Surface ozone concentrations typically peak during the daytime, driven by active photochemical production, and decrease gradually after sunset, due to chemical destruction and dry deposition. Here, we report that nocturnal ozone enhancement (NOE, defined as an ozone increase of more than 5 ppbv h⁻¹ in 1 of any 2 adjacent hours between 20:00 and 06:00 LT, local time) events are observed at multiple monitoring sites in China at a high frequency, which has not been recognized in previous studies. We present an overview of the general characteristics of NOE events in China and explore the possible mechanisms based on 6 years of observations from the national monitoring network. We find that the mean annual frequency of NOE events is 41±10 % (i.e., about 140 d would experience an NOE event per year) averaged over all 814 Chinese sites between 2014 and 2019, which is 46 % larger than that over Europe or the United States. The NOE event frequency is higher in industrialized city clusters (>50 %) than in regions with lighter ozone pollution, and it is higher in the warm season (46 %) than in the cold season (36 %), consistent with the spatiotemporal evolution of ozone levels. The mean ozone peak during NOE events reaches 37±6 ppbv in the warm season. The ozone enhancements are within 5–15 ppbv h⁻¹ during 85 % of the NOE events; however, in about 10 % of cases, the ozone increases can exceed 20 ppbv h⁻¹. We propose that high photochemistry-induced ozone during the daytime provides a rich ozone source in the nighttime residual layer, determining the overall high frequency of NOE events in China, and that enhanced atmospheric mixing then triggers NOE events by allowing the ozone-rich air in the residual layer to mix into the nighttime boundary layer. This is supported by our analyses which show that 70 % (65 %) of the NOE events are associated with increases in friction velocity (planetary boundary layer height), indicative of enhanced atmospheric mixing, and also supported by the observed sharp decreases in surface NO₂ and CO concentrations with ozone increases in NOE events, a typical signal of mixing with air in the residual layer. Three case studies in Beijing and Guangzhou show that synoptic processes such as convective storms and low-level jets can lead to NOE events by aggravating vertical mixing. Horizontal transport of ozone-rich plumes may also be a supplementary driver of NOE events. Our results summarize, for the first time, the characteristics and mechanism of NOE events in China based on nationwide and long-term observations, and our findings emphasize the need for more direct measurements and modeling studies on the nighttime ozone evolution from the surface to the residual layer.

The local strong sandstorms (LSS), similar to haboobs in Sahara and the North America, often occur suddenly, in tens of minutes during the late afternoon, and before dusk in deserts in China, causing a significant impact on the local atmospheric environment. The Sudan haboob or American haboob often appears in the wet season, followed by thunderstorm events. In contrast, the LSS in China appears most frequently in relatively dry season. The lack of observational data in weather conditions before their formation, during their development and after their disappearance have hindered our understanding of the evolution mechanism of LSS/haboobs. This paper provides a review of the current status and model studies on LSS/haboobs in different time and space to characterize the weather conditions and triggering mechanisms for LSS/haboobs occurrence, as well as highlight the subject for further understanding of LSS/haboobs. LSS are always followed by the occurrence of a dry squall. The interaction of dust radiation heating in the near-surface mixing layer with a mesoscale anticyclone air mass (cold-air pool) in the upper layer is the key process that leads to an LSS. Haboobs are followed by the occurrence of a wet squall. The release of latent heat due to the condensation of water vapor, involving moist convection and cold downdraughts, is the main driving force that cause the occurrence of a haboob. For a better understanding of the characteristics of the wind-sand two-phase flow and the mechanism of energy dissipation in LSS/haboobs, further accumulation of meteorological observation data and small-scale multiple-phase numerical simulations are required.