Hydrogen is undeniably one of the most promising options for producing energy with minimal environmental impact. However, current hydrogen production is still derived from carbon-intensive processes relying on fossil fuels. Biomass is a sustainable and versatile resource that can be converted into hydrogen through biological and thermochemical pathways from a large variety of feedstocks and technologies. This work reviews and compares existing biomass-to-hydrogen technologies, focusing on their characteristics, maturity level, benefits, limitations, and techno-economic and lifecycle environmental impacts. Less-developed biological conversion methods are characterized by low efficiencies and hydrogen productivity. More mature thermochemical routes enable higher efficiencies and hydrogen yields. Overall, while thermochemical processes suit centralized large-scale hydrogen production, biological pathways offer decentralized options, necessitating continued innovation for integration into future energy strategies. Some of these technologies, such as anaerobic digestion (best-case: 1.28 EUR/kgH₂) and conventional gasification (best-case: 1.79 EUR/kgH₂), emerge as promising, sustainable, and affordable alternatives for renewable hydrogen generation, offering production costs comparable to those of natural gas steam reforming (0.92–2.8 EUR/kgH₂).

The focus of this study is to provide a comparative techno-economic analysis concerning the deployment of small-scale gasification systems in dealing with various fuels from two countries, Portugal and Brazil, for electricity generation in a 15 kWe downdraft gasifier. To quantify this, a mathematical model was implemented and validated against experimental runs gathered from the downdraft reactor. Further, a spreadsheet economic model was developed combining the net present value (NPV), internal rate of return (IRR) and the payback period (PBP) over the project’s lifetime set to 25 years. Cost factors included expenses related to electricity generation, initial investment, operation and maintenance and fuel costs. Revenues were estimated from the electricity sales to the grid. A Monte Carlo sensitivity analysis was used to measure the performance of the economic model and determine the investment risk. The analysis showed an electricity production between 11.6 to 15 kW, with a general system efficiency of approximately 13.5%. The viability of the projects was predicted for an NPV set between 18.99 to 31.65 k€, an IRR between 16.88 to 20.09% and a PBP between 8.67 to 12.61 years. The risk assessment yielded favorable investment projections with greater risk of investment loss in the NPV and the lowest for IRR. Despite the feasibility of the project, the economic performance proved to be highly reliant on the electricity sales prices subdue of energy market uncertainties. Also, regardless of the broad benefits delivered by these systems, their viability is still strikingly influenced by governmental decisions, subsidiary support and favorable electricity sales prices. Overall, this study highlights the empowering effect of small-scale gasification systems settled in decentralized communities for electric power generation.

Syngas, a renewable fuel primarily composed of hydrogen and carbon monoxide, is emerging as a viable alternative to conventional fossil fuels in internal combustion engines (ICEs). Obtained mainly through the gasification of biomass and organic waste, syngas offers significant environmental benefits but also presents challenges due to its lower heating value and variable composition. This review establishes recent advances in understanding syngas combustion, chemical kinetics, and practical applications in spark-ignition (SI) and compression-ignition (CI) engines. Variability in syngas composition, dependent on feedstock and gasification conditions, strongly influences ignition behavior, flame stability, and emissions, demanding detailed kinetic models and adaptive engine control strategies. In SI engines, syngas can replace up to 100% of conventional fuel, typically at 20–30% reduced power output. CI engines generally require a pilot fuel representing 10–20% of total energy to start combustion, favoring dual-fuel (DF) operation for efficiency and emissions control. This work underlines the need to integrate advanced modelling approaches with experimental insights to optimize performance and meet emission targets. By addressing challenges of fuel variability and engine adaptation, syngas reveals promising potential as a clean fuel for future sustainable power generation and transport applications.

Mobile pyrolysis systems offer a practical pathway for the decentralized valorization of biomass waste, addressing the high logistical and economic burdens of transporting low-density, moisture-rich feedstocks to centralized facilities. By operating directly at the source, these systems convert diverse agricultural and forestry residues into biochar, bio-oil, pyrogas, and wood vinegar, while reducing transport volumes and associated emissions. Reported mobile reactors process between 4 kg per batch and 10 t/day, achieving biochar yields of 33–44 wt.% at 400 °C and bio-oil yields of 55–68 wt.% in fast pyrolysis at 500–550 °C, demonstrating performance comparable to stationary installations. This review synthesizes current mobile pyrolysis technologies, including reactor configurations, feedstock suitability, operational constraints, and recent advances in automation, real-time monitoring, and machine learning-based optimization. The agricultural and industrial applications of pyrolysis products are examined, with emphasis on soil health enhancement, biopesticide activity, renewable gas generation, and carbon sequestration. Emerging international projects and commercial efforts are highlighted, illustrating growing interest in flexible, low-carbon pyrolysis solutions for rural waste management and distributed bioresource utilization, while outlining the technological gaps that remain to be addressed.

Hydrogen is undoubtedly one of the most promising alternatives for generating energy with low environmental impact. However, most hydrogen produced today is derived from fossil fuels, which negatively impacts the environment. In this context, biomass conversion technologies emerge as a sustainable and environmentally friendly alternative to conventional fossil-based processes for hydrogen production. The main objective of this study is to underscore the potential of biomass-derived hydrogen, as one of the key sustainable energy solutions. This work reviews diverse biological and thermochemical pathways for biomass-derived hydrogen production, noting challenges in technology and feedstock diversity. Biomass offers local availability and economic benefits, potentially yielding negative emissions. Biological methods like bio-photolysis and fermentation promise low-energy, waste-recycling solutions despite operational constraints. Thermochemical processes, influenced by biomass type and energy content, favor economies of scale and conventional gasification for economic viability. Hydrothermal gasification shows promise for high-moisture feedstocks. Overall, while thermochemical processes suit centralized large-scale hydrogen production, biological pathways offer decentralized options, necessitating continued innovation for integration into future energy strategies.