Mining activities exert a far-reaching impact on the quality of groundwater, and health problems caused by heavy metal pollution have attracted global attention. In this study, inductively coupled plasma-mass spectrometry (ICP-MS) was employed to determine the contents of 8 heavy metals (Cd, Cr, As, Fe, Mn, Cu, Zn, and Pb) in shallow groundwater samples retrieved from a mining area in northern Anhui. Multivariate statistical methods were adopted to analyze the distribution and source of pollution and to evaluate 5% and 95% health risks based on Monte Carlo simulation. Fe, As and Cr significantly exceeded the safe drinking water standards of the World Health Organization (WHO). The average concentrations of As and Cr were as high as 46.45 μg/L and 133.96 μg/L, respectively. The correlation analysis and principal component analysis (PCA) results revealed that heavy metals are affected by complex factors, the main factor being human activities. The total carcinogenic health risks of Cr and As in adults were 2.49 × 10^-3 and 3.43 × 10^-4, respectively, which exceeded the maximum acceptable risk value (1 ×10^-4) recommended by the United States Environmental Protection Agency (USEPA), affecting human health. According to the USEPA classification of hazardous ingestion (HI), at HI < 1, the impact of non-carcinogenic heavy metals on human health is negligible. These results indicate that local residents should strengthen the monitoring of Cr and As pollution in shallow groundwater.

Coal mining cities are universally confronted with the degradation of groundwater quality, and the sulfate pollution of groundwater has become a widely studied environmental problem. In this study, we combined multi-isotope (δ³⁴S, δ¹⁸O-SO₄^2- and ⁸⁷Sr/⁸⁶Sr) approach with hydrochemical technique and a Bayesian mixed model to clarify sources and transformations and to quantitatively assess the contribution of sulfate from potential sources. The concentrations of SO₄^2- in groundwater ranged from 7.7 mg/L to 172.9 mg/L, and the high-value areas were located in coal mining area and residential area. The total values of δ³⁴S and δ¹⁸O-SO₄^2- varied from 10.6‰ to 26.9‰ and 6.9‰ to 14.1‰, respectively, in the groundwater. Analyses of SO₄^2- and Sr isotopes and water chemistry indicated that SO₄^2- in groundwater originated from various sources, such as atmospheric precipitation, sulfide mineral oxidation, evaporite dissolution, sewage and mine drainage. The oxidation of pyrite and bacterial sulfate reduction (BSR) had no significant impact on the stable isotopes of groundwater. At the same time, the calculation results of the Bayesian mixed model showed that the sources of SO₄^2- in groundwater mainly include evaporite dissolution in aquifer and mine drainage in the mixture of shallow and deep groundwater, with high contribution proportions of 39.8 ± 10.9% and 31.9 ± 5.7%, respectively, while the contributions of sewage (13.9 ± 8.5%), atmospheric precipitation (9.6 ± 8.6%) and the oxidation of sulfide (4.7 ± 3.3%) to SO₄^2- were lower. The research results revealed the source of SO₄^2- pollution in shallow groundwater in the coal mine area and provided an important scientific basis for the effective management and protection of groundwater resources.