Thiol-lignocellulose sodium bentonite (TLSB) nanocomposites can effectively remove heavy metals from aqueous solutions. TLSB was formed by using –SH group-modified lignocellulose as a raw material, which was intercalated into the interlayers of hierarchical sodium bentonite. Characterization of TLSB was then performed with BET, FTIR, XRD, TGA, PZC, SEM, and TEM analyses. The results indicated that thiol-lignocellulose molecules may have different influences on the physicochemical properties of sodium bentonite, and an intercalated–exfoliated structure was successfully formed. The TLSB nanocomposite was subsequently investigated to validate its adsorption and desorption capacities for the zinc subgroup ions Zn(II), Cd(II) and Hg(II). The optimum adsorption parameters were determined based on the TLSB nanocomposite dosage, concentration of zinc subgroup ions, solution pH, adsorption temperature and adsorption time. The results revealed that the maximum adsorption capacity onto TLSB was 357.29 mg/g for Zn(II), 458.32 mg/g for Cd(II) and 208.12 mg/g for Hg(II). The adsorption kinetics were explained by the pseudo-second-order model, and the adsorption isotherm conformed to the Langmuir model, implying that the dominant chemical adsorption mechanism on TLSB is monolayer coverage. Thermodynamic studies suggested that the adsorption is spontaneous and endothermic. Desorption and regeneration experiments revealed that TLSB could be desorbed with HCl to recover Zn(II) and Cd(II) and with HNO₃ to recover Hg(II) after several consecutive adsorption/desorption cycles. The adsorption mechanism was investigated through FTIR, EDX and SEM, which demonstrated that the introduction of thiol groups improved the adsorption capacity. All of these results suggested that TLSB is an eco-friendly and sustainable adsorbent for the extraction of Zn(II), Cd(II) and Hg(II) ions in aqueous media.

What should be done after an adsorbent has adsorbed heavy metals? Most previous studies on adsorption materials only focused on the preparation method and adsorption capacity and seldom considered the potential pollution of hazardous waste adsorbents. In this study, we not only designed an Amination@Wood-Aerogel (AWA) bulk adsorbent with easy recovery and high adsorption capacity for Zn(II) (400 mg L⁻¹, 297.03 mg g⁻¹) but also for the first time proposed a novel high-value reuse strategy for the in situ conversion of Zn(II) adsorbed onto AWA to ZnO/ZnS n-type heterojunction photocatalyst (ZnO/ZnS@AWA) via in situ chemical deposition, which will be further used for the photocatalytic degradation of Congo red. The adsorption sites (–OH, –COOH, –NH₂) on the AWA surface ensure that ZnO/ZnS could cover the AWA surface evenly with strong interfacial bonding strength. ZnO/ZnS@AWA successfully photocatalytically degraded Congo red (40 mg L⁻¹, 98.84%) through the synergistic degradation mechanism of adsorption and photocatalysis. This work proposes a new protocol for wood-based bulk adsorbents and provides a high-value reuse strategy for solving the potential pollution of hazardous waste adsorbents. It is indisputable that we point out a new direction to design adsorbents with high adsorption capacity and high-value reuse.

Heavy metal wastewater treatment is a huge problem facing human beings, and the application degree of Salix psammophila resources produced by flat stubble is low. Therefore, it is very important to develop high-value products of Salix psammophila resources and apply them in the removal heavy metal from effluent. In this work, we extracted the cellulose from Salix psammophila, and cellulose nanofibers (CNFs) were prepared through TEMPO oxidation/ultrasound. The aerogel spheres derived from Salix psammophila (ASSP) were prepared with the hanging drop method. The experimental results showed that the Cu(II) adsorption capacity of the ASSP composite (267.64 mg/g) doped with TOCNF was significantly higher than that of pure cellulose aerogel spheres (52.75 mg/g). The presence of carboxyl and hydroxyl groups in ASSP enhanced the adsorption capacity of heavy metals. ASSP is an excellent heavy metal adsorbent, and its maximum adsorption values for Cu(II), Mn(II), and Zn(II) were found to be 272.69, 253.25, and 143.00 mg/g, respectively. The abandoned sand shrub resource of SP was used to adsorb heavy metals from effluent, which provides an important reference value for the development of forestry in this sandy area and will have a great application potential in the fields of the adsorption of heavy metals in soil and antibiotics in water.

Zeolitic imidazolate framework-8 (ZIF-8) was evenly loaded on the surface of TiO₂ doped with KI, using a solvent synthesis method, in order to produce a ZIF-8@TiO₂ (KI) adsorption photocatalyst with good adsorption and photocatalytic properties. The samples were characterized by XRD, SEM, EDX, XPS, BET and UV-Vis. The photocatalytic efficiency of the material was obtained by photocatalytic tests. The results indicate that the doping with I inhibited the grain growth and reduced the crystallite size of TiO₂, reduced the band gap width and improved the utilization rate for light. TiO₂ (KI) was a single crystal of anatase titanium dioxide. The combination of ZIF-8 and TiO₂ (KI) improved the specific surface area and increased the reaction site. The ZIF-8@TiO₂ (KI) for Congo red was investigated to validate its photocatalytic performance. The optimal concentration of Congo red solution was 30 mg/L, and the amount of catalyst was proportional to the degradation efficiency. The degradation efficiency of ZIF-8@TiO₂ (5%KI) was 76.42%, after being recycled four times.