An overview of MOFs and their composite materials for better photocatalytic performance towards organic pollutants.

This review highlights the current progress in the chemistry of MOFs and their dye adsorption mechanisms.

This study reviews the development of titanium-based MOFs in the therapeutic areas of antibacterial therapy, tumor therapy, anti-inflammatory therapy, and bone injury therapy.

With the continuous evolution of bacteria and the constant use of traditional antibiotics, the emergence of drug-resistant bacteria and super viruses has attracted worldwide attention. Antimicrobial therapy has become the most popular and important research field at present. Coordination Polymer (CP) and/or metal-organic framework (MOF) platforms have the advantages of a high biocompatibility, biodegradability, and non-toxicity, have a great antibacterial potential and have been widely used in antibacterial treatment. This paper reviewed the mechanism and antibacterial effect of three typical MOFs (pure Ag-MOFs, hybrid Ag-MOFs, and Ag-containing-polymer @MOFs) in silver-based coordination polymers. At the same time, the existing shortcomings and future views are briefly discussed. The study on the antibacterial efficacy and mechanism of Ag-MOFs can provide a better basis for its clinical application and, meanwhile, open up a novel strategy for the preparation of more advanced Ag-contained materials with antibacterial characteristics.

A 2-D copper(II)-based coordination polymer, [Cu(SCN)(hmp)]_n CP (1), was crystallized via the slow evaporation method after the reaction of CuSO₄·5H₂O, 2-pyridinemethanol (hmpH), sodium thiocyanate and sodium hydroxide in water for functional applications. CP (1) was characterized via elemental analysis, FTIR, PXRD, magnetic, EPR, crystallographic and TGA studies. The crystal structure and EPR data confirmed a square pyramidal geometry around the Cu(II) ions. The topological analysis revealed that CP 1 has a {6^{^}3} point symbol with a [6.6.6] extended point symbol and 3-c net, uninodal net having hcb and Shubnikov hexagonal plane net/(6,3) type of uncommon topology. The magnetic studies suggested the strong antiferromagnetic nature of CP (1). The fluorescence sensing property of CP (1) was investigated with different nitro aromatic compounds and hazardous metal ions. CP (1) demonstrated high selectivity and sensitivity towards nitrobenzene, even in the presence of other competitive nitro aromatics. In addition, CP (1) showed excellent selectivity and sensitivity toward Fe³⁺ over other metal ions. The possible detection mechanisms were proposed employing UV-visible and fluorescence spectroscopy and DFT calculations. CP (1) also showed excellent recyclability towards both analytes, and its initial intensity was almost regained after several washings. Moreover, CP (1) acted as an excellent adsorbent material for natural dyes with different charges and sizes, i.e., methylene blue (MB), methyl orange (MO) and Rhodamine-B. Furthermore, CP (1) was utilized repeatedly for the effective adsorption of MB from wastewater without significant loss in its adsorption capacity. Hence, the present CP (1) was designed to relate coordination chemistry with various functional applications of interest.