Hydriding/dehydriding properties of a series of LaNi₅ based alloys were compared by applying both hydrogen gas phase and electrochemical hydrogen charge/discharge methods. The highest hydrogen absorption capacity of 1.4 wt.% H₂ was found for LaNi_4.3Co_0.4Al_0.3, although LaNi_4.8Sn_0.2 also reveals comparable hydrogen capacity (>1.3%). A significant difference in the hydriding kinetics was observed for all studied alloys before and after activation. The activated alloys (5 cycles at 65 °C, 40 atm. H₂) reach their maximum capacities after less than a minute, whereas the pure LaNi₅ alloy needs several minutes for complete hydriding. The electrochemical hydriding/dehydriding behavior of the alloys reveals superior performance of LaNi_4.3Co_0.4Al_0.3 and LaNi_4.8Sn_0.2 compared to the other compositions studied, as the capacity of LaNi_4.8Sn_0.2 decreases by only 10% for 60 charge/discharge cycles at a current density of 100 mA/g. Good agreement between the hydrogen sorption kinetics of the alloys obtained electrochemically and from hydrogen gas phase has also been observed.

The main goal of this study was to develop and validate a laboratory-scale prototype of a rechargeable metal hydride (MH)–air battery integrating gas diffusion electrodes (GDEs) and MH electrodes with stable performance over extended operation (>500 h) and repeated charge–discharge cycling (>100 cycles). This work addresses the critical transition from optimized electrode materials to a functioning system by investigating its operation under deep-discharge conditions, a key but still insufficiently explored regime in the context of stationary renewable energy storage. In this respect, this study explicitly targets the practical applicability of the developed system rather than focusing solely on material-level performance. The most efficient electrode materials, previously optimized, were successfully integrated into a single-cell configuration and systematically evaluated under various operating conditions. By determining the limiting current density for stable GDE operation, an appropriate operating window was defined, enabling maximum capacity utilization without compromising electrode integrity. At a current density of 10 mA, the maximum depth of discharge was achieved at a cell voltage of 575 mV, ensuring operation in a regime that limits GDE degradation while maintaining high energy efficiency. In addition, the electrode retains its mechanical stability after operation is interrupted, indicating good structural robustness. Furthermore, the performance of two identical cells connected in series was investigated to assess system scalability. The cells were operated under near-limit conditions and exhibited stable behavior. Overall, the present results confirm that the developed MH–air battery system extends beyond laboratory-scale validation and shows strong potential for implementation in stationary energy storage applications.