This work is a continuation of research on a correlation between the molecular structure and electronic charge distribution of phenolic compounds and their biological activity. The influence of lithium, sodium, potassium, rubidium and cesium cations on the electronic system of trans o-coumaric (2-hydroxy-cinnamic) acid was studied. We investigated the relationship between the molecular structure of the tested compounds and their antimicrobial activity. Complementary molecular spectroscopic techniques such as infrared (FT-IR), Raman (FT-Raman), ultraviolet-visible (UV-VIS) and nuclear magnetic resonance (¹H- and ¹³C-NMR) were applied. Structures of the molecules were optimized and their structural characteristics were calculated by the density functional theory (DFT) using the B3LYP method with 6-311++G** as a basis set. Geometric and magnetic aromaticity indices, atomic charges, dipole moments and energies were also calculated. Theoretical parameters were compared to the experimental characteristics of investigated compounds. Correlations between certain vibrational bands and some metal parameters, such as electronegativity, ionization energy, atomic and ionic radius, were found. The microbial activity of studied compounds was tested against Escherichia coli, Bacillus subtilis, Pseudomonas aeruginosa, Staphylococcus aureus, Proteus vulgaris and Candida albicans.

The aim of the presented research was to determine the suitability of cherry stones as a solid fuel. Mixtures of cherry stones with the addition of 10%, 15%, and 20% rye bran as a binder were subjected to the pressure agglomeration process in a rotary matrix working system (170, 220, and 270 rpm). The density of pellets, their kinetic durability, and power demand of the granulator’s device for each mix were determined. The highest quality was characterized by pellets containing 20% rye bran, which were combusted in a 25 kW boiler with a retort grate. The concentration of CO, CO₂, NO, SO₂, HCl, and O₂ in the exhaust gas was tested. On the basis of the results of combustion, high heating value (HHV), low heating value (LHV), and elemental analysis, it was found that pellets from cherry stones with the addition of rye bran can serve as a substitute for wood pellets in low-power installations.

The aim of the described research was to assess the suitability of onion husk waste as a material for the production of solid fuels in the form of granules (pellets). Due to the low susceptibility to thickening of onion husks, the addition of a binder in the form of potato pulp was used (waste with a high starch content). Both wastes were subjected to elemental analysis determining the content of C, H, N, S, Cl, and their HHV (High Heating Value) and LHV (Low Heating Value). Mixtures containing the addition of 10%, 15%, and 20% potato pulp to onion husks were subjected to granulation in a “flat matrix–thickening rollers” operating system at three rotational speeds of the granulator matrix a 170, 220, and 270 rpm. The influence of the potato pulp addition and matrix rotational speed on the quality of the obtained pellet was determined. The highest quality product was combusted in a low-power boiler with a retort grate, and the content of CO, CO₂, SO₂, NO, and HCl in the exhaust gas was determined. The highest quality granulate was obtained from a mixture containing 10% potato pulp, which was compacted at 170 rpm matrix, where the kinetic strength was 99.50% and the density was about 650 kg·m⁻³. The results of the combustion emissions from onion husk granules exceed the requirements of the EcoDesign Directive with the greatest being the case of CO.