Lignocellulosic biomass—the non-edible fraction of plants composed of cellulose, hemicellulose, and lignin—is the most abundant renewable carbon resource and a key lever for shifting from fossil to bio-based production. Agro-industrial residues (straws, cobs, shells, bagasse, brewery spent grains, etc.) offer low-cost, widely available feedstocks but are difficult to process because their polymers form a tightly integrated, three-dimensional matrix. Within this matrix, lignin provides rigidity, hydrophobicity, and defense, yet its heterogeneity and recalcitrance impede saccharification and upgrading. Today, most technical lignin from pulping and emerging biorefineries is burned for energy, despite growing opportunities to valorize it directly as a macromolecule (e.g., adhesives, foams, carbon precursors, UV/antioxidant additives) or via depolymerization to low-molecular-weight aromatics for fuels and chemicals. Extraction route and severity strongly condition lignin structure linkages (coumaryl-, coniferyl-, and sinapyl-alcohol ratios), determining reactivity, solubility, and product selectivity. Advances in selective fractionation, reductive/oxidative catalysis, and hybrid chemo-biological routes are improving yields while limiting condensation. Remaining barriers include feedstock variability, solvent and catalyst recovery, hydrogen and energy intensity, and market adoption (e.g., low-emission adhesives). Elevating lignin from fuel to product within integrated biorefineries can unlock significant environmental and economic benefits.

Slow population growth has limited the construction of new schools, leading to the renovation of existing buildings to achieve energy efficiency goals. While improvements are made to thermal insulation, heating and ventilation systems often remain outdated, presenting challenges in maintaining indoor air quality (IAQ) in schools, where children spend a significant amount of time in densely populated classrooms, and whose health is more affected by IAQ than that of adults. Therefore, this study assessed the possibilities to achieve IAQ requirements in schools ventilated by opening the windows by monitoring the carbon dioxide (CO₂) concentration, temperature, and relative humidity (RH) fluctuation. The results of the study have shown that it is not feasible to achieve the defined IAQ parameters in classrooms through window opening alone. The measured CO₂ concentration during lessons in many cases exceeded the limit value of 1000 ppm and did not decrease to ambient levels when the windows were opened during the break. Additionally, the internal air temperature dropped below the normative when lessons started, and RH was significantly below the recommended minimum value on all days. It was also found that the use of thermal energy decreases evenly because of inefficient air change leaving no direct economic leverage for the installation of efficient ventilation systems.

Polyisocyanurate (PIR) thermal insulation boards faced with carboard, plastic, aluminum, or multilayer facings are used for thermal insulation of buildings. Facing materials are selected according to the conditions of use of PIR products. At the corners of the building where these products are joined, facings can be in the direction of the heat flux movement and significantly increase heat transfer through the linear thermal bridge formed in the connection of PIR boards with facing of both walls. Analyzing the installation of PIR thermal insulation products on the walls of a building, the structural schemes of linear thermal bridges were created, numerical calculations of the heat transfer coefficients of the linear thermal bridges were performed, and the influence of various facings on the heat transfer through the thermal bridge was evaluated. Furthermore, an experimental measurement using a heat flow meter apparatus was performed in order to confirm the results obtained by numerical calculation. This study provides more understanding concerning the necessity to evaluate the impact of different thermal conductivity facings on the heat transfer through corners of buildings insulated with PIR boards.

Prefabricated products made of polyisocyanurate (PIR) thermal insulation material covered with cardboard, plastic, aluminium or composite facings are used for thermal insulation of building envelopes. The facing of these products is selected according to their conditions of use, and the effect of the facing on the declared thermal properties of the product depend only on water vapor diffuse properties of the facing. However, at the corners of the building where these products are joined, facings can be in the direction of the heat flux movement and significantly increase heat transfer through the longitudinal thermal bridge formed in the corner of the building. After analysing the solutions for installation of PIR thermal insulation products on the walls and roof corners of buildings, calculations of the heat transfer coefficients of the linear thermal bridges were made, and the influence of various facings and different structural solutions on the heat transfer coefficient value of the thermal bridge was determined. Aluminium foil facing have the greatest influence, but other facings must also be considered. The structural solutions with the greatest increase in the heat transfer due to the effect of the facing were selected, and the influence to the thermal and air tightness properties of the structural solution when facing is removed were analysed, the stability of thermal properties of the thermal insulation material were analysed as well. Proposals for joining PIR thermal insulation products with heat-conductive facings in the corners of buildings were prepared.

Polyisocyanurate (PIR) insulation boards are widely used in buildings because of their low thermal conductivity, however their long-term performance is affected by aging. This study investigates the effect of accelerated thermal aging at +70 °C on the thermal conductivity and gas composition of pentane-blown PIR boards. Thermal conductivity was monitored over time, while changes in blowing-agent composition were analyzed using gas chromatography/mass spectrometry (GC/MS). Thermal conductivity increased from 0.0201–0.0211 W/(m·K) to 0.0243–0.0247 W/(m·K), corresponding to an increase of approximately 18–22%, with the most pronounced changes occurring during the first 40–50 days before stabilizing. GC/MS identified isopentane, cyclopentane, and pentane as the main gases in the foam cells, with isopentane as the dominant component. Accelerated aging caused a progressive decrease in blowing-agent concentration, explaining the deterioration in thermal insulation performance. Thermal outgassing proved more reliable than solvent extraction, providing higher sensitivity and reproducibility. Sample location, sample size, and outgassing temperature significantly affected the measured gas quantities, while higher outgassing temperatures improved analytical sensitivity without changing gas composition trends. The results confirm that the aging-induced increase in thermal conductivity is primarily caused by the loss of low-conductivity blowing agents, improving understanding of the long-term performance of PIR insulation materials.