Silver nanoparticles (AgNPs) biosynthesized using plant extracts as reducing and capping agents show multiple possibilities for solving various biological problems. The aim of this study was to expand the boundaries of AgNPs using a novel low toxicity and production cost phytochemical method for the biosynthesis of nanoparticles from Eucalyptus globulus and Salvia officinalis aqueous leaf extracts. Biosynthesized AgNPs were characterized by various methods (ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared (FTIR) spectroscopy with horizontal attenuated total reflectance (HART), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS)). The determined antioxidative and antimicrobial activity of plant extracts was compared with the activity of the AgNPs. The UV-vis spectral analysis demonstrated the absorption peaks at 408 and 438 nm, which confirmed the synthesis of stable AgNPs from E. globulus and S. officinalis, respectively. FTIR-HART results suggested strong capping of phytochemicals on AgNPs. TEM results show mainly spherical-shaped AgNPs, whose size distribution depends on the plant leaf extract type; the smaller AgNPs were obtained with E. globulus extract (with size range of 17.5 ± 5.89 nm compared to 34.3 ± 7.76 nm from S. officinalis AgNPs). The in vitro antioxidant activity evaluated by radical scavenging assays and the reduction activity method clearly demonstrated that both the plant extracts and AgNPs showed prominent antioxidant properties. In addition, AgNPs show much stronger antimicrobial activity against broad spectrum of Gram-negative and Gram-positive bacteria strains than the plant extracts used for their synthesis.

Silicone-based polymer composites containing high atomic number additives are prioritized for the development of new materials for radiation shielding, due to their mechanical, thermal, electrical, and multifunctional properties. The X-ray attenuation properties, as well as mechanical properties, of the newly developed-lead-free multi-layered structures for radiation shielding, based on silicone composite layers containing tin, cerium oxide, tungsten oxide, and bismuth additives, are analyzed and discussed in this paper. It is shown that, by varying the additive concentrations in silicone composites, lead-free and flexible layered structures, exhibiting lead-equivalent X-ray shielding, can be fabricated.

One method for adding enhancing properties to textile materials is the insertion of natural ingredients into the textile products during the manufacturing or finishing process. The aim of this research is to investigate the formation of biodegradable melt-spun multifilament Poly(lactic acid) (PLA) yarns with different contents (i.e., 5%, 10%, and 15%) of natural material–rosin, also known as colophony. In this study, multifilament yarns were successfully formed from PLA and a natural substance–pine rosin by melt-spinning them at two different draw ratios (i.e., 1.75 and 2.75). The results indicated that a 1.75 draw ratio caused the formation of PLA and PLA/rosin yarns that were brittle. The presence of rosin (i.e., 5% and 10%) in multifilament yarns decreased the mechanical properties of the PLA/rosin melt-spun multifilament yarns’ tenacity (cN/tex), breaking tenacity (cN/tex), and tensile strain (%) and elongation at break (%) and increased absorbance in the entire UV region spectra. In addition, the melting point and degree of crystallinity decreased and there was an increase in the wetting angle compared with pure PLA multifilament. The investigation of melt-spun yarns with Raman spectroscopy proved the presence of rosin in PLA melt-spun yarns.

A microbial fuel cell (MFC) is a promising renewable energy option, which enables the effective and sustainable harvesting of electrical power due to bacterial activity and, at the same time, can also treat wastewater and utilise organic wastes or renewable biomass. However, the practical implementation of MFCs is limited and, therefore, it is important to improve their performance before they can be scaled up. The surface modification of anode material is one way to improve MFC performance by enhancing bacterial cell adhesion, cell viability and extracellular electron transfer. The modification of graphite felt (GF), used as an anode in MFCs, by electrochemical oxidation followed by the treatment with ethylenediamine or p-phenylenediamine in one-step short duration reactions with the aim of introducing amino groups on the surface of GF led to the enhancement of the overall performance characteristics of MFCs. The MFC with the anode from GF modified with p-phenylenediamine provided approx. 32% higher voltage than the control MFC with a bare GF anode, when electric circuits of the investigated MFCs were loaded with resistors of 659 Ω. Its surface power density was higher by approx. 1.75 times than that of the control. Decreasing temperature down to 0 °C resulted in just an approx. 30% reduction in voltage generated by the MFC with the anode from GF modified with p-phenylenediamine.

Recently an increasing interest in deposition of electrolytic Mn has been observed. Part of the experimental data published earlier (in the journals of the former Soviet Union), but unfamiliar to western researchers because of the inaccessibility of the literature is presented and compared. The following results were reported in these papers that were inaccessible to Western researchers: larger crystals of γ-Mn were obtained from chloride electrolytes than from sulfate electrolytes; the crystal structure of α-Mn phase was observed by XRD when Mo Kα radiation was used; the influence of Zn, Cd and Cu impurities on microhardness of Mn coatings was complex; successful deposition of γ-Mn was possible at temperature as high as 80°C from “ultra pure” sulfate electrolyte containing ammonium ion; the phase of deposited Mn from pure electrolytes was influenced by the cathode-substrate, but increase in current density allowed eliminating the influence of the cathode-substrate leading to the deposition of α-Mn coatings