Invisible orthodontic aligners (IOAs) have been introduced in the orthodontic field as an innovative alternative for fixed brackets, in relation to their ability to be easily inserted/removed from the oral cavity without affecting the chewing ability and the aesthetic of the patients. The paper provides a complete physicochemical and mechanical characterization of thermoplastic materials in the form of disks used for commercial IOAs. A wide palette of specific techniques is considered, from tensile tests and dynamic-mechanical analysis, to X-Ray diffraction (XRD), differential scanning calorimetry (DSC), Fourier transformation infrared spectroscopy (FTIR-ATR) analyses and water absorption tests. The disks are investigated before and after immersion into staining beverages (red wine, coffee, nicotine and artificial saliva), in terms of colour variations, transparency, and microscopic surface modifications by means of colorimetry, UV-VIS absorbance and scanning electron microscopy (SEM). Among all the samples, polyurethane (PU) exhibited the highest crystallinity and the highest values of mechanical and thermal resistance, while the poly(ethylene terephthalate)-glycol (PETG) samples presented better transparency and less ability to absorb water. Moreover, red wine and coffee give noticeable colour variations after 14 days of immersion, together with a slight reduction of transparency.

The split Hopkinson bar is a well-known apparatus for performing tests at high strain-rate on engineering materials. The specimen is placed between two long bars and quickly loaded by a pressure wave, which travels at sound speed along the input bar, passes through the specimen, then is partly reflected and partly transmitted to the output bar. In the classical version, the input wave is generated by the impact of a striker bar against the input bar at a given velocity. In the direct version of the Hopkinson bar, the wave is generated by pre-loading and releasing a portion of the input bar. However, with this approach the rise time of the pressure wave is usually longer respect to the classical version. In this paper, an innovative wave generation system is presented, which exploits the abrupt shear fracture of a thin brittle disc. In this way, the rise time of the incident waves can be close to that obtained by the classical impact-based Hopkison bars (80 µs instead of 50 µs). Moreover, both tension and compression tests can be carried out with the same experimental system.