The influence of the solvent type on the rheological properties of Carbopol ® NF 980 dispersions in water and in water/glycerol solutions is investigated. The material formulation, preparation procedure, common experimental challenges and artifact sources are all addressed. Transient and steady-state experiments were performed. For both solvent types, a clearly thixotropic behavior occurs slightly above the yield stress, where the avalanche effect is observed. For larger stresses, thixotropy is always negligible. Among other findings, it is observed that, for a given Carbopol concentration, the dispersion in the more viscous solvent possesses a lower yield stress and moduli, a larger power-law index, and a longer time to reach steady state.
1 March 2007 in Journal of Non-Newtonian Fluid Mechanics
We present an experimental investigation of bubbles rising in elasto-viscoplastic media. The effects of medium rheology and bubble size on the bubble velocity and shape are investigated. In addition, a discussion regarding the influence of the stress history on the bubble path is presented. Experimental tests are performed using yield stress materials which also present elastic behavior. Despite the difficulty in determining the relative importance of the different forces that are present in this flow, the results obtained illustrate the effect of yield stress, inertia, elasticity, and buoyancy on the dynamics and shape of the bubble.
1 July 2011 in Journal of Non-Newtonian Fluid Mechanics
We experimentally studied the viscous fingering instability considering a Newtonian oil displacing viscoelastic shear-thinning liquids and vice versa. The non-Newtonian liquids are aqueous solutions of polyacrylamide and xanthan gum, i.e., flexible and rigid polymers, respectively. A rectangular Hele-Shaw cell, connected by two plenum chambers, was developed to evaluate the displacement of a fixed volume. The experiment consists of analyzing the interface time evolution through a digital camera as a function of the geometric, dynamic, and rheological parameters. The displacement efficiency was determined through image processing in order to identify the formation of fingers or plugs. Unlike the Newtonian case, the transition does not occur when the viscosity ratio is roughly equal to one, but nevertheless, it was observed that the stability of the interface depends on the viscosity ratio. Specifically, more branches are observed at low viscosity ratios. Furthermore, a higher stability is observed when the Newtonian liquid displaces the shear thinning liquid, especially when the polymer is more rigid. When the Newtonian liquid is being displaced, elastic effects favor the displacing efficiency.