Although the discovery of plastic in the last century has brought enormous benefits to daily activities, it must be said that its use produces countless environmental problems that are difficult to solve.

The aim of this study is to examine the efficiency of biobased Spanish broom (SB) surface modified cellulose fibers to remove bisphenol A (BPA), a well-known endocrine disruptor, from water. Spanish brooms are flowering plants, which are native and abundant to Mediterranean regions. The functionalized fibers (FF) were found to have the best adsorption efficiency at pH 5, due to the optimal hydrophobic interaction between the FF fiber and BPA. Adsorption kinetics of BPA was found to fit well a pseudo-second order reaction. Equilibrium isotherm data were fitted by Langmuir and Freundlich models. A very fast and simple regeneration method was developed and it was observed that adsorption capacity of the fibers was kept almost unchanged after 3 consecutive uses. Bottled water and synthetic wastewater were also tested to assess the efficiency of the process under more realistic water and wastewater treatment conditions. It was found that BPA removal was slightly decreased from 77% in ultrapure water to 64% in synthetic wastewater matrix, indicating that FF has a high selectivity toward BPA, even in the presence of other organic compounds. Overall, it was observed that SB-modified fibers can be a new promising green biotechnology for water purification.

Carbonate lithologies host considerable quantities of the Earth's freshwater resources and partially supply a quarter of the global population with drinkable water. In addition, carbonates constitute substantial amounts of the global coastlines, yet it is not known if and how they can sustain freshened groundwater offshore. Here, we use controlled‐source electromagnetic, seismic reflection, and core sample data to derive a lithological model for the eastern margin of the Maltese Islands and identify four distinct resistivity anomalies within the Upper Coralline and Globigerina Limestone formations. The anomalies hosted in the former are likely associated with low porosities, whereas the anomaly within the latter is indicative of pore fluid freshening. Hydrogeological modeling suggests that freshened pore fluids, emplaced during sea‐level lowstands and preserved in low permeability units, are potentially still found within carbonate shelves. However, resource potential is low due to its relict nature and low permeability host environment.

BTX stands for Benzene, Toluene, and Xylenes, which are volatile organic compounds contained in petroleum products such as gasoline. They have negative health effects and are sadly known for soil, air, and water contamination. This paper provides an investigation on BTX removal from open water systems like those represented by natural water bodies. In such systems, the evaporation process takes place, stealing the pollutants from the aqueous matrix by transferring them into the air, resulting in a secondary pollution. To prevent this situation, adsorption of these organic compounds on cellulose fibers, extracted from Spanish Broom vegetable, was studied. Raw and surface modified cellulose fibers were used for this purpose. The second ones were hydrophobized by two different green and low-cost functionalization systems (no solvent urethane functionalization and low pressure plasma treatments). Batch experiments were performed in an open system where BTX underwent two competing removing mechanisms: volatilization, and adsorption/desorption on/from the fibers dispersed in the water system. A mathematical model was implemented for the interpretation of the observed time-varying pollutant concentrations and the estimation of the kinetic constants for adsorption, desorption, and evaporation. The developed model, provided with the aforementioned parameters calibrated for each type of fibers, was then used for the prediction of their adsorption capacities both into open and closed systems.

Lahars are erosive floods, mixtures of water and pyroclastic detritus, known for being the biggest environmental disaster and causing a large number of fatalities in volcanic areas. Safety measures have been recently adopted in the threatened territories by constructing retaining dams and embankments in key positions. More disastrous events could be generated by the difficulty of maintaining these works in efficiency and for the changed risk conditions originating from their presence and the effects of their functioning. LLUNPIY/3r, a version of the cellular-automaton model LLUNPIY for lahar simulations, is presented. The growing frequency of lahars in the Vascún valley of Tungurahua volcano (Ecuador), probably due to the effects of the climatic change, has recently produced smaller and less dangerous events, sometimes favored by the collapse of ponds generated by small landslides. An investigation is performed here in order to reproduce such situations in a controlled way by the use of LLUNPIY/3r simulations. Using precise field data, points are individuated where dams by backfill, which are easy to collapse, can produce the formation of ponds; LLUNPIY/3r simulations permit projecting the triggering of small lahars by minor rainfall events or projecting, in the case of more rainfall, the anticipation of lahar detachment, avoiding simultaneous and dangerous confluence with other lahars.