Purpose: With its substantial CO₂eq emissions, the agricultural sector is a significant greenhouse gas (GHG) emitter. Animal manure alone contributes 16% of the total agricultural emissions. With a rapidly increasing demand for animal-based protein, animal wastes are expected to rise if sustainable manure management practices are not implemented. Manures have the potential to be treated to generate valuable products (biofertiliser and biocrude) or feedstock for energy production. Thermochemical conversion technologies such as pyrolysis, combustion, supercritical gasification (SCWG), etc., have demonstrated their potential in manure management and valorisation. This study provides a broader overview of these technologies and envisages future manure valorisation trends. Methods: The paper presents a state-of-the-art review of manure valorisation. Characterisation of manure, modelling and optimisation of thermochemical conversion technologies along with life cycle anaalysis (LCA) are also reviewed. Results: The literature review highlighted that the thermochemical conversion technologies can generate bio-oils, syngas, H₂, biofuels, heat, and biochar as carbon-free fertiliser. The reported calorific value of the produced bio-oil was in the range of 26 MJ/kg to 32 MJ/kg. However, thermochemical conversion technologies are yet to be commercialised. The major challenges associated with the scale-up of manure derived feedstocks are relatively high moisture and ash content, lower calorific value and higher concentration of impurities (N, Cl, and S). LCA studies conclude that gasification presents a sustainable option for manure valorisation as it is economical with modest environmental threats. Significance of Study: This review briefly states the current challenges faced in manure management and presents the case for a sustainable valorisation of animal manures using thermochemical technologies. The economic, environmental and societal advantages of these technologies are presented in order to promote the scientific and industrial development of the subject in the academic and research community. Conclusions: Thermochemical conversion technologies are promising for manure valorisation for energy and nutrient recovery. However, their commercialisation viability needs wide-ranging evaluations such as techno-economics, life-cycle analysis, technology take-up and identification of stakeholders. There should be clear-cut policies to support such technologies. It should be advocated amongst communities and industries, which necessitates marketing by the governments to secure a clean energy future for the planet. Graphical

The circular economy is at the core of sustainable development. The generation of biogas from the massive quantity of agricultural waste biomass is one of the critical drivers of the circular economy. Biogas has enormous renewable energy potential and has multitudes of applications in today’s energy-intensive society. Oil cakes, a known Agri-waste, are the by-product of oil processing, and are rich in nutrients. The edible oil cakes mostly have been used as a cattle feed; however, non-edible oil cakes do not find many applications. Their production is continuously escalating as non-edible oils are increasingly used in biodiesel production. Recently, there is a lot of emphasis on biogas production from these oil cakes. This paper reviews in detail biogas production from both edible and non-edible oil cakes. Chemical composition and various other applications of the cakes are also reviewed in brief. The survey illustrates that multiple parameters such as inoculum sources, co-digestion and reactor design affect the biogas production. All those factors, along with biogas upgrading and the economy of the process, are reviewed. Finally, future research opportunities are suggested to improve the viability of the biogas production from oil cakes.

The dispersion of air pollutants emitted from industries has been studied ever since the dawn of industrialisation. The present work focuses on investigating the effect of negative atmospheric temperature gradient and the plume stack orientation of two individual equal-height stacks on the vertical rise and dispersion of the plume. The study carried out upon three-stack layout configurations namely inline, 45° and non-inline, separated by an inter-stack distance of 12 times the exit chimney diameter (12 D) and 22 times the exit chimney diameter (22 D) in each case over the two temperature gradients of −0.2 K/100 m and −0.5 K/100 m. The turbulence is modelled using realisable k-ε model, a model used in the FLUENT flow solver. In the case of the inline configuration, the upwind plume shields its downwind counterpart, which in turn allows for higher plume rise at a given temperature gradient. The plume oscillates more in the case of inline than 45° and non-inline cases. Also, for a temperature gradient of −0.5 K/100 m, the plumes oscillate violently in the vertical direction, mainly because, with the initial rise of the plume, cold air from higher altitudes moves down and forms a layer of lower temperature closer to the ground. The present study is important to highlight the plume dispersion characteristics under negative temperature gradient conditions.

Thermal decomposition kinetics of Polypropylene (PP) waste is extremely important with respect to valorisation of waste plastics and production of utilizable components viz. chemicals, fuel oil & gas. The present research study focuses on pyrolysis kinetics of PP waste, which is present as a fraction of municipal plastic waste through distributed activation energy model (DAEM). The decomposition kinetics for PP follows a Gaussian distribution, where the normal distribution curves were centred corresponding to activation energy of 224 kJ/mol. The standard deviation of the distribution for the PP sample was found to be 22 kJ/mol indicating its wider distribution of decomposition range. The data validation has been carried out by comparing the rate parameter and extent of conversion values calculated through DAEM model with the Thermogravimetric analysis (TGA) experiments carried out for PP at various heating rates of 5, 10, 20 and 40 °C/min.

(1-x)(0.93Bi0.5Na0.5TiO3/0.07BaTiO3)-xCoFe2O4 ((1-x)BNT/BT-xCFO, where x = 0.1, 0.2, 0.3, 0.4 and 0.5) composite samples were synthesized by microwave assisted solid state reaction route and sintered at 1050 °C. X-ray diffraction study showed the presence of ferroelectric/ferromagnetic (FE/FM) phases without any peak of secondary phase. This was further confirmed by SEM study showing the presence of both FE/FM grains distinctly. Frequency dependent dielectric study showed maximum dielectric constant ("r) for the composite sample with x = 0.4. Polarization versus electric field (P-E) loop study revealed that maximum remnant polarization (2Pr = 1.75 μC/cm2) was found also for the 0.6BNT/BT-0.4CFO sample. Remnant magnetization (Mr) of the composite sample with x = 0.4 was found to be ∼7.81 emu/g. Magnetodielectric (MD) study of the 0.6BNT/BT-0.4CFO composite sample showed decrease in "r with the application of magnetic field and a MD effect of ∼2.4% (at 10 kHz) was found. Low leakage current value (∼10−4 A) was obtained in the 0.6BNT/BT- 0.4CFO composite sample. Change in piezoresponse force microscopy contrast after poling indicated on the changes in polarization of the ferroelectric domains. Reduction in Mr, observed in magnetic force microscopy contrast gave a clear evidence of presence of electric field induced magneto-electric (ME) coupling in the 0.6BNT/BT-0.4CFO composite sample.

In the current era where pesticides play a vital role in one’s everyday life, large quantities of various pesticides some of which are highly toxic are being used routinely by industries and consumers. Extensive use of these chemicals provides greater risk to plants, animals and human population which has been reviewed from time to time. Apart from the biological degradation, photochemical removal holds considerable promise for the abatement of these pesticides in wastewaters. This paper reviews the photochemical degradation of pesticides. It is evident from the review that removal depends on several factors such as pH of the solution, catalysts loading, initial concentration of the pesticides, support based catalysts or suspended catalysts, light intensity and so on and so forth. Since the pesticides are ubiquitously present in the wastewaters, photochemical technology seems imperative to alleviate the pollution problems associated with the pesticides. However, commercial application of this technology has to be clearly assessed.