World orange production is estimated at 60 million tons per annum, while the annual production of orange peel waste is 32 million tons. According to available data, the adsorption capacity of orange peel ranges from 3 mg/g to 5 mg/g, while their water uptake is lower than 1 mg/g. The low water uptake of orange peel and the abundance of biomass in nature has made orange peel an excellent biosorption material. This review summarised different studies on orange peel adsorption of various contaminants to identify properties of orange peel that influence the adsorption of contaminants. Most of the literature reviewed studied orange peel adsorption of heavy metals, followed by studies on the adsorption of dyes, while few studies have investigated adsorption of oil by orange peel. FTIR spectra analysis and SEM micrographs of raw and activated orange peels were studied to understand the structural properties of the biomass responsible for adsorption. The study identified pectin, hydroxyl, carbonyl, carboxyl, and amine groups as components and important functional groups responsible for adsorption in orange peel. Furthermore, changes were observed in the structural properties of the peel after undergoing various modifications. Physical modification increased the surface area for binding and the adsorption of contaminants, while chemical treatments increased the carboxylic groups enhancing adsorption and the binding of contaminants. In addition, heating orange peel during the thermal modification process resulted in a highly porous structure and a subsequent increase in adsorption capacities. In conclusion, physical, chemical, and thermal treatments improve the structural properties of orange peel, resulting in high biosorption uptake. However, orange peels treated with chemicals recorded the highest contaminants adsorption capacities.

This study presents the effect of high plasticity on swell potential, swelling pressure and micro-structural characteristics of kaolinite-bentonite mixed clays. Five different mix ratios of kaolinite bentonite mixture of 100:0, 90:10, 75:25, 50:50 and 25:75 in % by weight of dry kaolinite were used. All five synthesised soils were then mixed with 0%, 5% and 8% of cement by weight of dry soil, cured for 28 days and subjected to the Atterberg limit, one-dimensional oedometer and scanning electron microscope test. The inclusion of 5% and 8% cement reduces the plasticity index of the treated soils as the percentage of bentonite increases. The effects on plasticity of treatment with 5% and 8% cement after a 28-day curing period was evaluated, and the results show that reduction in plasticity index resulted in decreased swell potential and swelling pressure of the kaolinite-bentonite mixed clays. The results of microstructural analysis of 5% cement-treated soils show formation of flocculated fabric and cementation of soil particles, and filling with cementitious compounds of the voids of flocculated fabric in the soil. The reduction in swell can be attributed to the resulting compacted and dense mass of treated soils due to cementation of soil particles and cation exchange. The complex swell behaviour of high-plasticity kaolinite-bentonite mix is explained using the one-dimensional oedometer test, by further experimental study and examination of the microstructure of treated soils.

Subgrade materials refer to the original ground underneath a road pavement, when these materials are made up of expansive soil it is referred to as expansive subgrade. Sometimes, these materials do not have sufficient capacity to support the weight of the road pavement and traffic load, which means they require some form of modification and re-engineering to enhance their load capacity. Chemical modification techniques using traditional stabilisers (such as cement and lime) have proved to be an effective means of subgrade stabilisation. However, high costs and environmental concerns associated with the use and production of these additives have highlighted the need for more sustainable and environmentally friendly substitutes. This study reviews the use of industrial by-products and other waste materials used for subgrade stabilisation, focusing on the sustainability of using processed wastes and how they alter the engineering properties of weak subgrade, compared to the use of cement and also reviews the availability of processed waste materials in quantities sufficient to meet the current demand for subgrade stabilisation. The findings illustrate that, processed waste is less expensive and has better sustainability credentials compared to cement. Moreover, processed wastes are available in sufficient quantities to meet existing demands for subgrade stabilisation. Therefore, it is recommended that the use of processed wastes should be promoted and utilised to improve and enhance the geotechnical properties of weak subgrade materials where possible.