Galactomannan, a neutral polysaccharide, was extracted from carob seeds and characterized. It was used for the first time for the fabrication of a laccase-based biosensor by the encapsulation of laccase in a chitosan+galactomannan composite. The fabricated biosensor was characterized by FTIR, scanning electron microscopy and cyclic voltammetry. The pyrocatechol detection was obtained by cyclic voltammetry measurements, through the detection of o-quinone at −0.447 V. The laccase activity was well preserved in the chitosan+galactomannan composite and the sensitivity of detection of pyrocatechol in the 10⁻¹⁶ M–10⁻⁴ M range was very high. The voltammetric response of the biosensor was stable for more than two weeks. To estimate the antioxidant capacity of olive oil samples, it was shown that the obtained laccase-based biosensor is a valuable alternative to the colorimetric Folin–Ciocalteu method.

Perovskite-modified electrodes have received increasing attention in the last decade, due to their electrocatalytic properties to undergo the sensitive and selective detection of bioactive molecules, such as hydrogen peroxide, glucose, and dopamine. In this review paper, different types of perovskites involved for their electrocatalytic properties are described, and the proposed mechanism of detection is presented. The analytical performances obtained for different electroactive molecules are listed and compared with those in terms of the type of perovskite used, its nanostructuration, and its association with other conductive nanomaterials. The analytical performance obtained with perovskites is shown to be better than those of Ni and Co oxide-based electrochemical sensors. Main trends and future challenges for enlarging and improving the use of perovskite-based electrochemical sensors are then discussed.