The transport of liquids, gasses, and aggressive agents into concrete is responsible for a variety of durability issues. To obtain the low-permeability concrete required for long-lasting, sustainable infrastructure, stakeholders desire the ability to specify concrete based upon the permeability rating for specific uses. The mechanisms of moisture ingress into concrete are complex phenomena, and they are highly dependent on materials, mixture characteristics, curing conditions, and other factors. This review article provides an overview of the available permeability test methods and identifies existing gaps in the current field and knowledge. It discusses the mechanisms and key factors influencing moisture movement within concrete (capillary suction, absorption, water, and gas permeability) and outlines the procedures, advantages, and limitations of available permeability test methods. Despite a variety of tests available for water permeability, widespread acceptance for use of a single (or even a few) tests has not been achieved. No clear link exists between these tests and acceptable field performance. Additionally, several tests are viewed as problematic from a time, cost, or variability standpoint. Therefore, improved rapid permeability tests are needed to provide a pathway for agencies to move toward performance specifications with confidence. Recommendations regarding future work to support the development of improved test methods and, potentially, a model that would predict moisture ingress based on electrical resistivity, are also presented.
26 October 2022 in Transportation Research Record: Journal of the Transportation Research Board
Implementation of self-healing concrete technologies is a promising approach to enhance the durability of the transportation infrastructure. Among these technologies, bacterial concrete has the potential to seal microcracks through microbial-induced calcite precipitation (MICP). To ensure the viability of this technology, bacterial protection is essential given concrete’s harsh environment. Additionally, the success of this technology depends on the presence of an adequate mineral precursor compound and nutrient for the bacteria. As such, the main objective of this study was to optimize the healing efficiency of bacterial concrete in subtropical climates through the vacuum impregnation of bacteria into a lightweight aggregate (LWA). To achieve this objective, mortar samples were prepared while incorporating different combinations of precursors (magnesium acetate, calcium lactate, and sodium lactate) and alkali-resistant healing agent Bacillus pseudofirmus bacteria (with and without). In addition, a control sample was prepared without bacteria or precursors for comparative purposes. For each sample, three mortar cubes and three mortar beams were cast and used to evaluate the compressive strength, crack healing efficiency, and flexural strength recovery. Additionally, the morphology of healing products was observed in bacteria-containing samples under scanning electron microscopy with energy x-ray dispersive spectroscopy using a scanning electron microscope (SEM) with EDAX Pegasus energy dispersive spectroscopy (EDS). Results showed that self-healing bacterial concrete could be optimized (without significant reduction in mechanical properties) if Bacillus pseudofirmus bacteria at a concentration of 108 cells/ml and sodium lactate precursor at a concentration of 75 mM/l were impregnated into lightweight aggregate.
1 December 2021 in Construction and Building Materials
We present the preparation and inhibition behavior of rebar in the presence of calcium nitrate (CN)-containing microcapsules with concentrations of 0.50, 2.00, and 5.00 wt.% in concrete. From both open circuit potential (OCP) and electrochemical impedance spectroscopy spectra, it was found that an addition of microcapsules containing CN corrosion inhibitor into concrete beams successfully repassivated or maintained the passivity of the rebar when the concrete was cracked. This corrosion inhibitor repassivated the rebar by forming a passive layer on the rebar surface under the crack. This repassivation process was evident by an increase of OCP values to more positive values or by stable OCP values at around -100 mV vs SCE. An increase in phase angle after corrosion activation for the sample with 2.00 wt.% microcapsule clearly showed this repassivation process. The optimum concentration for maintaining the passivity on rebar in the cracked concrete was found to be 5.00 wt.%.