Two different zinc-based metal-organic frameworks (MOFs) were investigated to remove one of the most used fluoroquinolone antibiotic, Ofloxacin (OFL), from polluted water. The most common zeolitic imidazolate framework-8 (ZIF-8) and the green Zn(II) and benzene-1,3,5-tri-carboxylate (Zn₃(BTC)₂) were prepared through a facile synthetic route and characterized by means of Fourier-Transform Infrared (FT-IR) Spectroscopy, X-ray Powder Diffraction (XRPD), and Scanning Electron Microscopy (SEM) analyses. The two MOFs were compared in terms of both adsorption and kinetic aspects under real conditions (tap water, natural pH). Results showed that OFL was adsorbed in remarkable amounts, 95 ± 10 and 25.3 ± 0.8 mg g⁻¹ on ZIF-8 and Zn₃(BTC)₂, respectively, following different mechanisms. Specifically, a Langmuir model well described the ZIF-8 profile, while for Zn₃(BTC)₂, cooperative adsorption occurred. Moreover the kinetic results were quite different, pseudo-second-order and sigmoidal, respectively. The suitability of ZIF-8 and Zn₃(BTC)₂ as adsorbent phases for water depollution was tested on tap water samples spiked with OFL 10 µg L⁻¹. The obtained removal efficiencies, of 88% for ZIF-8 and 72% for Zn₃(BTC)₂, make these materials promising candidates for removing fluoroquinolone antibiotics (FQs) from polluted waters, notwithstanding their limited reusability in tap water, as demonstrated by in-depth characterization of the two MOFs after usage.

A simple not solvent and time consuming Fe₃O₄@MIL-100(Fe), synthesized in the presence of a small amount of magnetite (Fe₃O₄) nanoparticles (27.3 wt%), is here presented and discussed. Layer-by-layer alone (20 shell), and combined layer-by-layer (5 shell)/reflux or /hydrothermal synthetic procedures were compared. The last approach (Fe₃O₄@MIL-100_H sample) is suitable (i) to obtain rounded-shaped nanoparticles (200–400 nm diameter) of magnetite core and MIL-100(Fe) shell; (ii) to reduce the solvent and time consumption (the layer-by-layer procedure is applied only 5 times); (iii) to give the highest MIL-100(Fe) amount in the composite (72.7 vs. 18.5 wt% in the layer-by-layer alone); (iv) to obtain a high surface area of 3546 m² g⁻¹. The MIL-100(Fe) sample was also synthesized and both materials were tested for the absorption of Ofloxacin antibiotic (OFL). Langmuir model well describes OFL adsorption on Fe₃O₄@MIL-100_H, indicating an even higher adsorption capacity (218 ± 7 mg g⁻¹) with respect to MIL-100 (123 ± 5 mg g⁻¹). Chemisorption regulates the kinetic process on both the composite materials. Fe₃O₄@MIL-100_H performance was then verified for OFL removal at µg per liter in tap and river waters, and compared with MIL-100. Its relevant and higher adsorption efficiency and the magnetic behavior make it an excellent candidate for environmental depollution.

TiO₂ sepiolite and zeolite composites, as well the corresponding N-doped composites, synthesized through a sol–gel method, were tested for the photocatalytic degradation of a widespread fluoroquinolone antibiotic (ofloxacin) under environmental conditions. The catalysts were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM), and diffuse reflectance spectroscopy (DRS) analyses. A complete drug degradation occurred in 10–15 min in the presence of both TiO₂ sepiolite and zeolite catalysts, and in 20–30 min with the N-doped ones. Sepiolite proved to be a better TiO₂ support compared to the most common zeolite both in terms of adsorption capacity and photocatalytic efficiency in pollutants degradation. The influence of nitrogen doping (red shift from 3.2 to 3.0 eV) was also investigated. Although it was blurred by a marked increase of the particle dimension and thus a decrease of the specific surface area of the doped catalysts, it allowed a faster drug removal than direct photolysis. The photochemical paths and photoproducts were investigated, too.

The present work aimed at decorating halloysite nanotubes (HNT) with magnetic Fe₃O₄ nanoparticles through different synthetic routes (co-precipitation, hydrothermal, and sol-gel) to test the efficiency of three magnetic composites (HNT/Fe₃O₄) to remove the antibiotic ofloxacin (OFL) from waters. The chemical–physical features of the obtained materials were characterized through the application of diverse techniques (XRPD, FT-IR spectroscopy, SEM, EDS, and TEM microscopy, thermogravimetric analysis, and magnetization measurements), while ecotoxicity was assessed through a standard test on the freshwater organism Daphnia magna. Independently of the synthesis procedure, the magnetic composites were successfully obtained. The Fe₃O₄ is nanometric (about 10 nm) and the weight percentage is sample-dependent. It decorates the HNT’s surface and also forms aggregates linking the nanotubes in Fe₃O₄-rich samples. Thermodynamic and kinetic experiments showed different adsorption capacities of OFL, ranging from 23 to 45 mg g⁻¹. The kinetic process occurred within a few minutes, independently of the composite. The capability of the three HNT/Fe₃O₄ in removing the OFL was confirmed under realistic conditions, when OFL was added to tap, river, and effluent waters at µg L⁻¹ concentration. No acute toxicity of the composites was observed on freshwater organisms. Despite the good results obtained for all the composites, the sample by co-precipitation is the most performant as it: (i) is easily magnetically separated from the media after the use; (ii) does not undergo any degradation after three adsorption cycles; (iii) is synthetized through a low-cost procedure. These features make this material an excellent candidate for removal of OFL from water.