Potential risks of supply shortages for critical metals including rare-earth elements and yttrium (REY) have spurred great interest in commercial mining of deep-sea mineral resources. Deep-sea mud containing over 5,000 ppm total REY content was discovered in the western North Pacific Ocean near Minamitorishima Island, Japan, in 2013. This REY-rich mud has great potential as a rare-earth metal resource because of the enormous amount available and its advantageous mineralogical features. Here, we estimated the resource amount in REY-rich mud with Geographical Information System software and established a mineral processing procedure to greatly enhance its economic value. The resource amount was estimated to be 1.2 Mt of rare-earth oxide for the most promising area (105 km2 × 0–10 mbsf), which accounts for 62, 47, 32, and 56 years of annual global demand for Y, Eu, Tb, and Dy, respectively. Moreover, using a hydrocyclone separator enabled us to recover selectively biogenic calcium phosphate grains, which have high REY content (up to 22,000 ppm) and constitute the coarser domain in the grain-size distribution. The enormous resource amount and the effectiveness of the mineral processing are strong indicators that this new REY resource could be exploited in the near future.
Deep-sea sediments have attracted much attention as a promising resource for rare-earth elements and yttrium (REY). In this study, we show statistically independent components characterising REY-enrichment in the abyssal ocean that are decoded by Independent Component Analysis of a multi-elemental dataset of 3,968 bulk sediment samples from 101 sites in the Pacific and Indian oceans. This study for the first time reconstructs the spatiotemporal variations of the geochemical signatures, including hydrothermal, hydrogenous and biogenic calcium phosphate components that were closely involved in the formation of REY-rich mud over the past 65 million years. An underlying key factor of significant REY-enrichment is a sufficiently low sedimentation rate that enables the mud to accumulate REY from seawater. In the early Cenozoic, a remarkably small supply of aeolian dust, compared with any other time and region, facilitated the deposition of very high-grade REY-rich mud in the South Pacific. This indicates an important link between the genesis of the seafloor mineral resources and Earth’s dynamic phenomena such as climate change and plate tectonics.
A certain type of deep‐sea sediment exhibits very high content of rare earth elements and yttrium (REY) and is therefore expected to serve as a novel resource for these industrially essential metals. In this paper, we statistically analyzed the bulk chemical composition of deep‐sea sediments collected from the western North Pacific Ocean. By applying independent component analysis to the multielemental data set, we extracted three independent components (ICs) that can be interpreted as the influence of Mn‐oxides (IC1), REY‐enriched biogenic calcium phosphate (IC2), and possibly a diagenetic effect involving Cu enrichment (IC3) on bulk sediment geochemistry. Subsequently, we selected representative samples based on the independent component analysis result, and implemented Sr–Nd–Pb isotopic analyses of bulk sediments. The results indicate that the extremely REY‐rich mud characterized by IC2 inherits the geochemical signature of deep Pacific seawater, whereas the non‐REY‐rich mud with less diagenetic alterations, characterized by IC3, implies an influence of terrigenous dust probably from the Taklimakan desert–Chinese loess plateau. IC1 may reflect the variation in sedimentation rates. Characteristic downhole variations of IC1 and IC3 scores imply the presence of hiatus and/or erosion of the sediment column across the REY content peak. The putative cause is an enhanced bottom current, which can physically separate coarse biogenic calcium phosphate grains with very high REY content and thus produce an extremely REY‐enriched sediment layer.