For the purpose of deriving spatiotemporal estimates of soil moisture, the triangle method is one of the most widely used approaches today utilizing remote sensing data. Generally, those techniques are based on the physical relationships that exist when a satellite-derived land surface temperature (Ts) is plotted against a spectral vegetation index (VI). The present study proposes an improvement in the triangle method in retrieving soil moisture over heterogeneous areas. In particular, it proposes a new approach in robustly identifying the extreme points required for the technique’s implementation. Those extreme points are then used in calculating fractional vegetation cover (Fr) and scaled Ts. Furthermore, the study proposes a new approach for calculating the coefficients required to develop the relationships between surface soil moisture (SSM) and Fr/Ts, which is implemented using a model and field data. As a case study, an agricultural field in the Varanasi district in India has been used, on which the triangle method is implemented using ECOSTRESS and Sentinel-2 data. The much-improved spatial resolution satellite data of ~70 m from ECOSTRESS allowed deriving more vivid results of SSM spatial variability for the study area. Comparisons between field soil moisture calculated using the proposed method returned an RMSE of 0.03 and R² value of 0.84, which are considered very satisfactory. The methodology proposed herein and the results obtained are of significant value with regards to the triangle method, contributing to ongoing efforts at present examining its use for operational product development at a global scale.