The 2D transition metal carbides/nitrides (2D MXenes) are a versatile class of 2D materials for photovoltaic (PV) systems. The numerous advantages of MXenes, including their excellent metallic conductivity, high optical transmittance, solution processability, tunable work‐function, and hydrophilicity, make them suitable for deployment in PV technology. This comprehensive review focuses on the synthesis methodologies and properties of MXenes and MXene‐based materials for PV systems. Titanium carbide MXene (Ti₃C₂T_x), a well‐known member of the MXene family, has been studied in many PV applications. Herein, the effectiveness of Ti₃C₂T_x as an additive in different types of PV cells, and the synergetic impact of Ti₃C₂T_x as an interfacial material on the photovoltaic performance of PV cells, are systematically examined. Subsequently, the utilization of Ti₃C₂T_x as a transparent conductive electrode, and its influence on the stability of the PV cells, are discussed. This review also considers problems that emerged from previous studies, and provides guidelines for the further exploration of Ti₃C₂T_x and other members of the 2D MXene family in PV technology. This timely study is expected to provide comprehensive understanding of the current status of MXenes, and to set the direction for the future development in 2D material design and processing for PVs.

This study firstly presents TADF dyes based LSC device. Charge transfer characteristics and twisted structures of TADF dyes help to achieve near-zero reabsorption losses. Thus, η _opt and η _PCE of champion device are 10.4% and 2.2% respectively.