Soil salinization is one of the major degradation processes threatening food security and sustainable development. Detailed soil salinity information is increasingly needed to tackle this global challenge for improving soil management. Soil-visible and near-infrared (Vis-NIR) spectroscopy has been proven to be a potential solution for estimating soil-salinity-related information (i.e., electrical conductivity, EC) rapidly and cost-effectively. However, previous studies were mainly conducted at the field, regional, or national scale, so the potential application of Vis-NIR spectroscopy at a global scale needs further investigation. Based on an extensive open global soil spectral library (61,486 samples with both EC and Vis-NIR spectra), we compared four spectral predictive models (PLSR, Cubist, Random Forests, and XGBoost) in estimating EC. Our results indicated that XGBoost had the best model performance (R² of 0.59, RMSE of 1.96 dS m⁻¹) in predicting EC at a global scale, whereas PLSR had a relatively limited ability (R² of 0.39, RMSE of 2.41 dS m⁻¹). The results also showed that auxiliary environmental covariates (i.e., coordinates, elevation, climatic variables) could greatly improve EC prediction accuracy by the four models, and the XGBoost performed best (R² of 0.71, RMSE of 1.65 dS m⁻¹). The outcomes of this study provide a valuable reference for improving broad-scale soil salinity prediction by the coupling of the spectroscopic technique and easily obtainable environmental covariates.

Wise soil management requires detailed soil information, but conventional soil class mapping in a rather coarse spatial resolution cannot meet the demand for precision agriculture. With the advantages of non-destructiveness, rapid cost-efficiency, and labor savings, the spectroscopic technique has proved its high potential for success in soil classification. Previous studies mainly focused on predicting soil classes using a single sensor. In this study, we attempted to compare the predictive ability of visible near infrared (vis-NIR) spectra, mid-infrared (MIR) spectra, and their fused spectra for soil classification. A total of 146 soil profiles were collected from Zhejiang, China, and the soil properties and spectra were measured by their genetic horizons. Along with easy-to-measure auxiliary soil information (soil organic matter, soil texture, color and pH), four spectral data, including vis-NIR, MIR, their simple combination (vis-NIR-MIR), and outer product analysis (OPA) fused spectra, were used for soil classification using a multiple objectives mixed support vector machine model. The independent validation results showed that the classification model using MIR (accuracy of 64.5%) was slightly better than that using vis-NIR (accuracy of 64.2%). The predictive model built on vis-NIR-MIR did not improve the classification accuracy, having the lowest accuracy of 61.1%, which likely resulted from an over-fitting problem. The model based on OPA fused spectra performed best with an accuracy of 68.4%. Our results prove the potential of fusing vis-NIR and MIR using OPA for improving prediction ability for soil classification.