Inspired by nature, tunable wettability has attracted a lot of attention in both academia and industry. Various methods of polymer surface tailoring have been studied to control the changes in wetting behavior. Polymers with a precisely controlled wetting behavior in a specific environment are blessed with a wealth of opportunities and potential applications exploitable in biomaterial engineering. Controlled wetting behavior can be obtained by combining surface chemistry and morphology. Plasma assisted polymer surface modification technique has played a significant part to control surface chemistry and morphology, thus improving the surface wetting properties of polymers in many applications. This review focuses on plasma polymerization and investigations regarding surface chemistry, surface wettability and coating kinetics, as well as coating stability. We begin with a brief overview of plasma polymerization; this includes growth mechanisms of plasma polymerization and influence of plasma parameters. Next, surface wettability and theoretical background structures and chemistry of superhydrophobic and superhydrophilic surfaces are discussed. In this review, a summary is made of recent work on tunable wettability by tailoring surface chemistry with physical appearance (i.e. substrate texture). The formation of smart polymer coatings, which adjust their surface wettability according to outside environment, including, pH, light, electric field and temperature, is also discussed. Finally, the applications of tunable wettability and pH responsiveness of polymer coatings in real life are addressed. This review should be of interest to plasma surface science communality particularly focused controlled wettability of smart polymer surfaces.

The proliferation of natural gas production had led to increased utilization of methane as a raw material for chemicals. The most significant bottleneck in this process is the high activation energy of methane. This paper reports the direct conversion of methane to acetylene in a novel rotating arc driven by AC electrical power. By feeding a sufficiently high concentration of CH₄ (greater than 43%) diluted in H₂ (the discharge gas) through the arc column, a low specific energy requirement (SER) of 10.2 kW h kg⁻¹ C₂H₂ was achieved. The use of hydrogen as the discharge gas strongly suppressed soot formation during the methane conversion process under high methane concentration conditions, resulting in a carbon balance of greater than 95% and a C₂H₂ selectivity of greater than 90% while maintaining a methane conversion rate of greater than 70%, depending on the conditions. The novel rotating arc enabled the elongation of the arc column itself, which controlled heat loss and improved the energy use for reaction. The ability to control the arc length based on low-current type arc generation has additional benefits for reaction enhancement. These results demonstrate that arc control, optimization of the reaction conditions, and a full understanding of reaction pathway are viable means for the energy-efficient direct conversion of methane to acetylene.

In this study, a sustainable air plasma-based nitrogen fixation into reactive nitrogen species in water (e.g. nitrate and nitrite) is presented, which mimics the lightning-based nitrogen fixation that occurs in nature. We report a hybrid plasma system that combines a dielectric barrier discharge (DBD) reactor (as an efficient ozone source) and an arc plasma reactor (as an efficient NO _x source). This hybrid plasma system completely converts gaseous NO _x and O ₃ into NO x − in water with almost zero emissions (NO _x and O ₃ ). Gaseous outlets, in-liquid species, and electrical parameters were investigated. The energy cost for nitrate production via a single-pass reaction was extremely reduced to 8 MJ mol ⁻¹ , which enhanced the applicability of the direct one-step nitrogen fixation into NO x − in water for distributed fertilizer production to decrease the dependence on the Haber–Bosh process toward sustainable agricultural development.