Composite electrolytes consisting of polymers and three-dimensional (3D) fillers are considered to be promising electrolytes for solid lithium batteries owing to their virtues of continuous lithium-ion pathways and good mechanical properties. In the present study, an electrolyte with polyethylene oxide–lithium (bis trifluoromethyl) sulfate–succinonitrile (PLS) and frameworks of three-dimensional SiO₂ nanofibers (3D SiO₂ NFs) was prepared. Taking advantage of the highly conductive interfaces between 3D SiO₂ NFs and PLS, the total conductivity of the electrolyte at 30 °C was approximately 9.32 × 10⁻⁵ S cm⁻¹. With a thickness of 27 μm and a tensile strength of 7.4 MPa, the electrolyte achieved an area specific resistance of 29.0 Ω cm². Moreover, such a 3D configuration could homogenize the electrical field, which was beneficial for suppressing dendrite growth. Consequently, Li/LiFePO₄ cells assembled with PLS and 3D SiO₂ NFs (PLS/3D SiO₂ NFs), which delivered an original specific capacity of 167.9 mAh g⁻¹, only suffered 3.28% capacity degradation after 100 cycles. In particular, these cells automatically shut down when PLS was decomposed above 400 °C, and the electrodes were separated by the solid framework of 3D SiO₂ NFs. Therefore, the solid lithium batteries based on composite electrolytes reported here offer high safety at elevated temperatures.

Dye-sensitized mesoscopic solar cell (DSC) has been intensively investigated as a promising photovoltaic cell. Redox electrolyte is important to determine the photovoltaic (PV) performance of the DSC devices, which has become the focus of this topic. In this contribution, recent advances in understanding and controlling of various redox couples are reviewed. Specially, we extend our discussion on the trends that enable iodide-free redox couples to be controllable and feasible for applications in the DSC with promising features.