 2.976, 2.108, 2.266, 2.421, 2.569, and 2.714 for BZBEr0.5, BZBEr1.0, BZBEr1.5, BZBEr2.0, BZBSm0.0, BZBSm0.5, BZBSm1.0, BZBSm1.5, and BZBSm2.0 glass samples at 0.06 MeV, respectively. The results showed that Er has a greater effect than Sm regarding the gamma-ray shielding properties of borate glasses. The results of this investigation could be used in further investigations and added to older investigations with the same aim, to aid the scientific community in determining the most appropriate rare-earth additive, to provide adequate shielding properties based on the requirement.