It has been observed that colloidal particles are anomalously repelled from the interface of nanoporous materials and water by up to hundreds of micrometers even if there is no additional external field present. Recently, the physical origin of this anomalous repulsion has turned out to be diffusiophoretic migration triggered by an ion exchange process through the interface. Since the repulsive force is induced by a salt gradient only, the phenomenon can be applied to a microscale water purification platform without the need for any external power sources. In this work, we suggest a micro/nanofluidic device for continuous water purification utilizing long-range diffusiophoretic migration around ion exchangeable surfaces. An ion concentration boundary layer was characterized by the Sherwood number (Sh) which is a key dimensionless number to describe the purification process. Depending on Sh, we have theoretically and experimentally demonstrated that long-range diffusiophoretic exclusion can be used for continuous water purification. Finally, our platform can be used as a highly energy-efficient and portable water treatment option for operations such as purification, disinfection, water softening, etc.

Ion concentration polarization (ICP) is a fundamental electrokinetic process that occurs near a perm-selective membrane under dc bias. Overall process highly depends on the current transportation mechanisms such as electro-convection, surface conduction and diffusioosmosis and the fundamental characteristics can be significantly altered by external parameters, once the permselectivity was fixed. In this work, a new ICP device with a bifurcated current path as for the enhancement of the surface conduction was fabricated using a polymeric nanoporous material. It was protruded to the middle of a microchannel, while the material was exactly aligned at the interface between two microchannels in a conventional ICP device. Rigorous experiments revealed out that the propagation of ICP layer was initiated from the different locations of the protruded membrane according to the dominant current path which was determined by a bulk electrolyte concentration. Since the enhancement of surface conduction maintained the stability of ICP process, a strong electrokinetic flow associated with the amplified electric field inside ICP layer was significantly suppressed over the protruded membrane even at condensed limit. As a practical example of utilizing the protruded device, we successfully demonstrated a non-destructive micro/nanofluidic preconcentrator of fragile cellular species (i.e. red blood cells).

To overcome a world-wide water shortage problem, numerous desalination methods have been developed with state-of-the-art power efficiency. Here we propose a spontaneous desalting mechanism referred to as the capillarity ion concentration polarization. An ion-depletion zone is spontaneously formed near a nanoporous material by the permselective ion transportation driven by the capillarity of the material, in contrast to electrokinetic ion concentration polarization which achieves the same ion-depletion zone by an external d.c. bias. This capillarity ion concentration polarization device is shown to be capable of desalting an ambient electrolyte more than 90% without any external electrical power sources. Theoretical analysis for both static and transient conditions are conducted to characterize this phenomenon. These results indicate that the capillarity ion concentration polarization system can offer unique and economical approaches for a power-free water purification system.

The separation of nanoparticles has drawn critical attention in various microfluidic applications including chemical analysis, diagnostics and environmental monitoring. Thus, a number of nanoparticle separation methods have been extensively proposed. However, most of the conventional methods require complicated structured devices, expensive manufacturing processes, and external power sources. While a spontaneous diffusiophoretic separation device based on an ion exchange mechanism could overcome such drawbacks, the recovery of separated particles and the inevitable development of an acidic environment due to the release of H⁺ from the cation exchange membrane limit its practical applicability. Therefore, in this work, we present a simple but robust nanoparticle separation method based on spontaneously induced diffusiophoresis, which is operated in a continuous manner to overcome the limitations of conventional methods. First, we confirmed that the particle exclusion distance followed the previously developed scaling law of diffusiophoresis. Consequently, we demonstrated the separation of nanoparticles of 40 nm, 200 nm and 2 μm diameter by utilizing the fact that the exclusion distances of various particles were proportional to their diffusiophoretic mobility. Furthermore, the use of Tris buffer increased the diffusiophoretic migration of nanoparticles due to the enhanced concentration gradient, and enabled the produced solution to be compatible with pH-sensitive bio-samples. Therefore, we expect this continuous and spontaneous diffusiophoretic separation platform to be useful in practical applications for analyzing various nano-meter scale bio-particles.