Random laser action with coherent feedback has been observed in ZnO nanorod arrays embedded in ZnO epilayers. The sample was fabricated by depositing a MgO buffer layer and followed by a layer of ZnO thin film onto a vertically well-aligned ZnO nanorod arrays grown on sapphire substrate. Under 355 nm optical excitation at room temperature, sharp lasing peaks emit at around 390 nm with a linewidth less than 0.4 nm has been observed in all directions. In addition, the dependence of the lasing threshold intensity on the excitation area is shown in good agreement with the random laser theory. Hence, it is demonstrated that random laser action can also be supported in ZnO nanorod arrays.
Room-temperature ultraviolet lasing is demonstrated in mirrorless zinc oxide thin-film waveguides on (100) silicon substrate. Laser cavities, due to closed-loop optical scattering from the lateral facets of the irregular zinc oxide grains, are generated through the post-growth annealing of high-crystal-quality zinc oxide thin films obtained from the filtered cathodic vacuum arc technique. It is found that the lasing wavelength and linewidth of the zinc oxide random lasers under 355 nm optical excitation are around 390 nm and less than 0.4 nm, respectively. In addition, the lasing threshold characteristics are in good agreement with the random laser theory.
Raman spectroscopy is a powerful non-destructive technique for qualitatively and quantitatively characterizing materials. However, noise often obscures interesting Raman peaks due to the inherently weak Raman signal, especially in biological samples. In this study, we develop a method based on spectral reconstruction to recover Raman spectra with low signal-to-noise ratio (SNR). The synthesis of narrow-band measurements from low-SNR Raman spectra eliminates the effect of noise by integrating the Raman signal along the wavenumber dimension, which is followed by spectral reconstruction based on Wiener estimation to recover the Raman spectrum with high spectral resolution. Non-negative principal components based filters are used in the synthesis to ensure that most variance contained in the original Raman measurements are retained. A total of 25 agar phantoms and 20 bacteria samples were measured and data were used to validate our method. Four commonly used de-noising methods in Raman spectroscopy, i.e. Savitzky-Golay (SG) algorithm, finite impulse response (FIR) filtration, wavelet transform and factor analysis, were also evaluated on the same set of data in addition to the proposed method for comparison. The proposed method showed the superior accuracy in the recovery of Raman spectra from measurements with extremely low SNR, compared with the four commonly used de-noising methods.
We report the low-temperature fabrication of heterojunction light-emitting diodes by filtered cathodic vacuum arc technique. Diodelike rectifying current-voltage characteristics, with turn-on voltage of and low reverse leakage current of , were measured at room temperature. In addition, ultraviolet emission with peak wavelength of and full width at half maximum of are observed at a forward biased voltage of . The ultraviolet electroluminescence from the heterojunction is originated from the exciton-exciton scattering inside the film.
8 October 2003 in Japanese Journal of Applied Physics
Prismatic zinc oxide microtubes have been fabricated by vapor transport. Room-temperature ultraviolet lasing action has been demonstrated in these microtube arrays. The ZnO microtubes, mainly appearing in tapped bell-mouthed shape, form natural laser cavities along the length direction. The hexagon diagonal and length of the microtube vary from 1 µm to 20 µm and 10 µm to a few hundred µm respectively. Under 355 nm optical excitation, lasing action is observed at room-temperature around 393 nm. Multi-longitudinal modes are also observed with significantly narrowed emission linewidth.
Self-organized zinc oxide (ZnO) nanofiber network with six-fold symmetry was fabricated on ZnO-buffered (0001) sapphire substrate with patterned gold catalyst by vapor-phase transport method. From the ZnO buffer layer, hexagonal ZnO nanorods with identical in-plane structure grew epitaxially along [0001] orientation to form vertical stems. The nanofiber branches grew horizontally from six side-surfaces of the vertical stem along and other equivalent directions. The aligned network structure constructed a waveguide array with optical gain. Ultraviolet amplified spontaneous emission was observed along the side-branching nanofibers when the aligned ZnO network was excited by a frequency-tripled Nd:YAG laser.