In this paper, a combined organic Rankine cycle (ORC) system that can effectively utilize the cold energy of Liquefied Nature Gas (LNG) and the waste heat of dual fuel (DF) marine engine was proposed. Particularly, the engine exhaust gas and the jacket cooling water of the DF marine engine were used as heat sources. Firstly, a thorough assessment of thermo-economic performance was conducted for the combined ORC system using 11 environmentally friendly working fluids (WFs). Afterwards, the effects of evaporation and condensation pressures on the net output work, energy efficiency, exergy efficiency, total investment cost and payback period were examined. Furthermore, the thermo-economic performances of the ORC system were optimized via multi-objective optimization with a genetic algorithm. Finally, exergy destructions and investment costs of each component under the optimal operating conditions were analyzed to make suggestions for further improvement. The results show that R1150-R1234yf-R600a and R170-R1270-R152a are the two most promising WF combinations. The exergy destruction of the combined ORC system mainly exists in heat exchangers. Through WF optimization, the exergy destruction in the intermediate heat exchanger was reduced by 18.99%. The proportion of expanders investment cost could be greater than 50% and the payback period of the combined ORC system varies in the range of 7.68–9.43 years. This study demonstrated that the selection of WF and the optimization of operating conditions had important potential to improve thermo-economic performances of ORC systems.

Recovering the waste heat of a marine main engine (M/E) to generate electricity was an environmental way to minimize the carbon dioxide emissions for ships, especially with organic Rankine cycle (ORC) technology. The M/E had variable loads and operating times during voyage cycle, which directly affected the ORC thermodynamic potential. In this paper, a voyage cycle-based waste heat utilization from the M/E was introduced to provide reliable evaluation for proposing and designing ORC. The effect of various M/E loads and operating times on ORC performance among three dry-type substances was analyzed. The environmental impact was presented based on the data from one voyage cycle navigation of objective container ship. The results showed that Cyclohexane was capable of net power while Benzene was more suitable for thermal efficiency. The evaporator and condenser were the main irreversible components of the ORC system and required further optimization. Taking the operational profile into consideration, the evaporation pressures were 922–1248 kPa (Cyclohexane), 932–1235 kPa (Benzene) and 592–769 kPa (Toluene), respectively. During the voyage cycle, the carbon dioxide emissions were 99.68 tons (Cyclohexane), 96.32 tons (Benzene) and 60.99 tons (Toluene), respectively. This study provided certain reference for the design and investigation of ORC application to further improve the energy efficiency for container ship.