A blue-emitting SiO ₂ :Eu ²⁺ compound has been successfully synthesized and characterized.

A novel blue-emitting LaOCl:Eu²⁺ phosphor has been successfully synthesized using the solid-state reaction. In addition, Ce³⁺ and Tb³⁺ activated LaOCl phosphors have been prepared and compared with the LaOCl:Eu²⁺ phosphor. FE-SEM images clearly indicate that the LaOCl:Eu²⁺ phosphor has a lamellar structure. XRD results and PL measurements for the LaOCl:Eu²⁺ phosphor indicate a preferred orientation along the [001] direction, which results in the blue-emission associated with the spectral characteristics of Eu²⁺. In contrast, the red-emission due to the formation of Eu³⁺ appears in a non-oriented one. These results reveal that Eu²⁺ ions are exclusively stabilized into the (00l) oriented LaOCl crystal lattice because the excitation and emission spectra of the blue-emitting LaOCl:Eu²⁺ phosphor consist of the spectral characteristics of Eu²⁺. The CIE chromaticity index (x = 0.151, y = 0.048) with high color saturation indicates that it is a promising candidate as a blue-emitting phosphor for white-light UV-LEDs.

Self-emitting blue and red EuOX (X = F, Cl, Br, and I) were successfully synthesized and characterized. Far-infrared and Raman measurements revealed that the vibration modes prominently reflected the Eu–O and Eu–X bond characters of these materials. X-ray photoelectron spectroscopy (XPS) of the red-emitting EuOX compounds showed that Eu exclusively existed as Eu³⁺, while in the blue-emitting EuOX, a mixed Eu³⁺/Eu²⁺ state was observed. For the red-emitting EuOX (X = F, Cl, and Br), the maximum wavelengths of the charge-transfer (CT) bands were red-shifted: F → Cl → Br (282, 320, and 330 nm for F, Cl, and Br, respectively). Using one-electron spin-polarized band structure calculations, it was verified that the red-shift of the CT energy from F to Br in EuOX was mainly due to the relative positions of the halogen orbital energies being gradually increased, following the trend in their electronegativity. For the blue-emitting EuOX (X = Cl, Br, and I), the emission band maxima were red-shifted from Cl to I (409, 414, and 432 nm for Cl, Br, and I, respectively), which was quite opposite to the trend predicted based on the spectrochemical series in crystal field theory, which was in good agreement with the previous results of the calculated 5d → 4f transition energies of the Eu²⁺ activator based on the crystal field theory. Through photoluminescence, UV-visible absorbance, and XPS, it was elucidated that the red emission due to Eu³⁺ was strongly masked by the intensified blue emission associated with the small amount of Eu²⁺ in the blue-emitting EuOX (X = Cl, Br, and I). These materials may provide a platform for modeling new phosphors for application in solid-state lighting.