1. RWTH Aachen University, Department of Georesources and Material Engineering, Division of Material Science and Engineering, Chair of Material Mechanics, Schinkelstr. 2, D-52062 Aachen, Germany
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Dr. Bob Svendsen
1. RWTH Aachen University, Department of Georesources and Material Engineering, Division of Material Science and Engineering, Chair of Material Mechanics, Schinkelstr. 2, D-52062 Aachen, Germany
The melting curve of iron, the primary constituent of Earth's core, has been measured to pressures of 250 gigapascals with a combination of static and dynamic techniques. The melting temperature of iron at the pressure of the core-mantle boundary (136 gigapascals) is 4800 ± 200 K. whereas at the inner core-outer core boundary (330 gigapascals), it is 7600 ± 500 K. Corrected for melting point depression resulting from the presence of impurities, a melting temperature for iron-rich alloy of 6600 K at the inner core-outer core boundary and a maximum temperature of 6900 K at Earth's center are inferred. This latter value is the first experimental upper bound on the temperature at Earth's center, and these results imply that the temperature of the lower mantle is significantly less than that of the outer core.
Single crystal Ni-based superalloys have long been an essential material for gas turbines in aero engines and power plants due to their outstanding high temperature creep, fatigue and oxidation resistance. A turning point was the addition of only 3 wt.% Re in the second generation of single crystal Ni-based superalloys which almost doubled the creep lifetime. Despite the significance of this improvement, the mechanisms underlying the so-called “Re effect” have remained controversial. Here, we provide direct evidence of Re enrichment to crystalline defects formed during creep deformation, using combined transmission electron microscopy, atom probe tomography and phase field modelling. We reveal that Re enriches to partial dislocations and imposes a drag effect on dislocation movement, thus reducing the creep strain rate and thereby improving creep properties. These insights can guide design of better superalloys, a quest which is key to reducing CO2 emissions in air-traffic.
1 February 2017 in Journal of the Mechanics and Physics of Solids
Magnesium-yttrium alloys show significantly improved room temperature ductility when compared with pure Mg. We study this interesting phenomenon theoretically at the atomic scale employing quantum-mechanical (so-called ab initio) and atomistic modeling methods. Specifically, we have calculated generalized stacking fault energies for five slip systems in both elemental magnesium (Mg) and Mg-Y alloys using (i) density functional theory and (ii) a set of embedded-atom-method (EAM) potentials. These calculations predict that the addition of yttrium results in a reduction in the unstable stacking fault energy of basal slip systems. Specifically in the case of an I 2 stacking fault, the predicted reduction of the stacking fault energy due to Y atoms was verified by experimental measurements. We find a similar reduction for the stable stacking fault energy of the {11 22} 11 23 non-basal slip system.