A NiCo2O4/MnO2 heterostructure with high mass loading MnO2 microflowers was built on the surface of 3D graphene/nickel foam for the preparation of an asymmetric supercapacitor with splended energy density (45.9 Wh kg−1).
23 March 2018 in Journal of Thermal Analysis and Calorimetry
Research on the conductivity and corrosion resistance of stainless steel bipolar plates in a proton exchange membrane fuel cell (PEMFC) is commonly performed in a normal-temperature environment (about 20 °C). However, these fuel cells must function in low-temperature environments (lower than 0 °C) in some conditions, such as in vehicle fuel cells and in portable power supplies that operate during the winter in northern China. Stainless steel bipolar plates have higher requirements in terms of their hydrophobic and anti-icing properties, in addition to needing high conductivity and corrosion resistance. In this study, carbon nanotubes (CNTs) are grown on the surface of 304 stainless steel (304 SS) without a catalyst coating by plasma-enhanced chemical vapor deposition (PECVD), which is a simple and cheap method that allows stainless steel to be used as bipolar plates in low-temperature environments. The Raman spectroscopy and scanning electron microscopy (SEM) results show that the CNTs grown on the surface of 304 SS have different morphologies. The stainless steel samples with different CNT morphologies are tested by hydrophobicity and in situ icing experiments to prove that vertical CNTs can achieve a superhydrophobic state and have good anti-icing properties. The interfacial contact resistance (ICR) of the bare 304 SS and the 304 SS with vertical CNTs is compared by voltammetry, and then the corrosion resistances of both types is compared in a simulated PEMFC environment via a three-electrode system. Consequently, the ICR of the 304 SS with vertical CNTs was lower than the bare 304 SS. The corrosion potential was positive, and the corrosion current density was greatly reduced for the stainless steel with vertical CNTs grown directly on its surface when compared with the bare 304 SS. The experimental results show that vertical CNTs have good application prospects as bipolar plates for PEMFCs in low-temperature environments.
This study investigated the force–frequency characteristics of quartz wafers inside a cantilever beam frame. Firstly, the force–frequency coefficient formula of quartz wafers with fixed ends under axial force was analyzed. Firstly, the formula for the force–frequency coefficient of quartz wafers with fixed ends under axial force was analyzed. A force–frequency coefficient formula suitable for cantilever beam structures was derived by considering the changes in surface stress and stiffness of quartz wafers with fixed ends and one end under force on the other. Subsequently, the formula’s accuracy was verified by experiments, and the accuracy was more than 92%. In addition, strain simulation analysis was performed on three different shapes of quartz wafers, and experimental verification was carried out on two of them. The results revealed that trapezoidal quartz wafers and cantilever beam structures exhibited superior stress distribution to rectangular chips. Furthermore, by positioning electrodes at various locations on the surface of the quartz chip, it was observed that, as the electrodes moved closer to the fixed end, the force–frequency coefficient of the rectangular quartz chip increased, along with an increase in chip strain under the cantilever structure. In summary, this study provides a new approach for designing cantilever quartz resonator sensors in the future.
Due to manufacturing errors, inaccurate measurement and working conditions changes, there are many uncertainties in laminated composite cylindrical shells, which causes the variation of vibration characteristics, and has an important influence on the overall performance. Therefore, an uncertainty representation methodology of natural frequency for laminated composite cylindrical shells is proposed, which considers probabilistic and interval variables simultaneously. The input interval variables are converted into a probabilistic density function or cumulative distribution function based on a four statistical moments method, and a unified probabilistic uncertainty analysis method is proposed to calculate the uncertainty of natural frequency. An adaptive Kriging surrogate model considering probabilistic uncertainty variables is established to accurately represent the natural frequency of laminated composite cylindrical shells. Finally, the dimensionless natural frequency of three-layer, five-layer and seven-layer laminated composite cylindrical shells with uncertainty input parameters is accurately represented. Compared with the Monte Carlo Simulation results, the mean error and standard deviation error are reduced to less than 0.07% and 4.7%, respectively, and the execution number of calculation function is significantly decreased, which fully proves the effectiveness of the proposed method.
Brake noise, a principal component of vehicle noise, is among the most critical measures of vehicle quality. The perceived quality of cars can be improved by reducing brake noise; therefore, vehicle manufacturers are extensively investigating the influencing factors, generating mechanism, and solutions of brake noise. Compressive strain is one of the most influential performance parameters of a brake pad and can be adjusted by regulating the material elastic modulus and by modifying the shape of the brake lining. In this study, the compressive strain of a brake pad was adjusted through four methods, and the noise characteristics of brake pads with different elastic modulus, section outlines, lining widths, and chamfers were studied through finite element analysis and the complex-eigenvalue method. The effects of compressive strain of a brake pad on brake noise were examined, and an optimized brake-pad scheme was developed. A dynamometer test conducted to validate the effectiveness of the optimized scheme confirmed a clear alleviation in brake noise.