Electronic skin, a class of wearable electronic sensors that mimic the functionalities of human skin, has made remarkable success in applications including health monitoring, human-machine interaction and electronic-biological interfaces. While electronic skin continues to achieve higher sensitivity and faster response, its ultimate performance is fundamentally limited by the nature of low-frequency AC currents. Herein, highly sensitive skin-like wearable optical sensors are demonstrated by embedding glass micro/nanofibers (MNFs) in thin layers of polydimethylsiloxane (PDMS). Enabled by the transition from guided modes into radiation modes of the waveguiding MNFs upon external stimuli, the skin-like optical sensors show ultrahigh sensitivity (1870 kPa-1), low detection limit (7 mPa) and fast response (10 μs) for pressure sensing, significantly exceeding the performance metrics of state-of-the-art electronic skins. Electromagnetic interference (EMI)-free detection of high-frequency vibrations, wrist pulse and human voice are realized. Moreover, a five-sensor optical data glove and a 2×2-MNF tactile sensor are demonstrated. These initial results pave the way toward a new category of optical devices ranging from ultrasensitive wearable sensors to optical skins.

A subwavelength-diameter tapered optical fiber coated with gelatin layer for fast relative humidity (RH) sensing is reported. The sensing element is composed of a 680-nm-diameter fiber taper coated with a 80-nm-thickness 8-mm-length gelatin layer, and is operated at a wavelength of 1550 nm. When exposed to moisture, the change in refractive index of the gelatin layer changes the mode field of the guided mode of the coated fiber, and converts a portion of power from guided mode to radiation mode, resulting in RH-dependent loss for optical sensing. The sensor is operated within a wide humidity range (9–94% RH) with high sensitivity and good reversibility. Measured response time is about 70 ms, which is one or two orders of magnitude faster than other types of RH sensors relying on conventional optical fibers or films.

Micro-/nanofibers (MNFs) are optical fibers with diameters close to or below the wavelength of the guided light. These tiny fibers can offer engineerable waveguiding properties including optical confinement, fractional evanescent fields, and surface intensity, which is very attractive to optical sensing on the micro-/nano scale. In this review, we first introduce the basics of MNF optics and MNF optical sensors from physical and chemical to biological applications and review the progress and current status of this field. Then, we review and discuss hybrid MNF structures for advanced optical sensing by merging MNFs with functional structures including chemical indicators, quantum dots, dye molecules, plasmonic nanoparticles, 2-D materials, and optofluidic chips. Thirdly, we introduce the emerging trends in developing MNF-based advanced sensing technology for ultrasensitive, active, and wearable sensors and discuss the future prospects and challenges in this exciting research field. Finally, we end the review with a brief conclusion.