We analyze the localized surface plasmon resonance spectra of periodic square lattice arrays of gold nano-disks, and we describe numerically and experimentally the effect of disorder on resonance width, spectrum, and EM field enhancement in increasingly randomized patterns. The periodic structure shows a narrower and stronger extinction peak, conversely we observe an increase of up to (1–2)×102 times enhancement as the disorder is gradually introduced. This allows for simpler, lower resolution fabrication, cost-effective in light harvesting for solar cell and sensing applications. We show that dipole-dipole interactions contribute to diffract light parallel to the surface as a mean of long-range coupling between the nano-disks.
This work reports fabrication of inverse silica opal photonic crystal structures from direct polystyrene micro sphere opals using low-temperature sol-gel infiltration of silica, and examines performance of these photonic crystals as environmental refractive index sensors. Sensitivity of the spectral position and optical attenuation of photonic stop gaps is found to allow detection of the index changes by the amount of ~10-3. The high value of sensitivity, which is comparable with those of other optical sensing techniques, along with simplicity of the optical detection setup required for sensing, and the low-temperature, energy-efficient fabrication process make inverse silica opals attractive systems for optical sensing applications.
21 January 2010 in The Journal of Physical Chemistry Letters
Microphotonic sensors have been actively studied with increasing demands for label-free biosensing in medical diagnoses and life sciences. For high-throughput and low-cost sensing, a high sensitivity is crucial for eliminating the pre-concentration process, while a simple setup of sensors is also desirable. This paper demonstrates a super-sensitivity for protein, which satisfies these requirements. The key device is a photonic crystal nanolaser, in particular with a nanoslot. Even using a simple setup, the nanolaser achieves an extraordinary-low detection limit for BSA protein, i.e. 255 fM on an average, which cannot be explained by its bulk index sensitivity. The specific adsorption of the protein is observed only around the nanoslot with strong laser intensity. This suggests that the super-sensitivity arises from the effective trapping of protein in the nanoslot.