Hydrothermal liquefaction (HTL) uses heat and pressure to liquefy the organic matter in biomass/waste feedstocks to produce biocrude. When hydrotreated the biocrude is converted into transportation fuels including sustainable aviation fuel (SAF). Further, by liquifying the organic matter in wet wastes such as sewage sludge, manure, and food waste, HTL can prevent landfilling or other disposal methods such as anerobic digestion, or incineration. A significant roadblock to the development of a new route for SAF is the strict approval process, and the large volumes required (>400 L) for testing. Tier α and β testing can predict some of the properties required for ASTM testing with <400 mL samples. The current study is the first to investigate the potential for utilizing wet-waste HTL biocrude (WWHTLB) as an SAF feedstock. Herein, several WWHTLB samples were produced from food waste, sewage sludge, and fats, oils, and grease, and subsequently hydrotreated and distilled to produce SAF samples. The fuels (both undistilled and distilled samples) were analyzed via elemental and 2D-GC-MS. Herein, we report the Tier α and β analysis of an SAF sample derived originally from a WWHTLB. The results of this work indicate that the upgraded WWHTLB material exhibits key fuel properties, including carbon number distribution, distillation profile, surface tension, density, viscosity, heat of combustion, and flash point, which all fall within the required range for aviation fuel. WWHTLB has therefore been shown to be a promising candidate feedstock for the production of SAF.

The approval and evaluation process for sustainable aviation fuels (SAF) via ASTM D4054 is both cost- and volume-intensive, namely due to engine operability testing under severe conditions. Engine operability tests of combustor under figures of merit (FOM) limit phenomena are the fuel effects on lean blowout, high-altitude relight, and cold-start ignition. One method to increase confidence and reduce volume in tiered testing is to use surrogate fuels for manipulation of properties. Key fuel performance properties (surface tension, viscosity, density) for cold-start ignition was determined prior to this study. Prior work regarding this FOM has not considered the combination of these properties. A surface tension blending rule was validated and incorporated into the jet fuel blend optimizer (JudO). A generalized surrogate calculator for N-dimensional surrogate components and features was developed. Jet fuel surrogates developed in this study were a mixture of conventional and sustainable aviation fuels instead of pure components. These surrogates suggested to be tested in this study could illuminate near worst-case effects for sustainable aviation fuel in a given configuration/rig. With those scenarios tested, we can further understand the influence on the key properties relative to cold-start ignition. This work and supporting experimental evidence could potentially lower the barrier for SAF approval processes.

This presentation outlines the benefits and procedures for prescreening Sustainable Aviation Fuel (SAF) candidates using GCxGC. To date, there are only 8 alternative fuels that have been approved due in part to the nature of the cost and time-intensive requirements of the ASTM evaluation and approval process. A Tier Alpha sustainable aviation fuel prescreening tool has been