Cellulose is a renewable and environmentally friendly raw material that has an important economic and technical impact in several applications. Recently, nanocellulose (NC) presented a promising road to support the manufacturing of functional carbon fibers (CFs), which are considered superior materials for several applications because of their outstanding properties. However, the smooth and limited effective surface areas make CFs virtually useless in some applications, such as energy storage. Therefore, strategies to increase the porosity of CFs are highly desirable to realize their potential. Within this article, we present an approach that focuses on the designing of porous CF precursors using polyacrilonitrile (PAN) and NC additives using a wet spinning method. To enhance the porosity, two jet stretching (50% and 100%) and four NC additive amounts (0 wt.%, 0.1 wt.%, 0.4 wt.% and 0.8 wt.%) have been applied and investigated. In comparison with the reference PAN fibers (without NC additives and stretching), the results showed an increase in specific surface area from 10.45 m²/g to 138.53 m²/g and in total pore volume from 0.03 cm³/g to 0.49 cm³/g. On the other hand, mechanical properties have been affected negatively by NC additives and the stretching process. Stabilization and carbonization processes could be applied in a future study to support the production of multifunctional porous CF.

The present study proposed a novel process for the matrix decomposition of carbon-fiber-reinforced plastics (CFRPs). For this purpose, the influence of ultraviolet (UV) radiation paired with semiconductors on CFRP was analyzed. Then, suitable process parameters for superficial and in-depth matrix decomposition in CFRP were evaluated. The epoxy resin was decomposed most effectively without damaging the embedded carbon fiber by using a UV light-emitting diode (LED) spotlight (395 nm, Semray 4103 by Heraeus Noblelight) at a power level of 66% compared to the maximum power of the spotlight. Using a distance of 10 mm and a treatment duration of only 35–40 s achieved a depth of two layers with an area of 750 mm², which is suitable for technological CFRP repair procedures. In addition to the characterization of the process, the treated CFRP samples were analyzed based on several analytical methods, namely, light microscopy (LM), scanning electron microscopy (SEM), and atomic force microscopy (AFM). Subsequently, the prepared carbon fibers (CFs) were tested using filament tensiometry, single filament tensile tests, and thermogravimetric measurements. All analyses showed the power level of 66% to be superior to the use of 96% power. The gentle (“fiber friendly”) matrix destruction reduced the damage to the surface of the fibers and maintained their properties, such as maximum elongation and maximum tensile strength, at the level of the reference materials.

For several decades, carbon fibers have been used for lightweight engineering in aircraft automotive and sports industries, mostly based on high-quality polyacrylonitrile (PAN). We investigated a novel PAN-based precursor fiber (PF) modified with a polycyclic aromatic hydrocarbon, namely hexabenzocoronene (HBC), which is expected to improve the thermal conversion process and to create a carbon fiber (CF) with enhanced mechanical properties. For this purpose, the novel PF and a spun-like homopolymeric PAN-based PF were thermally stabilized and carbonized in continuous lab-scale plants. The effect of the additive HBC on the conversion processes, fiber diameter and shape, density, and mechanical properties were investigated. The results showed that HBC seems to support stabilization reactions, and HBC/PAN-based PF show potentially higher stretchability of PF and stabilized fiber. The modified CF showed an improvement in Young’s modulus of about 25% at the same tensile strength compared to the unmodified PAN-based CF, resulting from enhanced crystalline orientation. The results showed a high potential of the HBC/PAN for energy-efficient production. In particular, the influence on tensile strength and modulus under optimized process conditions, as well as the possibility to use low quality PAN, need to be further investigated.

Polyacrylonitrile/lignin blends were spun by use of solvent wet spinning. The precursor fibers have been characterized by IR, rheometer, tensile tests and density calculation. Afterwards the fiber have been stabilized by means of a batch device and the stability indexes (S.i.) were assumed through differential scanning calorimetry.